Idealized collision model for reactive scattering: Energy dependence of the cross section for CH3I + K → CH3 + Kl

1975 ◽  
Vol 34 (3) ◽  
pp. 546-551 ◽  
Author(s):  
Hyung Kyu Shin
1991 ◽  
Vol 176 (6) ◽  
pp. 499-503 ◽  
Author(s):  
Qi-Xun Xu ◽  
R. Scott Mackay ◽  
F.J. Aoiz ◽  
Mark A. Quesada ◽  
Patrick J. Grunberg ◽  
...  

1961 ◽  
Vol 23 ◽  
pp. 513-517 ◽  
Author(s):  
L. Keszthelyi ◽  
I. Berkes ◽  
I. Demeter ◽  
I. Fodor

1984 ◽  
Vol 81 (12) ◽  
pp. 5725-5729 ◽  
Author(s):  
V. Saez Rabanos ◽  
E. Verdasco ◽  
V. J. Herrero ◽  
A. Gonzalez Ureña

1985 ◽  
Vol 63 (10) ◽  
pp. 1274-1277
Author(s):  
R. J. W. Hodgson

A prescription for separating the elastic cross section into its coherent and incoherent parts is used to gain more information about the excitation function at 90° and at 180°. Approximations become useless over most of the energy range owing to the extreme sensitivity of the cross section. Despite the apparent smooth energy dependence of the coherent and incoherent parts, interpolation does not generate the observed structure in the excitation functions.


1982 ◽  
Vol 60 (7) ◽  
pp. 981-987 ◽  
Author(s):  
B. Hird ◽  
S. P. Ali

The cross section for electron capture by Kr+ ions from rare gas atoms between 30 and 120 keV is found to be in good agreement with previous measurements where these exist, except for neon. The Rapp–Francis model gives an acceptable fit to the energy dependence of these and higher energy data but is too large by a factor of about five. In contrast the Landau–Zener model predictions are too large for helium and neon and too small for the heavier targets unless metastable states of krypton with large polarizabilities dominate the cross section.


The electric octupole excitation of the 40 keV isomeric state in 103 Rh has been observed with protons of energies 700 to 1200 keV. The energy dependence of the cross-section is consistent with that predicted by the W. K. B. treatment of Alder & Winther. The absolute cross-section is about three times that expected theoretically. Possible explanations for this discrepancy are suggested.


Author(s):  
S. Stu¨bing ◽  
M. Dietzel ◽  
M. Sommerfeld

For modeling agglomeration processes in the frame of the Lagrangian approach, where the particles are treated as point masses, an extended structure model was developed. This model provides not only information on the number of primary particles in the agglomerate, but also on the geometrical distension of the agglomerates. These are for example the interception diameter, the radius of gyration, the fractal dimension and the porosity of the agglomerate using the convex hull. The question however arises now, which is the proper agglomerate cross-section for the calculation of the drag force. In order to find an answer, the Lattice-Boltzmann-Method (LBM) was applied for simulating the flow about fixed agglomerates of different morphology and number of primary particles involved. From these simulations the drag coefficient was determined using different possible cross-sections of the agglomerate. Numerous simulations showed that the cross-section of the convex hull yields a drag coefficient which is almost independent on the structure of the agglomerate if they have the same cross-sectional area in flow direction. Using the cross-section of the volume equivalent sphere showed a very large scatter in the simulated drag coefficient. This information was accounted for in the Lagrangian agglomeration model. The basis of modeling particle collisions and possible agglomeration was the stochastic inter-particle collision model accounting for the impact efficiency. The possibility of particle sticking was based on a critical velocity determined from an energy balance which accounts for dissipation and the van der Waals adhesion. If the instantaneous relative velocity between the particles is smaller than this critical velocity agglomeration occurs. In order to allow the determination of the agglomerate structure reference vectors are stored between a reference particle and all other primary particles collected in the agglomerate. For describing the collision of a new primary particle with an agglomerate the collision model was extended in order to determine which primary particle in the agglomerate is the collision partner. For demonstrating the capabilities of the Lagrangian agglomerate structure model the dispersion and collision of small primary particles in a homogeneous isotropic turbulence was considered. From these calculations statistics on the properties of the agglomerates were made, e.g. number of primary particles, radius of gyration, porosity, sphericity and fractal dimension. Finally, the dispersion of particles in vertical grid turbulence was calculated by the Lagrangian approach. For one selected model agglomerate, dispersion calculations were performed with different possible characteristic cross-sections of the agglomerate. These calculations gave a deviation of the mean square dispersion of up to 20% after a dispersion time of 0.4 seconds for the different cross-sections. This demonstrates that a proper selection of the cross-section is essential for calculating agglomerate motion in turbulent flows.


1985 ◽  
Vol 437 (3-4) ◽  
pp. 630-642 ◽  
Author(s):  
B. Mayer ◽  
R. Bertini ◽  
J.M. Cameron ◽  
H. Catz ◽  
J.M. Durand ◽  
...  

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