Adsorption equilibrium and kinetic studies of crystal violet and naphthol green on torreya-grandis-skin-based activated carbon

2014 ◽  
Vol 32 (2) ◽  
pp. 335-341 ◽  
Author(s):  
Wei Dai ◽  
Huijing Yu ◽  
Na Ma ◽  
Xiaoyang Yan
2019 ◽  
Vol 31 (8) ◽  
pp. 1667-1674
Author(s):  
Roy George

Adsorption equilibrium and kinetics studies of effect of ortho-substituted benzoic acid in aqueous phase using granular activated carbon were investigated. The granular activated carbon (GAC) obtained from bituminous type coal having a surface area of 998 m2/g and loosely bounded and open pores morphology. The adorbates selected for this study was benzoic acid and its ortho-derivatives namely; salicylic acid, phthalic acid and o-toluic acid. The solubility of adsorbate in solvent affected the adsorption behaviour more pronouncly. The order of adsorption for adsorbates was found to be as: benzoic acid > salicylic acid > o-toluic acid > phthalic acid.


2012 ◽  
Vol 27 (2) ◽  
pp. 139-145 ◽  
Author(s):  
Dong XU ◽  
Jun ZHANG ◽  
Gang LI ◽  
Penny XIAO ◽  
Paul WEBLEY ◽  
...  

Author(s):  
Taher Selmi ◽  
Ghizlane Enaime ◽  
Aïda Kesraoui ◽  
Abdelaziz Baçaoui ◽  
Mongi Seffen

1997 ◽  
Vol 35 (7) ◽  
pp. 261-268 ◽  
Author(s):  
Kazuyuki Chihara ◽  
Kanji Oomori ◽  
Takao Oono ◽  
Yosuke Mochizuki

Supercritical CO2 regeneration is one of the possibilities for spent carbon regeneration loaded with some organics. Here, adsorption equilibrium and adsorption dynamics were evaluated for some typical organic pollutants under some supercritical CO2 conditions. A supercritical CO2 chromatograph packed with activated carbon (F-400, CAL) was used to detect the pulse responses of organics, which were analyzed by moment analysis. Adsorption equilibrium constants of some organics varied with CO2 density and their boiling points. Possibility of regeneration of each substance was discussed. Cost estimation was necessary and was the key point of this technique.


2018 ◽  
Vol 2018 ◽  
pp. 1-12 ◽  
Author(s):  
Lingjie Liu ◽  
Min Ji ◽  
Fen Wang

Coconut granular activated carbon (CGAC) was modified by impregnating with ZnCl2solution to remove nitrate from aqueous solutions. Sorption isotherm and kinetic studies were carried out in a series of batch experiments. Nitrate adsorption of both ZnCl2-modified CGAC and CGAC fitted the Langmuir and Freundlich models. Batch adsorption isotherms indicated that the maximum adsorption capacities of ZnCl2-modified CGAC and CGAC were calculated as 14.01 mgN·g−1and 0.28 mgN·g−1, respectively. The kinetic data obtained from batch experiments were well described by pseudo-second-order model. The column study was used to analyze the dynamic adsorption process. The highest bed adsorption capacity of 1.76 mgN·g−1was obtained by 50 mgN·L−1inlet nitrate concentration, 20 g adsorbents, and 10 ml·min−1flow rate. The dynamic adsorption data were fitted well to the Thomas and Yoon–Nelson models with coefficients of correlationR2 > 0.834 at different conditions. Surface characteristics and pore structures of CGAC and ZnCl2-modified CGAC were performed by SEM and EDAX and BET and indicated that ZnCl2had adhered to the surface of GAC after modified. Zeta potential, Raman spectra, and FTIR suggested the electrostatic attraction between the nitrate ions and positive charge. The results revealed that the mechanism of adsorption nitrate mainly depended on electrostatic attraction almost without any chemical interactions.


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