Solubility Parameters Measurements of 1-Propyl-3-Methyl-Imidazolium-Based Ionic Liquids via Inverse Gas Chromatography and Hansen Solubility Parameter in Practice

2021 ◽  
Author(s):  
Yanbiao Hu ◽  
Qiang Wang ◽  
Nuerbiya Yalikun ◽  
Shiqi Liu ◽  
Jing Li ◽  
...  
Keyword(s):  
Gas Chromatography ◽  
Ionic Liquids ◽  
Solubility Parameter ◽  
Inverse Gas Chromatography ◽  
Solubility Parameters ◽  
Hansen Solubility Parameter ◽  
Hansen Solubility

scholarly journals Practical Determination of the Solubility Parameters of 1-Alkyl-3-methylimidazolium Bromide ([CnC1im]Br, n = 5, 6, 7, 8) Ionic Liquids by Inverse Gas Chromatography and the Hansen Solubility Parameter

Molecules ◽  
2019 ◽  
Vol 24 (7) ◽  
pp. 1346 ◽  
Author(s):  
Qiao-Na Zhu ◽  
Qiang Wang ◽  
Yan-Biao Hu ◽  
Xawkat Abliz
Keyword(s):  
Gas Chromatography ◽  
Ionic Liquids ◽  
Physicochemical Properties ◽  
Solubility Parameter ◽  
Room Temperature ◽  
Inverse Gas Chromatography ◽  
Retention Volume ◽  
Solubility Parameters ◽  
Hansen Solubility Parameter ◽  
Hansen Solubility

The physicochemical properties of four 1-alkyl-3-methylimidazolium bromide ([CnC1im]Br, n = 5, 6, 7, 8) ionic liquids (ILs) were investigated in this work by using inverse gas chromatography (IGC) from 303.15 K to 343.15 K. Twenty-eight organic solvents were used to obtain the physicochemical properties between each IL and solvent via the IGC method, including the specific retention volume and the Flory–Huggins interaction parameter. The Hildebrand solubility parameters of the four [CnC1im]Br ILs were determined by linear extrapolation to be δ 2 ( [ C 5 C 1 im ] Br ) = 25.78 (J·cm−3)0.5, δ 2 ( [ C 6 C 1 im ] Br ) = 25.38 (J·cm−3)0.5, δ 2 ( [ C 7 C 1 im ] Br ) =24.78 (J·cm−3)0.5 and δ 2 ( [ C 8 C 1 im ] Br ) = 24.23 (J·cm−3)0.5 at room temperature (298.15 K). At the same time, the Hansen solubility parameters of the four [CnC1im]Br ILs were simulated by using the Hansen Solubility Parameter in Practice (HSPiP) at room temperature (298.15 K). The results were as follows: δ t ( [ C 5 C 1 im ] Br ) = 25.86 (J·cm−3)0.5, δ t ( [ C 6 C 1 im ] Br ) = 25.39 (J·cm−3)0.5, δ t ( [ C 7 C 1 im ] Br ) = 24.81 (J·cm−3)0.5 and δ t ( [ C 8 C 1 im ] Br ) = 24.33 (J·cm−3)0.5. These values were slightly higher than those obtained by the IGC method, but they only exhibited small errors, covering a range of 0.01 to 0.1 (J·cm−3)0.5. In addition, the miscibility between the IL and the probe was evaluated by IGC, and it exhibited a basic agreement with the HSPiP. This study confirms that the combination of the two methods can accurately calculate solubility parameters and select solvents.

scholarly journals Applications of the Hansen solubility parameter for cellulose

BioResources ◽  
2021 ◽  
Vol 16 (4) ◽  
pp. 7112-7121
Author(s):  
Jinyan Lang ◽  
Na Wang ◽  
Xinhui Wang ◽  
Yili Wang ◽  
Guorong Chen ◽  
...  
Keyword(s):  
Solubility Parameter ◽  
Solvent System ◽  
Accurate Prediction ◽  
Solubility Parameters ◽  
Hansen Solubility Parameters ◽  
Solvent Selection ◽  
Cellulose Solvent ◽  
Hansen Solubility Parameter ◽  
Parameter Theory ◽  
Hansen Solubility

Based on the solubility parameter theory, the Hansen solubility parameters of various solvents were calculated and compared to predict the solubility of cellulose in various solvents, which illustrates the feasibility of Hansen solubility parameters to predict the solubility of cellulose in solvents. This paper aims to make a more accurate prediction in advance when finding suitable cellulose solvent system, and then to reduce the burden of cellulose solvent selection.

INVERSE GAS CHROMATOGRAPHY STUDY OF HANSEN SOLUBILITY PARAMETERS OF RUBBER PROCESS OILS (DAE, TDAE, MES, AND NAP)

2019 ◽  
Vol 93 (2) ◽  
pp. 297-318 ◽  
Author(s):  
Negin Farshchi ◽  
Ali Abbasian
Keyword(s):  
Gas Chromatography ◽  
Inverse Gas Chromatography ◽  
Alkyl Chain ◽  
Solubility Parameters ◽  
Hansen Solubility Parameters ◽  
Polar Solvents ◽  
Significant Difference ◽  
Increasing Temperature ◽  
Parameter Values ◽  
Hansen Solubility

ABSTRACT Process oils are used for rubbers to improve their flexibility and processability in industry. The solubility parameter is a convenient way to determine the solubility of materials. Inverse gas chromatography was used to calculate the solubility parameters and depict solubility spheres for distillated aromatic extract (DAE), treated distillate aromatic extract (TDAE), mildly extracted solvate (MES), and hydro processed naphthenic oil (NAP). Results showed that despite the similarity in values of the solubility parameters of DAE and TDAE at ambient temperature, increasing temperature led to a significant difference in values. In contrast to other oils, TDAE showed a better compatibility with polar solvents. In addition, the interaction parameters showed no specific dependence on the temperature for DAE, MES, and NAP, except for polar solvents and TDAE. DAE had the highest compatibility with aromatic solvents. Upon raising the temperature to values greater than 100 °C, the compatibility trend between oils and toluene was the same for all oils investigated, except for TDAE, which increased with increasing temperature whereas others showed a reduction. The increase in the alkyl chain was also effective in increasing the compatibility of the probes as well as their interaction parameter values. The solubility parameters (δ2) of process oils were determined to be 18.9, 18.9, 18.5, and 19.0 (J/cm3)0.5 for DAE, TDAE, NAP, and MES at 25 °C, respectively.

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