Effective Removing of Remazol Black B by the Polyacrylamide Cryogels Modified with Polyethyleneimine

Author(s):  
Zehra Gün Gök ◽  
Murat İnal
2011 ◽  
Vol 9 (5) ◽  
pp. 867-876 ◽  
Author(s):  
Monika Wawrzkiewicz ◽  
Zbigniew Hubicki

AbstractIn this study, the use of the weakly basic anion exchange resins of phenol-formaldehyde (Amberlyst A 23), polyacrylate (Amberlite IRA 67) and polystyrene (Lewatit MonoPlus MP 62) matrices for removal of the reactive dye Remazol Black B (RBB) from aqueous solution and wastewater were investigated. RBB sorption on the anion exchangers was a time dependent process. Color reduction percentiles of 75.2, 33.9 and 25.1% in wastewater treatment were found after 216 h of phase contact time with Lewatit MonoPlus MP 62, Amberlyst A 23 and Amberlite IRA 67, respectively. Inorganic salts and anionic surfactant action influenced RBB uptake by the anion exchangers. The amounts of dye retained by the anion exchangers increased with a rise in temperature. The maximum sorption capacities calculated from the Langmuir model were 66.4, 282.1 and 796.1 mg g−1 for Amberlite IRA 67, Amberlyst A 23 and Lewatit MonoPlus MP 62, respectively. Regeneration of phenol-formaldehyde and polystyrene resins were possible using 1 M NaOH, 2 M KSCN, 1M KSCN in 40–60% methanol as well as 1 M NaOH in 60% methanol.


2019 ◽  
Vol 2019 ◽  
pp. 1-15 ◽  
Author(s):  
Pham Dinh Du ◽  
Huynh Thi Minh Thanh ◽  
Thuy Chau To ◽  
Ho Sy Thang ◽  
Mai Xuan Tinh ◽  
...  

In the present paper, the synthesis of metal-organic framework MIL-101 and its application in the photocatalytic degradation of Remazol Black B (RBB) dye have been demonstrated. The obtained samples were characterized by X-ray diffraction (XRD), transmission electron microscope (TEM), X-ray photoelectron spectroscopy (XPS), and nitrogen adsorption/desorption isotherms at 77 K. It was found that MIL-101 synthesized under optimal conditions exhibited high crystallinity and specific surface area (3360 m2·g-1). The obtained MIL-101 possessed high stability in water for 14 days and several solvents (benzene, ethanol, and water at boiling temperature). Its catalytic activities were evaluated by measuring the degradation of RBB in an aqueous solution under UV radiation. The findings show that MIL-101 was a heterogeneous photocatalyst in the degradation reaction of RBB. The mechanism of photocatalysis was considered to be achieved by the electron transfer from photoexcited organic ligands to metallic clusters in MIL-101. The kinetics of photocatalytic degradation reaction were analyzed by using the initial rate method and Langmuir-Hinshelwood model. The MIL-101 photocatalyst exhibited excellent catalytic recyclability and stability and can be a potential catalyst for the treatment of organic pollutants in aqueous solutions.


2011 ◽  
Vol 7 (4) ◽  
pp. 286-295 ◽  
Author(s):  
Irfan Timur ◽  
B. Filiz Senkal ◽  
Nagihan M. Karaaslan ◽  
Tulin BAL ◽  
Emine Cengiz ◽  
...  

2012 ◽  
Vol 32 (4) ◽  
pp. 328-341 ◽  
Author(s):  
Alireza Ashori ◽  
Yahya Hamzeh ◽  
Elham Azadeh ◽  
Soheila Izadyar ◽  
Mohammad Layeghi ◽  
...  

