Thermal degradation behaviour and kinetic parameters of copolymers obtained by copolymerization via zwitterion

1991 ◽  
Vol 184 (2) ◽  
pp. 183-191 ◽  
Author(s):  
Bernabe Luis Rivas ◽  
Guadalupe Del C. Pizarro ◽  
Luis H. Tagle
Keyword(s):  
Thermal Degradation ◽  
Kinetic Parameters ◽  
Degradation Behaviour

scholarly journals Thermal Degradation Behaviour of Ni(II) Complex of 3,4-Methylenedioxaphenylaminoglyoxime

2013 ◽  
Vol 2013 ◽  
pp. 1-7 ◽  
Author(s):  
Emin Karapınar ◽  
Ilkay Hilal Gubbuk ◽  
Bilge Taner ◽  
Pervin Deveci ◽  
Emine Ozcan
Keyword(s):  
Experimental Data ◽  
Activation Energy ◽  
Free Energy ◽  
Thermal Degradation ◽  
Metal Complex ◽  
Kinetic Parameters ◽  
Preexponential Factor ◽  
Degradation Behaviour ◽  
Mechanism Of Decomposition ◽  
Pyrolytic Decomposition

Thermal degradation behaviour of the Ni(II) complex of 3,4-methylenedioxaphenylaminoglyoxime was investigated by TG, DTA, and DTG at a heating rate of 10°C min−1under dinitrogen. The acquired experimental data shows that the complex is thermally stable up to 541 K. The pyrolytic decomposition process occurs by melting metal complex and metal oxide remains as final product. The energies of the reactions involved and the mechanism of decomposition at each stage have been examined. The values of kinetic parameters such as activation energy (E), preexponential factor (A) and thermodynamic parameters such as enthalpy (ΔH), entropy (ΔS), and Gibbs free energy (ΔG) are also evaluated.

scholarly journals Solid-state thermal degradation behaviour of 1-D coordination polymers of Ni(II) and Cu(II) bridged by conjugated ligand

2013 ◽  
Vol 114 (2) ◽  
pp. 653-664 ◽  
Author(s):  
Ram Lakhan Prasad ◽  
Anita Kushwaha ◽  
Rajesh Kumar ◽  
Imre Miklós Szilágyi ◽  
László Kótai
Keyword(s):  
Solid State ◽  
Thermal Degradation ◽  
Coordination Polymers ◽  
Degradation Behaviour

Application of Calculus Equation in Solving Thermal Decomposition Kinetics Parameters of Flame Retardant Wood

2014 ◽  
Vol 983 ◽  
pp. 190-193
Author(s):  
Cai Yun Sun ◽  
Yong Li Yang ◽  
Ming Gao
Keyword(s):  
Activation Energy ◽  
Thermal Decomposition ◽  
Thermal Degradation ◽  
Phosphoric Acid ◽  
Flame Retardant ◽  
Kinetic Parameters ◽  
Flame Retardancy ◽  
Decomposition Kinetics ◽  
Thermal Decomposition Kinetics ◽  
Kinetics Parameters

Wood has been treated with amino resins and amino resins modified with phosphoric acid to impart flame retardancy. The thermal degradation of samples has been studied by thermogravimetry (TG) in air. From the resulting data, kinetic parameters for different stages of thermal degradation are obtained following the method of Broido. For the decomposition of wood and flame retardant wood, the activation energy is found to decrease from 122 to 72 kJmol-1.

Thermal degradation behaviour of aromatic poly(ester–imide) investigated by pyrolysis–GC/MS

2007 ◽  
Vol 14 (5) ◽  
pp. 401-409 ◽  
Author(s):  
Wenjeng Guo ◽  
Tsu-Hwang Chuang ◽  
Sheng-Tuang Huang ◽  
Wen-Tsuen Leu ◽  
Sheng-Huei Hsiao
Keyword(s):  
Thermal Degradation ◽  
Degradation Behaviour
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