Substituent-Dependent Absorption and Fluorescence Properties of Perylene Bisimide Radical Anions and Dianions

2021 ◽  
Author(s):  
Rebecca Renner ◽  
Matthias Stolte ◽  
Julia Heitmüller ◽  
Tobias Brixner ◽  
Christoph Lambert ◽  
...  

Perylene-3,4:9,10-bis(dicarboximides) (PBIs) rank among the most important functional dyes and organic semiconductors but only recently their radical anions and dianions attracted interest for a variety of applications. Here, we systematically...

2021 ◽  
Author(s):  
Mingguang Zhu ◽  
Meihui Chen ◽  
Hongyu Guo ◽  
Fafu Yang

Abstract A novel fluorescein-bridged perylene bisimide (PBI) dimer for liquid crystal (LC) with geometrically symmetric structure was developed. The mesomorphic results indicated that the energetically stable and unstable conformers of fluorescein fragments could lead to the transformation of mesophases from a hexagonal columnar mesophase to an uncertain phase at 136.9 °C in heating, whilst a stable hexagonal columnar mesophase maintained between 175.6 °C and 58.6 °C in cooling. The selectively excited fluorescence characters in THF solution demonstrated that the fluorescence resonance energy transfer (FRET) effect between fluorescein fragments and PBI unites could provide a means to effectively impose strong fluorescence of the dimeric PBIs modified with suitable chromophore at the N-imide position, which alternatively serves as a platform for the further study of multi-functional PBI-based LCs.


2003 ◽  
Vol 13 (4) ◽  
pp. 767-772 ◽  
Author(s):  
Ulrike Haas ◽  
Christoph Thalacker ◽  
Jörg Adams ◽  
Jürgen Fuhrmann ◽  
Silke Riethmüller ◽  
...  

2018 ◽  
Vol 54 (18) ◽  
pp. 2208-2211 ◽  
Author(s):  
Lingyun Cui ◽  
Yang Jiao ◽  
Anhe Wang ◽  
Luyang Zhao ◽  
Qianqian Dong ◽  
...  

The behavior of PBI self-assembly can be precisely organised by the conjugation of sequence dependent dipeptides in aqueous media resulting in different assembled nanostructures with improved radical anions yield and enhanced photothermal conversion efficiency.


ChemPhysChem ◽  
2004 ◽  
Vol 5 (1) ◽  
pp. 137-140 ◽  
Author(s):  
Zhijian Chen ◽  
Michael G. Debije ◽  
Tony Debaerdemaeker ◽  
Peter Osswald ◽  
Frank Würthner

2007 ◽  
Vol 19 (21) ◽  
pp. 3692-3695 ◽  
Author(s):  
R. Schmidt ◽  
M. M. Ling ◽  
J. H. Oh ◽  
M. Winkler ◽  
M. Könemann ◽  
...  

2012 ◽  
Vol 48 (99) ◽  
pp. 12050 ◽  
Author(s):  
Mei-Jin Lin ◽  
Ángel J. Jiménez ◽  
Christian Burschka ◽  
Frank Würthner

2021 ◽  
Author(s):  
Sheetal Marganakop ◽  
Pramod Kattimani ◽  
Sudha Belgur Satyanarayana ◽  
Ravindra Kamble

Microwave chemistry involves the application of microwave radiation to chemical reactions and has played an important role in organic synthesis. Functional dyes are those with hi-tech applications and this chapter attempts to provide an overview of the recent developments in microwave-assisted synthesis of functional dyes. Emphasis has been paid to the microwave-assisted synthesis of dye molecules which are useful in hi-tech applications such as optoelectronics (dye-sensitized solar cells), photochromic materials, liquid crystal displays, newer emissive displays (organic-light emitting devices), electronic materials (organic semiconductors), imaging technologies (electrophotography viz., photocopying and laser printing), biomedical applications (fluorescent sensors and anticancer treatment such as photodynamic therapy). In this chapter, the advantages of microwaves as a source of energy for heating synthesis reactions have been demonstrated. The use of microwaves to functional dyes is a paradigm shift in dye chemistry. Until recently most academic laboratories did not practice this technique in the synthesis of such functional dyes but many reports are being appeared in the journals of high repute.


2021 ◽  
Author(s):  
Keita Tajima ◽  
Kyohei Matsuo ◽  
Hiroko Yamada ◽  
Shu Seki ◽  
Norihito Fukui ◽  
...  

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