Bayesian strategy of accuracy estimation for characteristics retrieved from experimental data using base dynamic models of atmospheric photochemical systems

2009 ◽  
Vol 52 (9) ◽  
pp. 618-626 ◽  
Author(s):  
M. Yu. Kulikov ◽  
D. N. Mukhin ◽  
A. M. Feigin
2009 ◽  
Vol 9 (21) ◽  
pp. 8199-8210 ◽  
Author(s):  
M. Y. Kulikov ◽  
A. M. Feigin ◽  
G. R. Sonnemann

Abstract. We propose an indirect method for retrieving a number of significant minor gas constituents of the atmosphere. The technique is based on the use of so-called basic dynamic models of atmospheric photochemical systems simplified mathematically correctly in a special manner. It is applied to a mesospheric system describing day evolution of key minor gas constituents at these heights. We take as initial data experimental data of the CRISTA-MAHRSI satellite campaign of August 1997 during which ozone and hydroxyl (O3 and OH) concentrations were measured simultaneously. It is demonstrated that the use of the basic dynamic model allows retrieval of vertical distribution (within the 53–85 km range of heights) of water vapor concentration that is one of the control parameters of the mesospheric photochemistry.


2009 ◽  
Vol 9 (2) ◽  
pp. 5753-5783
Author(s):  
M. Yu. Kulikov ◽  
A. M. Feigin ◽  
G. R. Sonnemann

Abstract. We propose an indirect method for retrieving a number of significant minor gas constituents of the atmosphere. The technique is based on the use of so-called basic dynamic models of atmospheric photochemical systems simplified mathematically correctly in a special manner. It is applied to a mesospheric system describing day evolution of key minor gas constituents at these heights. We take as initial data experimental data of the CRISTA-MAHRSI satellite campaign of August 1997 during which ozone and hydroxyl (O3 and OH) concentrations were measured simultaneously. It is demonstrated that the use of the basic dynamic model allows retrieval of vertical distribution (within the 53–85 km range of heights) of water vapor concentration that is one of the control parameters of the mesospheric photochemistry.


2021 ◽  
Vol 95 (10) ◽  
pp. 2059-2064
Author(s):  
M. A. Orekhov

Abstract Molecular dynamic models are created for properties of bivalent ions in organic solvents. It is shown that molecules of the considered solvents bound to ions via oxygen atoms. A theoretical model is developed that describes the ion coordination number. The coordination number in this model is determined by the ratio between the sizes of the ion and the atom organic molecule bound to it. It is shown that the coordination number depends weakly on the solvent and strongly on the type of ion. A value of 0.13 nm is obtained for the effective size of an oxygen atom bound to a bivalent ion. The constructed theoretical model agrees with the results from molecular dynamic calculations and the available experimental data.


2019 ◽  
Vol 183 ◽  
pp. 426-436 ◽  
Author(s):  
Simone Giorgi ◽  
Josh Davidson ◽  
Morten Jakobsen ◽  
Morten Kramer ◽  
John V. Ringwood

2021 ◽  
Vol 11 (4) ◽  
pp. 1780
Author(s):  
Yechan Yun ◽  
Young Soo Chang

Refrigerant charge faults, which occur frequently, increase the energy loss and may fatally damage the system. Refrigerant leakage is difficult to detect and diagnose until the fault has reached a severe degree. Various techniques have been developed to predict the refrigerant charge amount based on steady-state operation; however, steady-state experiments used to develop prediction models for the refrigerant charge amount are expensive and time-consuming. In this study, a prediction model was established with dynamic experimental data to overcome these deficiencies. The dynamic models for the condensation temperature, degree of subcooling, compressor discharge temperature, and power consumption were developed with a regression support vector machine (r-SVM) model and start-up experimental data. The dynamic models for the condensation temperature and degree of subcooling can predict the distinct start-up characteristics depending on the refrigerant charge amount. Moreover, the estimated root mean square error (RMSE) of the condensation temperature and degree of subcooling of the test data are 0.53 and 0.84 °C, respectively. The refrigerant charge is one of the predictors that defines the dynamic characteristics. The refrigerant charge can be estimated by minimizing the RMSE of the predicted values of the dynamic models and experimental data. When the dynamic characteristics of the two predictor variables, “condensation temperature” and “degree of subcooling” are used together, the average prediction error of the test data is 2.54%. The proposed method, which uses the dynamic model during start-up operation, is an effective technique for predicting the refrigerant charge amount.


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