Effect of reactive gas condition on nonpolar AlN film growth on MnS/Si (100) by reactive DC sputtering

The effects of reactive gas flow conditions on nonpolar AlN film growth on MnS/Si (100) substrates using reactive DC magnetron sputtering were investigated. During AlN deposition at a substrate temperature of 750 °C, the MnS surface can be unintentionally nitrided, resulting in a decrease in the crystallinity of the AlN. Low temperature growth of the AlN layer at 300 °C prevents this nitridation and results in the crystallization of nonpolar AlN. A N2 flow equal to 30% of the Ar sputtering gas flow was found to improve the crystallinity of the nonpolar AlN and to reduce nitrogen defects, which play an important role in interfacial reactions. Nitrogen defects promote the formation of alloys such as AlMn and MnSi that degrade the interface and can significantly decompose the MnS. A higher proportion of N2 improves the nonpolar AlN crystallinity, reduces the concentration of defects and suppresses reactions at the AlN/MnS interface.

Characterization of Titanium-Based Films Deposited by DC Sputtering Reactive on AISI 1018 Steel

The coated surfaces first layer Ti and second layer TiO2 as coating Nanostructured thin films of using DC sputtering on structural steel (AISI l018) and study characterization of coating SEM/EDS inspection shown a clearly perfect incorporation of layer by dc sputtering a granular structure of the layer with a variable hemisphere’s forms varied from 33 to 46 nm in size. X-XRD test complete for specimen indicates was found anatase phase titanium dioxide, the resulted coating layer of the target of Ti powders gives different morphology from the Ti layer alone The Specimens roughness average of coated Ti and TiO2with respectively was 4.831nm, 7.93 nm. Found that titanium layer will show a major part in increasing the bonding with improving the bond between the substrate steel AISI (1018) and the titanium oxide layer. The Vickers hardness increases when the coating with a layer of titanium with an oxygen content of ceramic layer is formed from 192.3 HV to 227 for Ti as well as important increase was detected in the Tio2 coating to 240 HV. In addition, Ti and Tio2 thin layer considered as a good barrier for hydrogen permeation through steel structure especially at cathode protection in pipelines.

A Comparison between Silver Nanosquare Arrays and Silver Thin-Films as a Blood Cancer Prognosis Monitoring Electrode Design Using Optical and Electrochemical Characterization

The development of silver (Ag) thin films and the fabrication of Ag nanosquare arrays with the use of an anodic aluminum oxide (AAO) template and leaf extracts were successfully carried out using the DC sputtering and spin coating deposition methods. Ag thin films and Ag nanosquare arrays are developed to monitor cancer prognosis due to the correlation between serum albumin levels and prognostic factors, as well as the binding of serum albumin to the surface of these electrodes. Nanosquare structures were fabricated using AAO templates with varying diameters and a gap distance between adjacent unit cells of 100 nm. The nanosquare array with a diameter of 250 nm and irradiated with electromagnetic waves with a wavelength of around 800 nm possessed the greatest electric field distribution compared to the other variations of diameters and wavelengths. The results of the absorption measurement and simulation showed a greater shift in absorption peak wavelength when carried out using the Ag nanosquare array. The absorption peak wavelengths of the Ag nanosquare array in normal blood and blood with cancer lymphocytes were 700–774 nm and 800–850 nm, respectively. The electrochemical test showed that the sensitivity values of the Ag thin-film electrode deposited using DC sputtering, the Ag thin-film electrode deposited using spin coating, and the Ag nanosquare array in detecting PBS+BSA concentration in the cyclic voltammetry (CV) experiment were 1.308 µA mM−1cm−2, 0.022 µA mM−1cm−2, and 39.917 µA mM−1cm−2, respectively. Meanwhile, the sensitivity values of the Ag thin film and the Ag nanosquare array in detecting the PBS+BSA concentration in the electrochemical impedance spectroscopy (EIS) measurement were 6593.76 Ohm·cm2/mM and 69,000 Ohm·cm2/mM, respectively. Thus, our analysis of the optical and electrochemical characteristics of Ag thin films and Ag nanosquare arrays showed that both can be used as an alternative biomedical technology to monitor the prognosis of blood cancer based on the concentration of serum albumin in blood.

Employment of DC Sputtering for Synthesizing Nano Cadmium Oxide for Sevoflurane Anesthetic Gas Sensor

Thin films of CdO doped with AgNPs were deposited on ITO quartz substrates using DC sputtering protocol. The films were characterized using different techniques like XRD pattern for both undoped and doped one CdO NPs with silver nanoparticles, with various doping concentrations (0.4, 1.04, and 1.20) at%. It has been noticed from X-ray pattern that the nanostructured films possessed polycrystalline reflection patterns and the Prevailing orientation plane (111) on 2θ=33.35o in addition the reflection intensity increases with increasing of the doping concentration (1chip, 2chips and 3 chips) of Silver nanoparticles that chipped to the surface cadmium plate. Microstructures characterization of synthesized samples was studied using SEM. Images of SEM demonstrated that the particle size increases directly along with the number of implanting Silver NPs with three chips (1, 2 and 3) to the essential plate of Cd metal. EDXS spectroscopy counting the elemental composition using the atomic percentage, it has been demonstrated existence of silver in doped once. More, the percentage of silver content increase with increasing the number of Ag chips increases as follows The Ag content in the doped films of the cadmium metal plate with 1 attached is (1.39 wt. % for one Ag chip, 2.02 wt. % for two Ag chips while, the concentration has been increased further for three Ag chips to 3.24 at. %. Sensitivity of the manufactured device to Sevoflurane Anesthetic Gas Sensor indicates that the resistance decreases with the increase in the number of silver chips, and this is due to an increase of the pure charge carriers of the current. Keywords: Cadmium Oxide, Sliver, Structural Properties, DC reactive magnetron sputtering method, Sevoflurane Anesthetic Gas.