Dynamic Pt Coordination in Dilute AgPt Alloy Nanoparticle Catalysts Under Reactive Environments

Author(s):  
Jordan Finzel ◽  
Phillip Christopher

2013 ◽  
Vol 17 (4) ◽  
pp. 326-335 ◽  
Author(s):  
Alice Welther ◽  
Axel Jacobi von Wangelin


Author(s):  
Joakim Tafjord ◽  
Erling Rytter ◽  
Anders Holmen ◽  
Rune Myrstad ◽  
Ingeborg-Helene Svenum ◽  
...  


2013 ◽  
Vol 28 (10) ◽  
pp. 1326-1333 ◽  
Author(s):  
Zhonglai Wang ◽  
Hua Liu ◽  
Long Chen ◽  
Lingjun Chou ◽  
Xiaolai Wang

Abstract



2015 ◽  
Vol 112 (52) ◽  
pp. 15809-15814 ◽  
Author(s):  
Sheng Zhang ◽  
Peng Kang ◽  
Mohammed Bakir ◽  
Alexander M. Lapides ◽  
Christopher J. Dares ◽  
...  

Developing sustainable energy strategies based on CO2 reduction is an increasingly important issue given the world’s continued reliance on hydrocarbon fuels and the rise in CO2 concentrations in the atmosphere. An important option is electrochemical or photoelectrochemical CO2 reduction to carbon fuels. We describe here an electrodeposition strategy for preparing highly dispersed, ultrafine metal nanoparticle catalysts on an electroactive polymeric film including nanoalloys of Cu and Pd. Compared with nanoCu catalysts, which are state-of-the-art catalysts for CO2 reduction to hydrocarbons, the bimetallic CuPd nanoalloy catalyst exhibits a greater than twofold enhancement in Faradaic efficiency for CO2 reduction to methane. The origin of the enhancement is suggested to arise from a synergistic reactivity interplay between Pd–H sites and Cu–CO sites during electrochemical CO2 reduction. The polymer substrate also appears to provide a basis for the local concentration of CO2 resulting in the enhancement of catalytic current densities by threefold. The procedure for preparation of the nanoalloy catalyst is straightforward and appears to be generally applicable to the preparation of catalytic electrodes for incorporation into electrolysis devices.



2018 ◽  
Vol 301 ◽  
pp. 153-163 ◽  
Author(s):  
Nathalie Mager ◽  
Pierre Libioulle ◽  
Samuel Carlier ◽  
Sophie Hermans


2011 ◽  
Vol 13 (7) ◽  
pp. 2571 ◽  
Author(s):  
J. Chris Bauer ◽  
David Mullins ◽  
Meijun Li ◽  
Zili Wu ◽  
E. Andrew Payzant ◽  
...  


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