Higher-order spectral moments in collision-induced absorption. Inert gas mixtures

1983 ◽  
Vol 95 (4-5) ◽  
pp. 430-434 ◽  
Author(s):  
Z. Gburski ◽  
C.G. Gray ◽  
D.E. Sullivan
Keyword(s):  
Gas Mixtures ◽  
Higher Order ◽  
Inert Gas ◽  
Spectral Moments ◽  
Induced Absorption

Collision-Induced Absorption in Alkali-Metal-Atom—Inert-Gas Mixtures

1973 ◽  
Vol 7 (5) ◽  
pp. 1606-1609 ◽  
Author(s):  
C. Bottcher ◽  
A. Dalgarno ◽  
E. L. Wright
Keyword(s):  
Alkali Metal ◽  
Metal Atom ◽  
Alkali Metal Atom ◽  
Gas Mixtures ◽  
Inert Gas ◽  
Induced Absorption

Collision Induced Microwave Absorption in N2, CH4, and N2–Ar, N2–CH4 Mixtures at 1.1 and 2.3 cm−1

1974 ◽  
Vol 52 (9) ◽  
pp. 821-829 ◽  
Author(s):  
I. R. Dagg ◽  
G. E. Reesor ◽  
J. L. Urbaniak
Keyword(s):  
Microwave Absorption ◽  
Quadrupole Moment ◽  
Linear Dependence ◽  
Relaxation Times ◽  
High Sensitivity ◽  
Higher Order ◽  
Induced Absorption ◽  
High Q ◽  
Order Dependence

Collision induced microwave absorption is reported in pure N2, N2–Ar, N2–CH4, mixtures, and in pure CH4 in the 35 and 70 GHz regions (1.1 and 2.3 cm−1) at a temperature of 22 °C. The measurements are accomplished using overmoded high Q cavities capable of pressurization of up to 5000 p.s.i.g. The apparatus and method are described. With the high sensitivity attained, the results in pure N2 from 30 → 250 amagat reveal terms in the square and cube of the density from which the relaxation times are calculated. The linear dependence on frequency of the collision induced absorption up to 2.3 cm−1 is established. Higher order dependence on the density is observed in the N2–Ar and N2–CH4 mixtures. Various estimates of the quadrupole moment of N2 are given, making use of earlier results in other frequency regions.

Conductivity of a photoplasma of sodium vapor-inert gas mixtures

1999 ◽  
Vol 27 (1) ◽  
pp. 182-192 ◽  
Author(s):  
N.A. Gorbunov ◽  
A.S. Melnikov ◽  
I.A. Movtchan ◽  
I. Smurov ◽  
G. Flamant
Keyword(s):  
Gas Mixtures ◽  
Inert Gas ◽  
Sodium Vapor

COLLISION-INDUCED ABSORPTION OF COMPRESSED GASES IN THE FAR INFRARED, PART I

1965 ◽  
Vol 43 (5) ◽  
pp. 729-750 ◽  
Author(s):  
D. R. Bosomworth ◽  
H. P. Gush
Keyword(s):  
Fourier Analysis ◽  
Infrared Absorption ◽  
Michelson Interferometer ◽  
Far Infrared ◽  
Gas Mixtures ◽  
Experimental Techniques ◽  
Rare Gas ◽  
Absorption Coefficients ◽  
Induced Absorption ◽  
Separate Paper

A study is being made of the far infrared absorption occurring in compressed rare-gas mixtures, and compressed homonuclear diatomic gases. The region investigated lies between 20 and 400 cm−1. The spectra are obtained from the Fourier analysis of interferograms produced by a dynamic Michelson interferometer. It is possible to obtain accurate absolute absorption coefficients for broad bands using this method provided care is exercised in the analysis of the interferograms. The necessary precautions are discussed in detail. The precision of the method obtained in practice is demonstrated using the far infrared bands of hydrogen and nitrogen as examples. Only the experimental techniques are discussed in this paper; the detailed results follow in a separate paper.

Collision-induced absorption in ethane–rare gas mixtures

1983 ◽  
Vol 61 (4) ◽  
pp. 633-640 ◽  
Author(s):  
I. R. Dagg ◽  
L. A. A. Read ◽  
A. Anderson
Keyword(s):  
Fourier Transform ◽  
Temperature Dependence ◽  
Quadrupole Moment ◽  
Gas Mixtures ◽  
Rare Gas ◽  
Fourier Transform Spectrometer ◽  
Rare Gases ◽  
Induced Absorption ◽  
Absolute Value ◽  
The Absolute

The collision-induced spectra of mixtures of ethane and each of the rare gases He, Ar, Kr, and Xe in the 40–360 cm−1 region have been obtained using a Michelson Fourier transform spectrometer. In addition, the temperature dependence of the absorption in ethane and ethane–xenon mixtures is reported. All results have been analyzed according to the theory for quadrupole induced rotation–translation absorption. The absolute value of the quadrupole moment of ethane is estimated to be less than 1.0 B and most likely less than 0.5 B. Various speculations are made concerning the induction mechanisms (other than quadrupolar) for each of the mixtures.

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