Kinetics of the reactions of intrinsic and phosphorus doped polycrystalline silicon with molecular chlorine

1991 ◽  
Vol 153 (3) ◽  
pp. 483-489 ◽  
Author(s):  
Zane H. Walker ◽  
Elmer A. Ogryzlo
1991 ◽  
Vol 138 (1) ◽  
pp. 214-219 ◽  
Author(s):  
Yangyuan Wang ◽  
Jiang Tao ◽  
Shen Tong ◽  
Tiejun Sun ◽  
Aizhen Zhang ◽  
...  

1987 ◽  
Vol 51 (17) ◽  
pp. 1328-1330 ◽  
Author(s):  
N. Hayasaka ◽  
H. Nakahara ◽  
H. Okano ◽  
Y. Horiike

2013 ◽  
Vol 102 (21) ◽  
pp. 212102 ◽  
Author(s):  
T. Antesberger ◽  
T. A. Wassner ◽  
C. Jaeger ◽  
M. Algasinger ◽  
M. Kashani ◽  
...  

1984 ◽  
Vol 37 (11) ◽  
pp. 2249
Author(s):  
KA Ahmed ◽  
PJ Hanhela ◽  
M Hassan ◽  
J Miller ◽  
DB Paul

The activating effect of the phenylazo substituent in electrophilic substitution has been examined. The rates and partial rate factors for chlorination of azobenzene with molecular chlorine and protonated chlorine acetate have been determined relative to benzene. Whereas the chlorine acetate reaction proceeds readily (relative rate 4900) there is virtually no activation to chlorination by molecular chlorine. Complexes between azobenzene and bromine were, however, isolated and chatacterized. Their formation implies that during molecular halogenation reactions the electrophile is essentially unavailable. The relative chlorination rates for azobenzene and azoxybenzene have also been established: the phenylazo group is more activating towards protonated chlorine acetate whereas azoxybenzene (which does not complex with halogens) is the more reactive with molecular chlorine. The chlorination results confirm the versatility of the phenylazo group which is the first substituent for which kinetic data have been obtained quantifying activation of aromatic electrophilic, radical and nucleophilic substitution.


1981 ◽  
Vol 52 (11) ◽  
pp. 6870-6878 ◽  
Author(s):  
G. Lubberts ◽  
B. C. Burkey ◽  
F. Moser ◽  
E. A. Trabka

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