Kinetic investigations of emulsion- and solvent-mediated radiation induced graft copolymerization of glycidyl methacrylate onto nylon-6 fibres

2016 ◽  
Vol 311 (1) ◽  
pp. 843-857 ◽  
Author(s):  
Teo Ming Ting ◽  
Mohamed Mahmoud Nasef ◽  
Paveswari Sithambaranathan
2015 ◽  
Vol 719-720 ◽  
pp. 63-66 ◽  
Author(s):  
T.M. Ting ◽  
Mohamed Mahmoud Nasef ◽  
Kamaruddin Hashim

The graft copolymerization of vinylbenzyl chloride (VBC) onto nylon-6 fiber was investigated by the pre-irradiation method using electron beam. The effects of grafting parameters, monomer concentration, absorbed dose and reaction temperature were investigated. The empirical kinetic rate equation dGo/dt=k[M]^0.86*[D]^1.06 was used to describe grafting of VBC onto nylon-6. The overall activation energy for graft copolymerization of VBC was found to be 22.6 kJ/mol. The results revealed that the grafting kinetic was controlled by the amounts of trapped radicals and monomer molecules. Fourier transform infrared (FT-IR) was used to provide evidence for the formation of grafted copolymers.


2016 ◽  
Vol 122 ◽  
pp. 35-42 ◽  
Author(s):  
Rihab Musaad Moawia ◽  
Mohamed Mahmoud Nasef ◽  
Nor Hasimah Mohamed ◽  
Adnan Ripin

1975 ◽  
Vol 11 (1) ◽  
pp. 19-24 ◽  
Author(s):  
M.A. El-Azmirly ◽  
A.H. Zahran ◽  
M.F. Barakat

1961 ◽  
Vol 18 (197) ◽  
pp. 550-556 ◽  
Author(s):  
Ichiro Sakurada ◽  
Toshio Okada ◽  
Sadao Torikai

1996 ◽  
Vol 61 (2) ◽  
pp. 259-267 ◽  
Author(s):  
Bhupendra N. Misra ◽  
G. S. Chauhan ◽  
Inderjeet Kaur

Radiation-induced graft copolymerization of vinyl acetate (VAC) and isopropenyl acetate (PAC) onto isotactic polypropylene (IPP) has been studied. The percentage of grafting was calculated for various reaction parameters, and the optimum conditions for attaining the maximum percentage of grafting were determined. Maximal achieved extents of grafting are 39% and 29% for VAC and PAC, respectively. The reactivity of the two monomers with respect to grafting is discussed.


2004 ◽  
Vol 15 (5) ◽  
pp. 270-274 ◽  
Author(s):  
M. Patri ◽  
Varsha R. Hande ◽  
Swati Phadnis ◽  
B. Somaiah ◽  
Suhasini Roychoudhury ◽  
...  

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