Thermal stability of polymers based on vinyl derivatives of silicon

1966 ◽  
Vol 8 (5) ◽  
pp. 976-981 ◽  
Author(s):  
N.S. Nametkin ◽  
N.A. Nechitailo ◽  
S.G. Durgar'yan ◽  
V.S. Khotimskii
1987 ◽  
Vol 42 (4) ◽  
pp. 489-494 ◽  
Author(s):  
Eckehard V. Dehmlow ◽  
Roland Kramer

Abstract The title compounds la-3c were prepared by stereoselective reduction of the respective dibromides. Pyrolysis gave allylic bromides (8, 9, 11) as primary and dienes (10, 12) as secondary products. Product ratios were independent of the stereochemistry of the starting materials. No differences of the rearrangement rates of the stereoisomers were observed in gas phase reactions of the derivatives of bicyclo[6.1.0]- and bicyclo[8.1.0]alkanes. With the larger bicyclo[10.1.0] derivatives, however, distinct differences in the thermal stability of cis-trans-isomers4c/5c or 2c/3c were found in condensed phase.


1978 ◽  
Vol 20 (10) ◽  
pp. 2487-2493
Author(s):  
Yu.N. Sazanov ◽  
G.N. Fedorova ◽  
L.M. Shcherbakova ◽  
G.I. Nosova

2017 ◽  
Vol 19 (12) ◽  
pp. 8595-8601 ◽  
Author(s):  
T. Alphazan ◽  
P. Florian ◽  
C. Thieuleux

We report here the controlled preparation of SiO2 supported Sb-(mono)layers and their thorough characterization (in situ IR, solid-state NMR, elemental analyses) for the non-destructive Sb-doping of semiconductors.


RSC Advances ◽  
2020 ◽  
Vol 10 (38) ◽  
pp. 22370-22376
Author(s):  
Katarzyna Jastrzębska ◽  
Barbara Mikołajczyk ◽  
Piotr Guga

3′-O-(2-Thio-1,3,2-oxathiaphospholane) derivatives of 5′-O-DMT-LNA-nucleosides were used to prepare P-stereodefined (RP-PS)-DNA#LNA chimeras, which form thermally stable parallel complexes with (2′-OMe)-RNA matrices.


2021 ◽  
Vol 36 (27) ◽  
pp. 2150195
Author(s):  
Aloke Kumar Sinha

The criteria for thermal stability of a most general quantum black hole derived by us appeared in the form of a series of inequalities connecting second-order derivatives of black hole mass with respect to its parameters, which determine the mass of the black hole. These nullify the concept of positivity of specific heat as the sole criteria for thermal stability. Using this most general stability criterion, we prove here that AdS Schwarzschild black holes are no longer stable anywhere in their parameter space if cosmological constant is allowed to vary. We also calculate the fluctuations of both horizon area and cosmological constant of this black hole. We calculate specific heat of it and compare this with Hawking’s prediction.


2015 ◽  
Vol 35 (1) ◽  
pp. 1-10 ◽  
Author(s):  
Iwona Zarzyka

Abstract Hydroxyalkyl derivatives containing oxamidoester and oxamide fragments have been separately obtained using oxamic acid, oxamide and alkylene carbonates. It has been proven that the presence of oxamidoester and oxamide structural fragments in oligomer structures is responsible for the thermal stability of these products. Rigid, thermally stable polyurethane foams were obtained with the use of oligomers with oxamidoestercarbamidoimide, carbamide, oxamidoester and oxamide groups as polyols components. The properties of these foamed materials were compared with each other and with the properties of reference foams. It was found that the polyurethane foams characterized by the best properties were obtained from hydroxypropyl derivatives of oxamide.


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