Dye removal using 4A-zeolite/polyvinyl alcohol mixed matrix membrane adsorbents: preparation, characterization, adsorption, kinetics, and thermodynamics

2015 ◽  
Vol 42 (6) ◽  
pp. 5309-5328 ◽  
Author(s):  
Bahareh Baheri ◽  
Raziyeh Ghahremani ◽  
Mohammad Peydayesh ◽  
Mahnaz Shahverdi ◽  
Toraj Mohammadi
Keyword(s):  
Polyvinyl Alcohol ◽  
Adsorption Kinetics ◽  
Dye Removal ◽  
Mixed Matrix Membrane ◽  
Mixed Matrix ◽  
Kinetics And Thermodynamics ◽  
4A Zeolite

Synthesis of PVDF‐B 4 C mixed matrix membrane for ultrafiltration of protein and photocatalytic dye removal

2021 ◽  
pp. 51663
Author(s):  
Yuanyuan Ouyang ◽  
Tunmise Ayode Otitoju ◽  
Dafu Jiang ◽  
Sanxi Li ◽  
Noor Fazliani Shoparwe ◽  
...  
Keyword(s):  
Dye Removal ◽  
Mixed Matrix Membrane ◽  
Mixed Matrix

scholarly journals Polyvinyl Alcohol/Calcium Carbonate Nanocomposites as Efficient and Cost-Effective Cationic Dye Adsorbents

Polymers ◽  
2020 ◽  
Vol 12 (10) ◽  
pp. 2179
Author(s):  
Davoud Jahani ◽  
Amin Nazari ◽  
Jaber Ghourbanpour ◽  
Amir Ameli
Keyword(s):  
Calcium Carbonate ◽  
Polyvinyl Alcohol ◽  
Adsorption Kinetics ◽  
Dye Removal ◽  
Dye Adsorption ◽  
Second Order ◽  
Order Kinetic ◽  
Cationic Dye ◽  
Intraparticle Diffusion Model ◽  
Pseudo Second Order

A novel polyvinyl alcohol (PVA)/calcium carbonate-based double-layer cationic dye adsorbent was developed. Polyvinyl alcohol (50 wt %) and calcium carbonate (50 wt %) were used together with borax as a cross-linking agent. The nanocomposite was prepared using only water, without the need for any toxic solvent or hazardous chemical. The final samples were obtained by the solvent casting method. The nanocomposite adsorbent was characterized using a Fourier transform infrared (FTIR) spectroscope and a scanning electron microscope (SEM). The adsorption performance on two cationic dyes, i.e., methylene blue and safranin was studied. Dye adsorption was quantified by measuring the nanocomposite swelling, contact time, and dye concentration. Pseudo first-order and pseudo second-order kinetic models as well as intraparticle diffusion model were used to model the adsorption kinetics. Moreover, the isotherm dye adsorption was investigated by Langmuir and Freundlich models. The results revealed that the developed nanocomposite has relatively high adsorption efficiency and short adsorption time and retains its performance after several successive absorption–desorption processes. The results also showed that the pseudo-second-order model best describes the adsorption kinetics, and the Freundlich isotherm model has a better compatibility with the experimental data. Finally, an adsorption mechanism was proposed for the dye removal process. The developed PVA/CaCO3 nanocomposite can be potentially used for efficient dye removal in wastewater treatments.

scholarly journals Ag-exchanged NaY zeolite introduced polyvinyl alcohol/polyacrylic acid mixed matrix membrane for pervaporation separation of water/isopropanol mixture

RSC Advances ◽  
2018 ◽  
Vol 8 (37) ◽  
pp. 20669-20678 ◽  
Author(s):  
YongSung Kwon ◽  
Shivshankar Chaudhari ◽  
ChaEun Kim ◽  
DaHae Son ◽  
JiHwan Park ◽  
...  
Keyword(s):  
Ion Exchange ◽  
Polyvinyl Alcohol ◽  
Polyacrylic Acid ◽  
Mixed Matrix Membrane ◽  
Nay Zeolite ◽  
Mixed Matrix ◽  
Aqueous Mixture ◽  
Pervaporation Separation

Ag-exchanged NaY zeolite (Ag-NaZ) particles were prepared by ion exchange and introduced to a polyvinyl alcohol (PVA) membrane cross-linked with polyacrylic acid (PAA) for the pervaporation dehydration of an isopropanol (IPA) aqueous mixture.

