Reduction Kinetics of Fe-based Oxygen Carriers Using Syngas in a Honeycomb Fixed-Bed Reactor for Chemical-Looping Combustion

2019 ◽  
Vol 29 (1) ◽  
pp. 13-24 ◽  
Author(s):  
Xiangyu Liu ◽  
Hao Zhang ◽  
Hui Hong
2006 ◽  
Vol 45 (1) ◽  
pp. 157-165 ◽  
Author(s):  
Beatriz M. Corbella ◽  
Luis F. de Diego ◽  
Francisco García-Labiano ◽  
Juan Adánez ◽  
José M. Palacios

2005 ◽  
Vol 19 (2) ◽  
pp. 433-441 ◽  
Author(s):  
B. M. Corbella ◽  
L. De Diego ◽  
F. García ◽  
J. Adánez ◽  
J. M. Palacios

2007 ◽  
Vol 21 (4) ◽  
pp. 1843-1853 ◽  
Author(s):  
Alberto Abad ◽  
Francisco García-Labiano ◽  
Luis F. de Diego ◽  
Pilar Gayán ◽  
Juan Adánez

2016 ◽  
Vol 872 ◽  
pp. 196-200
Author(s):  
Sujinda Thongsermsuk ◽  
Benjapon Chalermsinsuwan ◽  
Prapan Kuchonthara ◽  
Pornpote Piumsomboon

Fe2O3/Al2O3/ZnO oxygen carriers with small content ZnO (5 wt% to 10 wt%) were prepared by physical mixing method and were evaluated its capability as an oxygen carrier in a chemical looping combustion. The combustion was conducted by using CH4 as a fuel gas. The reduction process of Fe2O3/Al2O3/ZnO oxygen carrier was carried out in a fixed bed reactor. The solid reduction products were characterized by X-ray diffraction (XRD) and Scanning Electron Microscope with EDS Attachment (SEM-EDS). The results show that the reactivity of Fe2O3/Al2O3/ZnO oxygen carriers is greater than that of Fe2O3/Al2O3 which is implied the synergetic effect between ZnO and Fe2O3. XRD results show that the iron oxide in the oxygen carriers is reduced to metallic iron. SEM-EDS also shows that the iron agglomeration is prevented. Consequently, the suitable content of ZnO in oxygen carriers is ranged from 5 wt% to 10 wt%.


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