Impact of surface modification on the properties of sol–gel synthesized nanotitanium dioxide (TiO2)-based styrene butadiene rubber (SBR) nanocomposites

2015 ◽  
Vol 77 (3) ◽  
pp. 718-726 ◽  
Author(s):  
Kumarjyoti Roy ◽  
Swapan Kumar Mandal ◽  
Md. Najib Alam ◽  
Subhas Chandra Debnath
Keyword(s):  
Surface Modification ◽  
Sol Gel ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Styrene Butadiene

In situsilica reinforcement of vinyltriethoxysilane-grafted styrene-butadiene rubber by sol-gel process

2012 ◽  
Vol 128 (4) ◽  
pp. 2262-2268 ◽  
Author(s):  
Changjie Yin ◽  
Qiuyu Zhang ◽  
Junwei Gu ◽  
Jucheng Zheng ◽  
Guangbi Gong ◽  
...  
Keyword(s):  
Sol Gel ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Sol Gel Process ◽  
Styrene Butadiene

Cure Characteristics and Mechanical Properties of NR/ SBR Blends Filled with Nano-sized CaCO3

2005 ◽  
Vol 21 (2) ◽  
pp. 101-115
Author(s):  
Chaoying Wan ◽  
Yong Zhang ◽  
Yin Zhu ◽  
Yinxi Zhang
Keyword(s):  
Mechanical Properties ◽  
Surface Modification ◽  
Stearic Acid ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Cure Rate ◽  
Cure Characteristics ◽  
Cure Time ◽  
Surface Modified ◽  
Styrene Butadiene

Four kinds of nano-sized calcium carbonate (CaCO3) surface-modified with stearic acid, aluminate, titanate and aluminate-titanate complex coupling agents, were used to reinforce natural rubber (NR)/styrene-butadiene rubber (SBR) blends. The effects of surface modification and CaCO3 content on the cure characteristics, swelling behaviour, and mechanical properties of NR/SBR blends were studied. The surface modification of CaCO3 improved the processing and mechanical properties, and the stearic acid coated CaCO3 (SA-CaCO3) had finer dispersion and produced a better reinforcement effect than the other modified CaCO3. Furthermore, a commercial high abrasion furnace carbon black (HAF) was used for comparison. The results showed that both CaCO3 and HAF increased the cure rate, reduced the optimum cure time and improved the mechanical properties of NR/SBR blends at appropriate filler contents. The tensile strength of filled NR/SBR composites reached its maximum value when the SA-CaCO3 content was 50 phr or the HAF content was 30 phr. The modulus at 200%, tear strength, and Shore A hardness of filled NR/SBR composites all increased with increasing filler content. The CaCO3 reinforced the NR/SBR blends to some extent, though it was still not as effective as HAF.

The Effect of Bis(3-Triethoxysilylpropyl) Tetrasulfide on Silica Reinforcement of Styrene-Butadiene Rubber

1998 ◽  
Vol 71 (2) ◽  
pp. 289-299 ◽  
Author(s):  
A. S. Hashim ◽  
B. Azahari ◽  
Y. Ikeda ◽  
S. Kohjiya
Keyword(s):  
Fine Particles ◽  
Sol Gel ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Mechanical Mixing ◽  
Transmission Electron ◽  
Curing Characteristics ◽  
Sol Gel Process ◽  
Styrene Butadiene

Abstract Bis(3-triethoxysilylpropyl)tetrasulfide (TESPT) was found to affect the curing characteristics and the physical properties of styrene-butadiene (SBR) gum rubber and xin situ silica-filled SBR vulcanizates. Silica incorporated by the in situ sol-gel reaction of tetraethoxysilane with TESPT showed a much higher reinforcing efficiency than did conventional mechanical mixing and the in situ method without TESPT. The higher reinforcing efficiency is attributed to the formation of a silica-rubber network, which also changed the dynamic mechanical behavior of the SBR vulcanizates. Transmission electron microscopy observations showed in situ silica incorporation of very fine particles in comparison to the sol-gel process without TESPT.

scholarly journals Effects of octamethylcyclotetrasiloxane grafting and in situ silica particle generation on the curing and mechanical properties of a styrene butadiene rubber composite

RSC Advances ◽  
2019 ◽  
Vol 9 (59) ◽  
pp. 34330-34341 ◽  
Author(s):  
Changjie Yin ◽  
Qiuyu Zhang
Keyword(s):  
Mechanical Properties ◽  
Silica Particle ◽  
Sol Gel ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Particle Generation ◽  
In Situ Silica ◽  
Rubber Composite ◽  
Styrene Butadiene

The reinforcement of octamethylcyclotetrasiloxane (D4) grafted styrene butadiene rubber (SBR-g-D4) with in situ generated silica was performed using the sol–gel reaction of tetraethoxysilane (TEOS) in latex.

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