scholarly journals Source rock potential assessment of the Paleocene coal and coaly shale in the Attock-Cherat Range of Pakistan

2021 ◽  
Vol 11 (6) ◽  
pp. 2299-2313
Author(s):  
Khalid Latif ◽  
Muhammad Hanif ◽  
Syed Anjum Shah ◽  
Irfan U. Jan ◽  
Muhammad Younis Khan ◽  
...  
Keyword(s):  
Oxygen Index ◽  
Vitrinite Reflectance ◽  
Geochemical Data ◽  
Hydrocarbon Generation ◽  
Visual Examination ◽  
Terrestrial Environment ◽  
Hydrocarbon Generation Potential ◽  
Geochemical Parameters ◽  
Rock Eval ◽  
Reflectance Measurements

AbstractIn this study the hydrocarbon generation potential of the coal and coaly shale samples collected from coal mines in Attock-Cherat Range of Pakistan is optically and analytically evaluated. These samples, representing the Paleocene Hangu Formation, are analyzed across a range of thermal maturity stages to understand their hydrocarbon generation potential. The visual examination of maceral type and values of vitrinite reflectance have been considered while interpreting the geochemical results for the coal and associated sediments from the Paleocene Hangu Formation. The maceral group is dominated by vitrinite, mainly collodetrinite, followed by inertinite and liptinite, and suggests Type III kerogen for the samples. The geochemical parameters suggest that the samples are post mature, however, the vitrinite reflectance measurements show late mature conditions for a gas-prone generation. The overall petrographical and geochemical data suggest that the coal and coaly shale appear to occupy the gas window and fall in the dry gas zone. Based on the maceral types and Rock–Eval data, an anoxic to terrestrial environment is inferred for the deposition of the coal and associated sediments. The vitrinite reflectance, Rock–Eval pyrolysis, and the type and frequency of macerals show that the coal is of good quality, i.e., medium to high volatile bituminous and hard brown coal, mature, and is lying in the gas window. Oxygen index is continuously low throughout the analyzed interval, which further supports that the coal is of good quality.

GEOLOGY, SOURCE ROCKS AND HYDROCARBON GENERATION IN THE CLARENCE-MORETON BASIN

1982 ◽  
Vol 22 (1) ◽  
pp. 5
Author(s):  
A. R. Martin ◽  
J. D. Saxby
Keyword(s):  
Vitrinite Reflectance ◽  
Source Rocks ◽  
Geochemical Data ◽  
Hydrocarbon Potential ◽  
Hydrocarbon Generation ◽  
Tectonic Events ◽  
History Of ◽  
Rock Eval ◽  
Coal Measures ◽  
Migration Pathways

The geology and exploration history of the Triassic-Cretaceous Clarence-Moreton Basin are reviewed. Consideration of new geochemical data ('Rock-Eval', vitrinite reflectance, gas chromatography of extracts, organic carbon and elemental analysis of coals and kerogens) gives further insights into the hydrocarbon potential of the basin. Although organic-rich rocks are relatively abundant, most source rocks that have achieved the levels of maturation necessary for hydrocarbon generation are gas-prone. The exinite-rich oil-prone Walloon Coal Measures are in most parts relatively immature. Some restraints on migration pathways are evident and igneous and tectonic events may have disturbed potentially well-sealed traps. Further exploration is warranted, even though the basin appears gas-prone and the overall prospects for hydrocarbons are only fair. The most promising areas seem to be west of Toowoomba for oil and the Clarence Syncline for gas.

scholarly journals Use of petrological and organic geochemical data in determining hydrocarbon generation potential of coals: miocene coals of Malatya Basin (Eastern Anatolia-Turkey)

2020 ◽  
Author(s):  
Nazan Yalcin Erik ◽  
Faruk Ay
Keyword(s):  
Organic Matter ◽  
Vitrinite Reflectance ◽  
Hydrogen Index ◽  
Quality Data ◽  
Geochemical Data ◽  
Mineral Matter ◽  
Hydrocarbon Generation ◽  
Thermal Maturity ◽  
Hydrocarbon Generation Potential ◽  
Northern District

