scholarly journals Purification of recovered phosphoric acid by extracting aluminium with di-2-ethylhexyl phosphoric acid

2021 ◽  
Author(s):  
Sini Reuna ◽  
Ari Väisänen
Keyword(s):  
Phosphoric Acid ◽  
Sulphuric Acid ◽  
Organic Phase ◽  
Real Life ◽  
Phosphoric Acid Solution ◽  
Extractant Concentration ◽  
Wastewater Treatment Process ◽  
Optimized Conditions ◽  
Composite Face ◽  
Stripping Efficiency

AbstractThe extraction of aluminium from dilute phosphoric acid with di-2-ethylhexyl phosphoric acid (DEHPA) was optimized using response surface methodology. The optimization was based on the experimental three-level central composite face-centred design (CCF) and was conducted on real-life samples. The three variables included were pH, extractant concentration and aqueous to organic phase ratio (AO). Under the optimized conditions (pH 2.5, 0.6 M DEHPA and AO ratio 1:2), extraction efficiency of 99% for aluminium in four extraction stages is achieved. The purified phosphoric acid solution can then be utilized by the fertilizing industry. Stripping tests for organic phase loaded with aluminium were conducted with sulphuric acid. Extremely high stripping efficiency was obtained with 0.9 M sulphuric acid resulting in the recovery rate of 88% in one stage. After stripping, the aluminium sulphate solution can be reused as a precipitation agent for phosphorus in the wastewater treatment process.

Electropolishing of horizontal copper cylinders in unstirred phosphoric acid solution

1978 ◽  
Vol 7 (4) ◽  
pp. 313-318 ◽  
Author(s):  
I.A.S. Mansour ◽  
G.H. Sedahmed ◽  
M.Z. El-Abd ◽  
A.M. Ahmed
Keyword(s):  
Phosphoric Acid ◽  
Acid Solution ◽  
Phosphoric Acid Solution

scholarly journals Kinetic Modelling and Optimizing of Butyl Propionate over a Synthesied Material (Tungstan Phosphoric Acid) Heteropoly Catalyst Using Response Surface Technique

2021 ◽  
Vol 45 (4) ◽  
pp. 273-280
Author(s):  
Raju Kalakuntala ◽  
Srinath Surnani
Keyword(s):  
Experimental Data ◽  
Phosphoric Acid ◽  
Response Surface ◽  
Kinetic Modelling ◽  
Quadratic Model ◽  
Molar Ratio ◽  
Catalyst Loading ◽  
Response Surface Technique ◽  
Optimized Conditions ◽  
Surface Technique

The performance of heteropoly acid i.e., Tungstan phosphoric acid for the synthesis of butyl propionate at optimized conditions. Effect on conversion and yield of propionic acids using the Response Surface Methodology (RSM) were evaluated by different process parameters including catalyst loading, alcohol/acid molar ratio. There were no external and internal mass transmission limits. A quadratic model acquired by the variance study (ANOVA) has been shown to view experimental data successfully with the regression (R2 = 0.94 and R2 = 0.942) coefficients approaching to unity. The pseudo homogeneous kinetic model (PH) validated with experimental data to determine kinetic parameters i.e., activation energy (45.97 kJ/mol) and frequent factor (91319 L/mol-min).

Evaluation of environmentally friendly inhibitor for corrosion of mild steel in phosphoric acid solution: unconventional approach

2018 ◽  
Vol 65 (5) ◽  
pp. 506-514 ◽  
Author(s):  
Khalid Rashid ◽  
Anees Khadom
Keyword(s):  
Corrosion Rate ◽  
Phosphoric Acid ◽  
Acid Solution ◽  
Mild Steel ◽  
Design Method ◽  
Correlation Coefficients ◽  
Environmentally Friendly ◽  
Phosphoric Acid Solution ◽  
Content Type ◽  
Phenolic Components

PurposeThe purpose of this study is to investigate the corrosion inhibition of mild steel alloy in 2 M H3PO4solution by the pomegranate peel extract as a friendly inhibitor was studied at various temperatures, inhibitor concentrations and immersion times.Design/methodology/approachA weight loss method was used to evaluate the corrosion rate. The experimental Taguchi design method was used for the distribution of experiments. The experimental design gave results which were impossible to show graphically. However, this problem was solved effectively with the aid of regression analysis.FindingsCorrosion rate increased with temperature according to Arrhenius equation. It was found that the efficiency of inhibition was increased with an increase in the concentration of inhibitor and immersion time. However, this diminishes with increased temperature. According to Langmuir isotherm, the inhibitor was adsorbed physically on steel surface. The negative sign of estimated heat of adsorption suggests a stable spontaneous inhibition process. Combination of mathematical and statistical analysis was proposed to demonstrate the results of corrosion rate with high correlation coefficients. In addition, Fourier transform infrared spectrometer examinations confirmed that the organic inhibitor consists of phenolic components as main materials.Originality/valueUsing unconventional approach for evaluation of environmentally friendly inhibitor for corrosion of mild steel in phosphoric acid solution.

scholarly journals Electrochemical Oscillations during Electro-oxidation of Copper Anode in Phosphoric Acid Solution

2019 ◽  
Vol 87 (1) ◽  
pp. 14-19 ◽  
Author(s):  
Lifeng DING ◽  
Peng WU ◽  
Jun CHENG ◽  
Yulan NIU ◽  
Zhengwei SONG ◽  
...  
Keyword(s):  
Phosphoric Acid ◽  
Acid Solution ◽  
Phosphoric Acid Solution ◽  
Copper Anode ◽  
Electro Oxidation
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