2012 ◽  
Vol 20 (4) ◽  
pp. 2472-2483 ◽  
Author(s):  
Arzu Y. Dursun ◽  
Ozlem Tepe ◽  
Gülşad Uslu ◽  
Gülbeyi Dursun ◽  
Yusuf Saatci

2013 ◽  
Vol 15 (1) ◽  
pp. 21-28 ◽  

In the present study, the photocatalytic treatment of two synthetic textile dyehouse effluents was investigated. The first synthetic effluent (SE1) is a Remazol Black B aqueous solution, while the second one (SE2) is an aqueous mixture of sixteen dyes and auxiliary chemicals that are usually employed in the textile industry. Various illumination sources were studied, while emphasis was given on the use of simulated and natural solar light. Results indicated that the use of solar irradiation can constitute an advantageous treatment strategy, due to its energy efficient and environmentally friendly operation, for textile dyehouse effluents. Specifically, it was observed that total decolorization and mineralization of SE1 occurred after about 120 min and 300 min, respectively, in the presence of at least 2 g L-1 TiO2, under natural sunlight. On the other hand, total decolorization of SE2 was achieved only after 300 min of photocatalytic treatment, while COD removal practically remained unchanged, at about 20%, regardless the applied operating parameters, due to the presence of other organic and inorganic substances. Furthermore, it was found that process efficiency was significantly affected by the catalyst loading.


2016 ◽  
Vol 5 (1) ◽  
Author(s):  
Ni Putu Sri Ayuni ◽  
Ni Wayan Yuningrat ◽  
Ketut Yesi Andriani

Abstrak Sekitar 2-50% dari zat warna azo yang digunakan selama proses pencelupan ini tidak mengikat serat dan langsung dilepaskan ke lingkungan melalui instalasi pengolahan limbah. Hal ini perlu dilakukan pengolahan limbah cair yang mengandung zat warna azo jenis Remazol Black B sebelum dibuang ke lingkungan. Penelitian ini bertujuan untuk mengetahui kondisi optimum membran PEC kitosan-pektin yang dapat digunakan untuk mengadsorpsi zat warna azo jenis Remazol Black B .Untuk memperoleh kondisi optimum akan dilakukan adsorpsi zat warna azo jenis Remazol Black B dengan variasi waktu kontak (5-150 menit), pH (5-9) dan konsentrasi larutan zat warna azo jenis Remazol Black B (5, 10, 15, 20, dan 25 mg/L). Untuk mengetahui karakteristik zat warna jenis Remazol Black B oleh membran PEC kitosan-pektin di analisis dengan persamaan isoterm adsorpsi Langmuir dan isoterm adsorpsi Freundlich sedangkan daya adsorpsi maksimum dari membran PEC kitosan pektin ditentukan dari kurva berdasarkan karakteristik membran yang diperoleh. Hasil penelitian menunjukkan bahwa adsorpsi zat warna azo jenis Remazol Black B terjadi pada kondisi optimum dengan pH 5, waktu 120 menit dan konsentrasi larutan zat warna azo jenis Remazol Black B 10 mg/L (62,75 %). Pola adsorpsi mengikuti pola adsorpsi isoterm Freundlich dengan daya adsorpsi maksimum 0,02 (mg/g). Untuk efisiensi desorpsi maksimal diperoleh pada larutan NaCl 1 M (11,17 %) Kata Kunci: adsorpsi, membran polielektrolit kitosan pektin, Remazol Black B Abstract Azo dyes produced approximately 2-50% from dying process were thrown through effluent to the environment without any treatment. The objective of this research were to know the optimum condition of PEC chitosan pectin membrane using to adsorp Remazol Black B with various contact time (5-150 min), pH (5-9) and Remazol Black B concentration (5, 10, 15, 20, dan 25 mg/L). Adsorption charactheristic of Remazol Black B by PEC chitosan pectin membrane were determined by Langmuir and Freundlich isotherm equation. Maximum capacity adsorption was determined by the graph of membrane characteristic. The results show that optimum condition of Remazol Black B adsorption by PEC chitosan pectin membrane at pH 5, 10 mg/L remazol black B for 120 minutes (62,75 %). The adsorption pattern is Freundlich isoterm with maximum capacity 0,02 (mg/g).Maximal Desorption efisiency at NaCl 1 M (11,17 %) Keywords : adsorption, PEC chitosan pectin membrane, Remazol Black B


Sign in / Sign up

Export Citation Format

Share Document