AbstractWith this study, the hydrocarbon generation potential of Miocene aged coals around Arguvan-Parçikan in the northern district of Malatya province was evaluated with the aid of petrological and organic geochemical data. According to organic petrography, coal quality data, and low thermal maturity, the Arguvan-Parçikan coals are of high-ash, high-sulfur subbituminous B/C rank. The organic fraction of the coals is mostly comprised of humic group macerals, with small percentages derived from the inertinite and liptinite groups. The mineral matter of the coals is comprised mainly of calcite and clay minerals. The total organic carbon (TOC, wt%) values of the shale and coal samples are between 2.61 wt% and 43.02 wt%, and the hydrogen index values are between 73 and 229 mg HC/g TOC. Pyrolysis (Tmax, PI), huminite/vitrinite reflectance (Ro, %), and biomarker ratios (CPI, Pr/Ph ratio, Ts/(Ts + Tm) ratio, C32 homohopane ratio (22S/22S + 22R) and C29ββ/(ββ + αα sterane ratio) indicate that the organic matter of the studied coals is thermally immature. When all these data are taken together, Miocene aged coals around Arguvan are suitable for hydrocarbon generation, especially gas, in terms of organic matter type (Type III and Type II/III mixed), organic matter amount (> 10 wt% TOC), however, low liptinitic macerals (< 15%–20%), low hydrogen index (< 200 mg HC/g TOC) and low thermal maturity values inhibit the hyrocarbon generation.

Biomarker Geochemistry and Hydrocarbon Generation Potential of the Evaporites in Dongying Lacustrine Basin

2012 ◽  
Vol 616-618 ◽  
pp. 1042-1047
Author(s):  
Zhong Hong Chen
Keyword(s):  
Organic Matter ◽  
Hydrocarbon Generation ◽  
Lacustrine Basin ◽  
Hydrocarbon Generation Potential ◽  
Deep Wells ◽  
Generating Capacity ◽  
High Maturity ◽  
Different Response ◽  
Hydrocarbon Expulsion ◽  
Rock Eval

To investigate hydrocarbon potential of the evaporites, some deep wells such as Haoke-1 well and Fengshen-2 well were intensively cored, tested by TOC, Rock-Eval, and chromatography and mass spectrometry and evaluated using geochemistry of biomarker and hydrocarbon generation. High content of gammacerane and low Pr/Ph was exhibited in the evaporite system compared to the non-evaporite system. Different response of biomarkers parameters for the different sedimentary systems was exhibited, such as C19/(C19+C23) terpanes, C29/(C27+C28+C29) steranes, C24/C23 and C22/C21 tricyclic terpane. The evaporites and mud stones have the capacity to generate and expel hydrocarbons. The tested samples were mostly typeⅠand typeⅡ1 of organic matter, and their original generating capacity can reach 40 mg/g rock and 20 mg/g rock respectively. The efficiency of hydrocarbon expulsion reached 60%, but the distribution of organic matter and its generative potential was highly variable. In general, the mudstones show greater generative potential than the evaporites. High maturity severely reduced the capacity of their rocks to generate and expel petroleum.

scholarly journals Particle-Size Fractionation and Thermal Variation of Oil Shales in the Songliao Basin, NE China: Implication for Hydrocarbon-Generated Process

Energies ◽  
2021 ◽  
Vol 14 (21) ◽  
pp. 7191
Author(s):  
Jianliang Jia ◽  
Zhaojun Liu
Keyword(s):  
Particle Size ◽  
Vitrinite Reflectance ◽  
Thermal Analyses ◽  
Songliao Basin ◽  
Particle Analysis ◽  
Hydrocarbon Generation ◽  
Particle Sizes ◽  
Thermal Variation ◽  
Hydrocarbon Generation Potential ◽  
Oil Shales

The synchronous variation and association of organic matter (OM) and minerals in the hydrocarbon-generated process of oil shales are poorly understood. The goal of the paper is to investigate OM occurrence and thermal variation so as to reveal the hydrocarbon generation potential of oil shales. Based on detailed analyses of particle, organic, mineral, and thermal data from lacustrine oil shales in the Songliao Basin, we observed three layers of shale particles after settling in the water column characterized by a distinct color, degree of consolidation, and particle size. The particle sizes are divided into three ranges of fine grain (<1 μm), medium grain (1–20 μm), and coarse grain (>20 μm) via laser particle analysis. The particle-size distribution indicates the presence of OM polymerization and dominant contribution of the associated mineral surface and bioclastic OMs to the OM abundance of oil shale. Various OM occurrences are influenced by OM sources and redox conditions, whereas the degree of biodecomposition and particle sizes affect the placement of OM occurrences. Based on multiple thermal analyses, a synchronous response of OM and minerals to thermal variation dominates at 300–550 °C. The I/S and chlorite minerals are characterized by an entire illitization, while solid/absorbed OMs and hydrocarbon-generated water were expelled in large quantities. This contributes to major loss weights of oil shales during heating. The peak hydrocarbon-generated rate occurred at 457 °C for oil shales, corresponding to around 1.3% vitrinite reflectance value. These results are suggested to improve the understanding of OM occurrences and the thermal degradation constraint on the hydrocarbon-generated process, and contribute to the interpretation of the hydrocarbon generation potential and in-situ exploitation of oil shales.

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