A polyvinyl alcohol‐based mixed matrix membrane with uniformly distributed Schiff base network‐1 for ethanol dehydration

2020 ◽  
Vol 137 (42) ◽  
pp. 49308
Author(s):  
Zhanbin Wang ◽  
Jiahao Liu ◽  
Houchao Shan ◽  
Guozhen Li ◽  
Ze Wang ◽  
...  
Keyword(s):  
Schiff Base ◽  
Polyvinyl Alcohol ◽  
Mixed Matrix Membrane ◽  
Ethanol Dehydration ◽  
Mixed Matrix ◽  
Base Network

Aqueous One-Step Modulation for Synthesizing Monodispersed ZIF-8 Nanocrystals for Mixed-Matrix Membrane

2021 ◽  
Vol 13 (9) ◽  
pp. 11296-11305
Author(s):  
Xu Jiang ◽  
Shanshan He ◽  
Gang Han ◽  
Jun Long ◽  
Songwei Li ◽  
...  
Keyword(s):  
Mixed Matrix Membrane ◽  
Mixed Matrix ◽  
One Step

Kinetics studies on free radical scavenging property of ceria in polysulfone–ceria radiation resistant mixed-matrix membrane

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Amita Bedar ◽  
Beena G. Singh ◽  
Pradip K. Tewari ◽  
Ramesh C. Bindal ◽  
Soumitra Kar
Keyword(s):  
Radical Scavenging ◽  
Radiation Environment ◽  
Mixed Matrix Membranes ◽  
Mixed Matrix Membrane ◽  
Ceria Nanoparticles ◽  
Ros Scavenging ◽  
Mixed Matrix ◽  
Stable States ◽  
Host Matrix ◽  
Γ Radiation

Abstract Cerium oxide (ceria) contains two stable states of cerium ions (Ce3+ and Ce4+). The presence of these two states and the ability to swap from one state to another (Ce3+ ↔ Ce4+) by scavenging the highly reactive oxygen species (ROS) generated from radiolysis of water, ensure the enhanced stability of polysulfone (Psf) membranes in the γ-radiation environment. In this study, the ROS scavenging ability of ceria was studied. Ceria nanoparticles were found to scavenge ROS like hydroxyl radicals and hydrogen peroxide (H2O2). The H2O2 scavenging is due to the peroxidase-like catalytic activity of ceria nanoparticles. The ROS scavenging is responsible for offering protection to the Psf host matrix and in turn the stability to the Psf-ceria mixed-matrix membranes (MMMs) in γ-radiation environment. Thus, presence of ceria nanoparticles provides an opportunity for utilizing Psf-ceria MMMs in ionizing radiation environment with increased life span, without compromise in the performance.

scholarly journals Multiple Amine-Contained POSS-Functionalized Organosilica Membranes for Gas Separation

Membranes ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 194
Author(s):  
Xiuxiu Ren ◽  
Masakoto Kanezashi ◽  
Meng Guo ◽  
Rong Xu ◽  
Jing Zhong ◽  
...  
Keyword(s):  
Gas Separation ◽  
Mixed Matrix Membranes ◽  
Mixed Matrix Membrane ◽  
Separation Performance ◽  
Hybrid Membranes ◽  
Mixed Matrix ◽  
Translation Model ◽  
Good Thermal Stability ◽  
Oligomeric Silsesquioxane

A new polyhedral oligomeric silsesquioxane (POSS) designed with eight –(CH2)3–NH–(CH2)2–NH2 groups (PNEN) at its apexes was used as nanocomposite uploading into 1,2-bis(triethoxysilyl)ethane (BTESE)-derived organosilica to prepare mixed matrix membranes (MMMs) for gas separation. The mixtures of BTESE-PNEN were uniform with particle size of around 31 nm, which is larger than that of pure BTESE sols. The characterization of thermogravimetric (TG) and gas permeance indicates good thermal stability. A similar amine-contained material of 3-aminopropyltriethoxysilane (APTES) was doped into BTESE to prepare hybrid membranes through a copolymerized strategy as comparison. The pore size of the BTESE-PNEN membrane evaluated through a modified gas-translation model was larger than that of the BTESE-APTES hybrid membrane at the same concentration of additions, which resulted in different separation performance. The low values of Ep(CO2)-Ep(N2) and Ep(N2) for the BTESE-PNEN membrane at a low concentration of PNEN were close to those of copolymerized BTESE-APTES-related hybrid membranes, which illustrates a potential CO2 separation performance by using a mixed matrix membrane strategy with multiple amine POSS as particles.

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