Synthesis, structural, and opto-electrochemical properties of cobalt aluminate type spinel and its use with ZnO for Cr(VI) photoreduction

Author(s):  
Rachida Bouallouch ◽  
Mohammed Kebir ◽  
Noureddine Nasrallah ◽  
Faouzi Saib ◽  
Atef El Jery ◽  
...  
2013 ◽  
Vol 58 (1) ◽  
pp. 95-98 ◽  
Author(s):  
M. Zielinska ◽  
J. Sieniawski

Superalloy René 77 is very wide used for turbine blades, turbine disks of aircraft engines which work up to 1050°C. These elements are generally produced by the investment casting method. Turbine blades produced by conventional precision casting methods have coarse and inhomogeneous grain structure. Such a material often does not fulfil basic requirements, which concern mechanical properties for the stuff used in aeronautical engineering. The incorporation of controlled grain size improved mechanical properties. This control of grain size in the casting operation was accomplished by the control of processing parameters such as casting temperature, mould preheating temperature, and the use of grain nucleates in the face of the mould. For nickel and cobalt based superalloys, it was found that cobalt aluminate (CoAl2O4) has the best nucleating effect. The objective of this work was to determine the influence of the inoculant’s content (cobalt aluminate) in the surface layer of the ceramic mould on the microstructure and mechanical properties at high temperature of nickel based superalloy René 77. For this purpose, the ceramic moulds were made with different concentration of cobalt aluminate in the primary slurry was from 0 to 10% mass. in zirconium flour. Stepped and cylindrical samples were casted for microstructure and mechanical examinations. The average grain size of the matrix ( phase), was determined on the stepped samples. The influence of surface modification on the grain size of up to section thickness was considered. The microstructure investigations with the use of light microscopy and scanning electron microscopy (SEM) enable to examine the influence of the surface modification on the morphology of ’ phase and carbides precipitations. Verification of the influence of CoAl2O4 on the mechanical properties of castings were investigated on the basis of results obtained form creep tests.


2020 ◽  
Author(s):  
Thomas Baumgartner ◽  
Paul Demay-Drouhard

The unexpectedly challenging synthesis of 4-pyridyl-extended dithienophospholes is reported. The optical and electrochemical properties of the phosphoryl-bridged species were studied experimentally and computationally, and their properties compared to their non-<i>P</i>-bridged congeners. The 4-pyridyl-extended dithieno-phospholes display quantitative luminescence quantum yields in solution.<br><br>


2020 ◽  
Author(s):  
Thomas Baumgartner ◽  
Paul Demay-Drouhard

The unexpectedly challenging synthesis of 4-pyridyl-extended dithienophospholes is reported. The optical and electrochemical properties of the phosphoryl-bridged species were studied experimentally and computationally, and their properties compared to their non-<i>P</i>-bridged congeners. The 4-pyridyl-extended dithieno-phospholes display quantitative luminescence quantum yields in solution.<br><br>


2016 ◽  
Vol 15 (5) ◽  
pp. 955-963 ◽  
Author(s):  
Corneliu Munteanu ◽  
Bogdan Istrate ◽  
Daniel Mareci ◽  
Sergiu Stanciu ◽  
Carmen-Iulia Crimu ◽  
...  

2014 ◽  
Vol 13 (8) ◽  
pp. 1987-1995 ◽  
Author(s):  
Liviu-Virgil Costea ◽  
Gunter Fafilek ◽  
Hermann Kronberger

2019 ◽  
Vol 24 (4) ◽  
pp. 51-58
Author(s):  
Le Hong Quan ◽  
Nguyen Van Chi ◽  
Mai Van Minh ◽  
Nong Quoc Quang ◽  
Dong Van Kien

The study examines the electrochemical properties of a coating based on water sodium silicate and pure zinc dust (ZSC, working title - TTL-VN) using the Electrochemical Impedance Spectra (EIS) with AutoLAB PGSTAT204N. The system consists of three electrodes: Ag/AgCl (SCE) reference electrode in 3 M solution of KCl, auxiliary electrode Pt (8x8 mm) and working electrodes (carbon steel with surface treatment up to Sa 2.5) for determination of corrosion potential (Ecorr) and calculation of equivalent electric circuits used for explanation of impedance measurement results. It was shown that electrochemical method is effective for study of corrosion characteristics of ZSC on steel. We proposed an interpretation of the deterioration over time of the ability of zinc particles in paint to provide cathodic protection for carbon steel. The results show that the value of Ecorr is between -0,9 and -1,1 V / SCE for ten days of diving. This means that there is an electrical contact between the zinc particles, which provides good cathodic protection for the steel substrate and most of the zinc particles were involved in the osmosis process. The good characteristics of the TTL-VN coating during immersion in a 3,5% NaCl solution can also be explained by the preservation of corrosive zinc products in the coating, which allows the creation of random barrier properties.


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