Water vapour sorption behaviour of copolymers of N,N-diethylaminoethyl methacrylate and methyl methacrylate

Biomaterials ◽  
1996 ◽  
Vol 17 (12) ◽  
pp. 1187-1193 ◽  
Author(s):  
Jose M. Cornejo-Bravo ◽  
Ronald A. Siegel
2013 ◽  
Vol 49 (5) ◽  
pp. 2362-2371 ◽  
Author(s):  
Carmen-Mihaela Popescu ◽  
Callum A. S. Hill ◽  
Simon Curling ◽  
Graham Ormondroyd ◽  
Yanjun Xie

Holzforschung ◽  
2010 ◽  
Vol 64 (4) ◽  
Author(s):  
Callum A.S. Hill ◽  
Andrew Norton ◽  
Gary Newman

Abstract The water vapour sorption behaviour of Sitka spruce was analysed based on the parallel exponential kinetics (PEK) model. The PEK model deconvolutes the sorption kinetics curve into two exponential kinetics processes (fast and slow) which have characteristic times and moisture contents associated with them. The sorption kinetics was examined at different temperatures enabling the determination of activation energies for the sorption kinetic processes throughout the hygroscopic range (from 5% to 95% relative humidities). The physical interpretation of the PEK model is also discussed.


CrystEngComm ◽  
2019 ◽  
Vol 21 (15) ◽  
pp. 2551-2558 ◽  
Author(s):  
Dominik Fröhlich ◽  
Philipp Hügenell ◽  
Helge Reinsch

The water sorption behaviour of aluminium MOF CAU-10 and CAU-15-Cit was followed by in situ powder X-ray diffraction.


2015 ◽  
Vol 50 (22) ◽  
pp. 7282-7292 ◽  
Author(s):  
Cristina Simón ◽  
Luis García Esteban ◽  
Paloma de Palacios ◽  
Francisco García Fernández ◽  
Raquel Martín-Sampedro ◽  
...  

Holzforschung ◽  
2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Mohd Khairun Anwar Uyup ◽  
Siti Hanim Sahari ◽  
Zaihan Jalaludin ◽  
Hamdan Husain ◽  
Seng Hua Lee ◽  
...  

AbstractThe purpose of this study was to determine the applicability of methyl methacrylate (MMA) and MMA–styrene in treating batai (Paraserianthes falcataria) wood. The effectiveness of the treatment was evaluated based on Fourier transform infrared spectroscopy (FTIR) analysis, physico-mechanical properties of the treated wood, and moisture sorption isotherm using dynamic vapour sorption (DVS) apparatus. Physico-mechanical properties of the modified batai wood were improved. The MMA-treated batai wood showed better improvement in terms of physical and mechanical properties compared to the MMA–styrene-treated batai wood. The equilibrium moisture content (EMC) for untreated batai wood was higher than that of treated samples. At 95% RH, the EMC for untreated batai wood was 20.7%, whereas the EMC for MMA- and MMA–styrene-treated samples was 7.9 and 8.8%, respectively. The findings indicate that the modified batai wood absorbed less moisture compared to the untreated batai wood. Moreover, the untreated batai wood had larger hysteresis loop than the treated batai wood. The highest hysteresis value was observed at 80% RH for untreated batai wood (3.8%), followed by MMA–styrene-treated batai wood (1.7%) and MMA-treated batai wood (1.2%). Both MMA and MMA–styrene proved to be effective treatments for batai wood because they reduced its hygroscopicity.


Holzforschung ◽  
2019 ◽  
Vol 73 (12) ◽  
pp. 1059-1068 ◽  
Author(s):  
Kristiina Lillqvist ◽  
Susanna Källbom ◽  
Michael Altgen ◽  
Tiina Belt ◽  
Lauri Rautkari

Abstract The objective of the study was to investigate the water vapour sorption behaviour of thermally modified (TM) wood powder, e.g. ground wood prepared from waste streams of TM solid wood, and wood powder that was extracted in pressurised hot water. Solid spruce wood was TM in steam conditions (210°C for 3 h), milled and hot-water-extracted (HWE) at elevated pressure (140°C for 1 h). The results evidence that the hot-water extraction reduced the water sorption and the accessible hydroxyl group concentration by the removal of amorphous carbohydrates. In contrast, the enhanced cross-linking of the cell wall matrix and the annealing of amorphous matrix polymers during thermal modification reduced the sorption behaviour of wood additionally, without further reducing the hydroxyl accessibility. These additional effects of thermal modification were at least partially cancelled by hot-water extraction. The results bring novel insights into the mechanisms that reduce the water vapour sorption of wood by compositional and structural changes induced by heating.


2013 ◽  
Vol 4 (3) ◽  
pp. 191-196 ◽  
Author(s):  
C A S Hill ◽  
J Ramsay ◽  
K Laine ◽  
L Rautkari ◽  
M Hughes

2010 ◽  
Vol 46 (2) ◽  
pp. 479-489 ◽  
Author(s):  
Yanjun Xie ◽  
Callum A. S. Hill ◽  
Zaihan Jalaludin ◽  
Simon F. Curling ◽  
Rajesh D. Anandjiwala ◽  
...  

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