Isothermal and non-isothermal crystallisation kinetics of pCBT and PBT

2008 ◽  
Vol 95 (1) ◽  
pp. 221-227 ◽  
Author(s):  
B. Lehmann ◽  
J. Karger-Kocsis
Polymers ◽  
2021 ◽  
Vol 13 (19) ◽  
pp. 3396
Author(s):  
Luboš Běhálek ◽  
Jan Novák ◽  
Pavel Brdlík ◽  
Martin Borůvka ◽  
Jiří Habr ◽  
...  

The physical properties and non-isothermal melt- and cold-crystallisation kinetics of poly (l-lactic acid) (PLLA) and poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) biobased polymers reprocessed by mechanical milling of moulded specimens and followed injection moulding with up to seven recycling cycles are investigated. Non-isothermal crystallisation kinetics are evaluated by the half-time of crystallisation and a procedure based on the mathematical treatment of DSC cumulative crystallisation curves at their inflection point (Kratochvil-Kelnar method). Thermomechanical recycling of PLLA raised structural changes that resulted in an increase in melt flow properties by up to six times, a decrease in the thermal stability by up to 80 °C, a reduction in the melt half-time crystallisation by up to about 40%, an increase in the melt crystallisation start temperature, and an increase in the maximum melt crystallisation rate (up to 2.7 times). Furthermore, reprocessing after the first recycling cycle caused the elimination of cold crystallisation when cooling at a slow rate. These structural changes also lowered the cold crystallisation temperature without impacting the maximum cold crystallisation rate. The structural changes of reprocessed PHBV had no significant effect on the non-isothermal crystallisation kinetics of this material. Additionally, the thermomechanical behaviour of reprocessed PHBV indicates that the technological waste of this biopolymer is suitable for recycling as a reusable additive to the virgin polymer matrix. In the case of reprocessed PLLA, on the other hand, a significant decrease in tensile and flexural strength (by 22% and 46%, respectively) was detected, which reflected changes within the biobased polymer structure. Apart from the elastic modulus, all the other thermomechanical properties of PLLA dropped down with an increasing level of recycling.


2013 ◽  
Vol 139 (1-4) ◽  
pp. 184-195 ◽  
Author(s):  
Miguel A. Bootello ◽  
Richard W. Hartel ◽  
Madeline Levin ◽  
Jose M. Martínez-Blanes ◽  
Concepción Real ◽  
...  

2007 ◽  
Vol 15 (7) ◽  
pp. 561-567
Author(s):  
Qingyuan Hu ◽  
Xiangling Ji ◽  
Yunfeng Lu

Non-isothermal crystallisation kinetics of a polyamide 6/mesoporous silica nanocomposite (PA6-MS) has been investigated by differential scanning calorimetry (DSC) at different cooling rates. Mandelkern, Jeziorny-Ziabicki and Ozawa methods were applied to describe this crystallisation process. The analyses show that the mesoporous silica particles act as nucleating agents in the composite and that the Avrami exponent n varies from 3.0 to 4.6. The addition of mesoporous silica influenced the mechanism of nucleation and the growth of polyamide 6 (PA 6) crystallites.


2007 ◽  
Vol 208 (4) ◽  
pp. 364-376 ◽  
Author(s):  
Alexandros A. Vassiliou ◽  
George Z. Papageorgiou ◽  
Dimitrios S. Achilias ◽  
Dimitrios N. Bikiaris

Nanomaterials ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 392 ◽  
Author(s):  
Ibrahim Ahmad ◽  
Hyun-Kyung Kim ◽  
Suleyman Deveci ◽  
R. Kumar

In the published paper [1], there was a typo error mistake in Equation (5), which was supposed to be expressed as “ log Z t + n log t = log K T − m log Φ ” instead of “log Zt + n log t = log KT − ml” [...]


1990 ◽  
Vol 162 (1) ◽  
pp. 179-188 ◽  
Author(s):  
M. Laus ◽  
P. Ferruti ◽  
D. Caretti ◽  
A.S. Angeloni ◽  
G. Galli ◽  
...  

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