Effect of catalyst onin situ silica reinforcement of styrene–butadiene rubber vulcanizate by the sol–gel reaction of tetraethoxysilane

1997 ◽  
Vol 7 (3) ◽  
pp. 455-458 ◽  
Author(s):  
Yuko Ikeda ◽  
Akira Tanaka ◽  
Shinzo Kohjiya
2012 ◽  
Vol 128 (4) ◽  
pp. 2262-2268 ◽  
Author(s):  
Changjie Yin ◽  
Qiuyu Zhang ◽  
Junwei Gu ◽  
Jucheng Zheng ◽  
Guangbi Gong ◽  
...  

2017 ◽  
Vol 58 (1) ◽  
pp. 74-85 ◽  
Author(s):  
Joyeeta Ghosh ◽  
Soumyajit Ghorai ◽  
Satyaban Bhunia ◽  
Madhusudan Roy ◽  
Debapriya De

1998 ◽  
Vol 71 (2) ◽  
pp. 289-299 ◽  
Author(s):  
A. S. Hashim ◽  
B. Azahari ◽  
Y. Ikeda ◽  
S. Kohjiya

Abstract Bis(3-triethoxysilylpropyl)tetrasulfide (TESPT) was found to affect the curing characteristics and the physical properties of styrene-butadiene (SBR) gum rubber and xin situ silica-filled SBR vulcanizates. Silica incorporated by the in situ sol-gel reaction of tetraethoxysilane with TESPT showed a much higher reinforcing efficiency than did conventional mechanical mixing and the in situ method without TESPT. The higher reinforcing efficiency is attributed to the formation of a silica-rubber network, which also changed the dynamic mechanical behavior of the SBR vulcanizates. Transmission electron microscopy observations showed in situ silica incorporation of very fine particles in comparison to the sol-gel process without TESPT.


RSC Advances ◽  
2019 ◽  
Vol 9 (59) ◽  
pp. 34330-34341 ◽  
Author(s):  
Changjie Yin ◽  
Qiuyu Zhang

The reinforcement of octamethylcyclotetrasiloxane (D4) grafted styrene butadiene rubber (SBR-g-D4) with in situ generated silica was performed using the sol–gel reaction of tetraethoxysilane (TEOS) in latex.


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