Phase Evolution Behavior and Oxidation Induration Mechanism of High-Chromium Vanadium–Titanium Magnetite Flux Pellets

2021 ◽  
Author(s):  
Bojian Chen ◽  
Jing Wen ◽  
Tao Jiang ◽  
Lin Li ◽  
Guangdong Yang ◽  
...  
Keyword(s):  
Phase Evolution ◽  
High Chromium ◽  
Vanadium Titanium ◽  
Evolution Behavior ◽  
Titanium Magnetite

Phases Transition and Consolidation Mechanism of High Chromium Vanadium-Titanium Magnetite Pellet by Oxidation Process

2016 ◽  
Vol 35 (7) ◽  
pp. 729-738
Author(s):  
Jue Tang ◽  
Man-sheng Chu ◽  
Cong Feng ◽  
Feng Li ◽  
Zheng-gen Liu
Keyword(s):  
Phase Transition ◽  
Oxidation Process ◽  
Consolidation Process ◽  
High Chromium ◽  
Oxidized Pellet ◽  
Three Stages ◽  
Roasting Temperature ◽  
Vanadium Titanium ◽  
Roasting Time ◽  
Titanium Magnetite

AbstractBased on the fundamental characteristics of high chromium vanadium-titanium magnetite (HCVTM), the effects of roasting temperature and roasting time on the phase transition and oxidation consolidation during the oxidation were investigated systematically. It was shown that the oxidation of HCVTM pellet was not a simple process but complex. With increasing roasting temperature and time, the compressive strength of oxidized pellet was improved. The phase transition during oxidation was hypothesized to proceed as follows: (1) Fe3O4 → Fe2O3; (2) Fe2.75Ti0.25O4 → Fe9TiO15 + FeTiO3 → Fe9TiO15 + Fe2Ti3O9; (3) Fe2VO4 → V2O3 → (Cr0.15V0.85)2O3; (4) FeCr2O4 → Cr2O3 → Cr1.3Fe0.7O3 + (Cr0.15V0.85)2O3. The oxidation consolidation process was divided into three stages: (1)oxidation below 1,173 K; (2) recrystallization consolidation at 1,173 – 1,373 K; (3) particle refining recrystallization-consolidation by the participation of liquid phase at 1,373 – 1,573 K. To obtain the HCVTM oxidized pellet with good quality, the rational roasting parameters included a roasting temperature of 1,573 K and a roasting time of 20 min.

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