Distribution of Alloying Elements in Carbides of Refractory Nickel Alloys under the Conditions of Equiaxial Crystallization

2021 ◽  
Author(s):  
О. А. Glotka
Author(s):  
V.N. Gadalov ◽  
A.V. Filonovich ◽  
I.V. Vornacheva ◽  
E.A. Filatov ◽  
I.A. Makarova

The positive effect of alloying elements on the thermal stability of the γ-matrix and the strengthening γ'-phase of casting nickel alloys, and consequently, on the increase in their heat-temperature strength is established. The alloying elements inhibit diffusion processes, thereby increasing the creep resistance of alloys at high temperatures and loads. It is found that the most indicative parameters of the phase composition of the test alloys are the alloying elements distribution coefficients between the γ- and γ'-phases. The basic principles of balanced alloying are formulated, on which the choice of the optimal chemical composition of heat-temperature nickel alloys is carried out.


Metallurgist ◽  
1968 ◽  
Vol 12 (5) ◽  
pp. 275-275
Author(s):  
L. N. Ermolenko

2014 ◽  
Vol 56 (3-4) ◽  
pp. 175-180
Author(s):  
N. A. Lysenko ◽  
A. A. Pedash ◽  
A. G. Kolomoitsev ◽  
E. I. Tsivirko

2021 ◽  
Vol 99 (3) ◽  
pp. 15-22
Author(s):  
O.A. Glotka ◽  
◽  
V.Yu. Olshanetskii ◽  

The aim of this work is to obtain predictive regression models, with which it is possible to adequately calculate the mechanical properties of heat-resistant nickel alloys, without prior experiments. Industrial alloys of directional crystallization of domestic and foreign production were selected for research. The values were processed by the method of least squares to obtain correlations with the receipt of mathematical equations of regression models that optimally describe these dependencies. As a result of processing of experimental data, the ratio of alloying elements which can be used for an estimation of mechanical properties taking into account complex influence of the main components of an alloy is offered for the first time. Since the dimensional mismatch of the lattice parameters is associated with the degree of concentration of solid-soluble hardening of γ- and γ'-phases, the efficiency of dispersion hardening of the alloy, creep rate and other properties, the obtained ratio allows to link these properties with multicomponent systems. Regression models are presented, with the help of which it is possible to calculate dimensional mismatch, strength, heat resistance, number of  phases and density of alloys with high accuracy. The regularities of the composition influence on the properties of heat-resistant nickel alloys of directional crystallization are established. It is shown that for multicomponent nickel systems it is possible to predict with high probability misfit, which significantly affects the strength characteristics of alloys of this class. The decrease in the value of misfit is accompanied by an increase in the solubility of the elements in the -solid solution at a value of the ratio of alloying elements of 1.5 - 1.6. However, an increase in the ratio of alloying elements greater than 2 is accompanied by an increase in misfit, because the -solid solution has reached a maximum of dissolution. The perspective and effective direction in the decision of a problem of forecasting of the basic characteristics influencing a complex of service properties of alloys both at development of new heat-resistant nickel alloys, and at perfection of structures of known industrial marks of this class is shown. Keywords: nickel-based superalloys, dimensional mismatch (γ / γ'- mismatch), strength, heat resistance.


2020 ◽  
pp. 67-79
Author(s):  
O.M. Gubanov ◽  
V.N. Gadalov ◽  
Yu.V. Skripkina ◽  
I.A. Makarova

The analysis of alloying of the chemical and phase composition of domestic and foreign cast heat-resistant alloys with a nickel matrix is carried out; the tendency to increase the level of heat-resistant properties of cast nickel alloys due to more complex alloying is traced. Recently, expensive rhenium, ruthenium, hafnium, and dysprosium have increasingly been used as alloying elements. The positive effect of these elements on the thermal stability of the γ-matrix and the strengthening γ'-phase is established. The above elements inhibit diffusion processes, thereby increasing the creep resistance of alloys at high temperatures and loads. The evaluation of heatresistant nickel alloys obtained by directional crystallization is given. It is established that the most significant parameters of the phase composition of the studied alloys are the distribution coefficients of alloying elements between the γ' and γ-phases (Ki). The basic principles of balanced alloying, which are used to select the optimal chemical composition of heat-resistant nickel alloys, are formulated. To achieve the maximum heat resistance parameters in the selected heat-resistant nickel alloys alloying system, the calculated value γ/γ' defined by “misfit” was used, which is calculated by the formula: Δа = (аγ-аγ')/ аγ, where аγ and аγ' are the lattice periods of γ and γʹ-phases. Thus, the calculated Δа should be positive for аγ> аγ' and at least two to three times more than for single-crystal heat-resistant nickel alloys with a traditional alloying system, for which Δа = (0.1-0.2) or more. It is shown that misfit (γ/γ') is mainly determined by those alloying elements that increase the аγ most significantly. These elements are Re, Pu, Mo, W, Nb, and Ta in ascending order of influence on the lattice period (аγ) of the phase.


1965 ◽  
Vol 7 (1) ◽  
pp. 11-14
Author(s):  
B. S. Natapov ◽  
V. E. Ol'shanetskii ◽  
E. P. Ponomarenko

2018 ◽  
Vol 60 (1-2) ◽  
pp. 106-114 ◽  
Author(s):  
E. N. Kablov ◽  
N. V. Petrushin ◽  
P. I. Parfenovich

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