scholarly journals Assessing glyphosate in water, marine particulate matter, and sediments in the Lagoon of Venice

2021 ◽  
Author(s):  
Matteo Feltracco ◽  
Elena Barbaro ◽  
Elisa Morabito ◽  
Roberta Zangrando ◽  
Rossano Piazza ◽  
...  
Keyword(s):  
Particulate Matter ◽  
Suspended Particulate Matter ◽  
Water Environment ◽  
Venice Lagoon ◽  
Lagoon Of Venice ◽  
Agricultural Chemicals ◽  
Sediment Samples ◽  
Lagoon Water ◽  
Pollution Levels ◽  
Suspended Particulate

Abstract Lagoon water, suspended particulate matter, and sediment samples from seven sites at Lagoon of Venice were collected from 2019 to 2021 in order to study the presence of the herbicide glyphosate (N-(phosphonomethyl)glycine), among the most widely used agricultural chemicals worldwide, but its occurrence in lagoon water environment has not been deeply investigated. The sites were selected considering a supposed diversity of inputs and of pollution levels. An analytical method based on ion chromatography coupled with tandem mass spectrometry was optimized and validated for lagoon water, marine particulate matter, and sediment samples. Maximum concentrations of glyphosate were 260 and 7 ng L−1 for lagoon water and suspended particulate matter, respectively, and 15 ng g−1 for sediment, with some spatial and temporal fluctuations. Our results demonstrate that glyphosate content in the Venice Lagoon mainly depends on external forcing from river inlets and agricultural lagoon activities.

scholarly journals A Reliable and Cost-Effective Method for Determination of Endocrine-Disrupting Compounds in Coastal Waters, Suspended Particulate Matter, and Sediments by Ultrafast Liquid Chromatography Coupled to Photodiode Array and Fluorescence Detectors

2021 ◽  
Author(s):  
Gabriel de Souza ◽  
Cristiane Fahning ◽  
Vanessa Hatje ◽  
Gisele da Rocha
Keyword(s):  
Liquid Chromatography ◽  
Particulate Matter ◽  
Suspended Particulate Matter ◽  
Coastal Waters ◽  
Endocrine Disrupting Compounds ◽  
Northeastern Brazil ◽  
Sediment Samples ◽  
Suspended Particulate ◽  
Endocrine Disrupting ◽  
Photodiode Array

Analytical methods for determining 14 endocrine-disrupting compounds (EDCs) in coastal waters, suspended particles, and sediment samples were successfully performed by ultrafast liquid chromatography with photodiode array and fluorescence detections (UFLC-PDA-FLD). Solid‑phase extraction (SPE) and ultrasound-assisted extraction (USE) were used for sample preparation. Two chromatographic methods have been developed. An isocratic separation method was used to separate bisphenol A (BPA) and steroids and another gradient elution method to separate phthalates and alkylphenols. The detection by fluorescence was used for alkylphenols, BPA, and steroids and photodiode array (PDA) for phthalates. Limits of detection (LOD) ranged from 0.41 (4-tert-octylphenol (4tOP)) to 63 ng L-1 (dibutylphthalate (DBP)), 0.41 (4tOP) to 63.2 ng g-1 dried weight (dw) coastal waters, and solid samples (suspended particulate matter (SPM) and sediment samples), respectively. Recoveries ranged from 52 (diethylphthalate (DEP)) to 116% (DBP) for water, from 54 (DEP) to 108% (estrone (E1)) for SPM, and from 62 (4-n-nonylphenol (4nNP)) to 117% (4-n-octylphenol (4nOP)) for sediment samples. Finally, with the minimization of reagents and energy, the proposed methods were applied to samples collected from Todos os Santos Bay (BTS), Bahia, Northeastern Brazil.

Physical and bacterial processes affecting suspended particulate matter in a tidal river

1998 ◽  
Vol 38 (6) ◽  
pp. 327-335
Author(s):  
Yasunori Kozuki ◽  
Yoshihiko Hosoi ◽  
Hitoshi Murakami ◽  
Katuhiro Kawamoto
Keyword(s):  
Particle Size ◽  
Particulate Matter ◽  
Suspended Particulate Matter ◽  
River Mouth ◽  
Tidal River ◽  
Natural Soil ◽  
Size Change ◽  
Run Off ◽  
Suspended Particulate ◽  
And Behavior

In order to clarify the origin and behavior of suspended particulate matter (SPM) in a tidal river, variation of SPM in a tidal river was investigated with regard to its size and constituents. SPM was separated into three groups according to size. Change of contents of titanium and organic substances of each group of SPM was examined. SPM which was discharged by run-off was transported with decomposition and sedimentation in a tidal river. Concentration of SPM with a particle size greater than 0.45 μm increased due to resuspension in a tidal river. Origin of SPM with a size of less than 0.45 μm at upstream areas was from natural soil and most of such SPM which had been transported settled near a river mouth. It was determined from examination of the CN ratio and the ratio of the number of attached bacteria to free bacteria that SPM with a size greater than 1.0 μm at upstream areas was decomposing intensively. At the downstream areas, SPM with a size of less than 0.45 μm came from the sea. SPM with particle size greater than 1.0 μm consisted of plankton and substances which were decomposed sufficiently while flowing.

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