Carbonylation of methyl acetate to acetic anhydride using homogeneous nickel complex catalyst

1993 ◽  
Vol 80 (1) ◽  
pp. 21-29 ◽  
Author(s):  
A.A. Kelkar ◽  
R.S. Ubale ◽  
R.V. Chaudhari
1990 ◽  
Vol 63 (3) ◽  
pp. L29-L31 ◽  
Author(s):  
Ashutosh A. Kelkar ◽  
Raghunath V. Chaudhari

1973 ◽  
Vol 51 (13) ◽  
pp. 2177-2179 ◽  
Author(s):  
R. P. Mariella ◽  
K. H. Brown

The failure of methyl-substituted tertiary amines to yield methyl acetate on cleavage by acetic anhydride indicates that the mechanism proposed by Gol'dfarb and Belen'kii cannot be correct. The results of cleavage of cinnamyldimethylamine are offered as support for the mechanism proposed by Mariella and Brown. Catalysis by acetic acid is not considered to be important.


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