Catalytic properties of non-stoichiometric uranium-thorium mixed oxides in carbon monoxide oxidation

1969 ◽  
Vol 14 (4) ◽  
pp. 322-331 ◽  
Author(s):  
B CLAUDEL
ChemCatChem ◽  
2016 ◽  
Vol 8 (22) ◽  
pp. 3546-3555 ◽  
Author(s):  
Dmitry A. Svintsitskiy ◽  
Ilya Yu. Pakharukov ◽  
Elena M. Slavinskaya ◽  
Tatyana Yu. Kardash ◽  
Valentin N. Parmon ◽  
...  

2012 ◽  
Vol 53 (3) ◽  
pp. 409-418 ◽  
Author(s):  
A. A. Shutilov ◽  
G. A. Zenkovets ◽  
S. V. Tsybulya ◽  
V. Yu. Gavrilov ◽  
G. N. Kryukova

Author(s):  
G. R. Kosmambetova ◽  
O. I. Yanushevska ◽  
N. V. Vlasenko ◽  
O. Z. Didenko ◽  
V. I. Grytsenko ◽  
...  

1994 ◽  
Vol 108 (2) ◽  
pp. 115-122 ◽  
Author(s):  
Ana Terlecki-Baričević ◽  
Dušan Jovanović ◽  
Boško Grbić ◽  
Tsvetana Marinova ◽  
Plamen Kirilov-Stefanov

Author(s):  
L.D. Schmidt ◽  
K. R. Krause ◽  
J. M. Schwartz ◽  
X. Chu

The evolution of microstructures of 10- to 100-Å diameter particles of Rh and Pt on SiO2 and Al2O3 following treatment in reducing, oxidizing, and reacting conditions have been characterized by TEM. We are able to transfer particles repeatedly between microscope and a reactor furnace so that the structural evolution of single particles can be examined following treatments in gases at atmospheric pressure. We are especially interested in the role of Ce additives on noble metals such as Pt and Rh. These systems are crucial in the automotive catalytic converter, and rare earths can significantly modify catalytic properties in many reactions. In particular, we are concerned with the oxidation state of Ce and its role in formation of mixed oxides with metals or with the support. For this we employ EELS in TEM, a technique uniquely suited to detect chemical shifts with ∼30Å resolution.


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