Impact of bismuth concentration on the fluorescence properties of the bismuth borosilicate glasses

2021 ◽  
Vol 53 (7) ◽  
Author(s):  
M. Al Mahalawy ◽  
H. Farouk ◽  
A. Ratep ◽  
I. Kashif
1967 ◽  
Vol 64 ◽  
pp. 173-182 ◽  
Author(s):  
Erhard J. Schimitschek ◽  
Richard B. Nehrich Jr ◽  
John A. Trias

2000 ◽  
Vol 72 (3) ◽  
pp. 415 ◽  
Author(s):  
Joydip Das ◽  
Rosalie K. Crouch ◽  
Parkson Lee-Gau Chong

Author(s):  
Keita Nobuhara ◽  
Yusuke Inagaki ◽  
Wataru Setaka

Intramolecular charge transfer (ICT) fluorescence has been widely investigated and exploited in sensor molecules. However, steric effects on the ICT fluorescence properties have rarely been reported so far, although research...


2021 ◽  
Vol 5 (1) ◽  
Author(s):  
Christoph Lenting ◽  
Thorsten Geisler

AbstractFluid-cell Raman spectroscopy is a space and time-resolving application allowing in operando studies of dynamic processes during solution–solid interactions. A currently heavily debated example is the corrosion mechanism of borosilicate glasses, which are the favoured material for the immobilization of high-level nuclear waste. With an upgraded fluid-cell lid design made entirely from the glass sample itself, we present the polymerization of the surface alteration layer over time in an initially acidic environment, including the differentiation between pore and surface-adsorbed water within it. Our results support an interface-coupled dissolution-precipitation model, which opposes traditional ion-exchange models for the corrosion mechanism. A sound description of the corrosion mechanism is essential for reliable numerical models to predict the corrosion rate of nuclear waste glasses during long-term storage in a geological repository.


AIP Advances ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 125008
Author(s):  
Siqi Li ◽  
Yunpeng Rao ◽  
Liangliang Pan ◽  
Yongjun Chen ◽  
Xiaoyu Zhai ◽  
...  

Author(s):  
Xue-Zhen Zhang ◽  
Xiao-Feng Wang ◽  
Wei-Hui Fang ◽  
Jian Zhang

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