Anaerobic digestion of palm oil mill effluent using an up-flow anaerobic sludge blanket reactor

Palm oil Mill Effluent (POME) with concentrated butyrate was treated in a 4.5 l upflow anaerobic sludge blanket reactor (UASBR), run over a range of influent concentrations (16.5–46.0 g-COD l−1), chemical oxygen demand (COD) loading rates (1.5–11.5 g-CODl−1d−1) and 11–4 days hydraulic retention time (HRT) at 37 °C by maintaining pH between 6.5–7.5. The process consistently removed 97–99% of COD at loading rates up to 1.5–4.8 g-COD l−1d−1 by varying HRT (11–7.2 days). Butyrate is an important intermediate in the anaerobic degradation of organic matter. In sulphate-depleted environment, butyrate in POME (BOD/COD ratio of 0.5) is β-oxidised to acetate and hydrogen, by obligate proton reducers in syntrophic association with hydrogen utilizing methanogens. The conversion of acetate to methane appeared to be rate limiting step. Maximum biogas (20.17 ll−1d−1) and methane production (16.2 ll−1d−1) were obtained at COD loading rate of 4.80 gl−1d−1and HRT of 7.2 days. The biogas and methane production were higher in the presence of butyrate compared to control. The methane content of the biogas was in the range of 70–80% throughout the study while in control it was 60–65%. Finding of this study clearly indicates the successful treatment of POME with butyrate in UASBR. Santrauka Palmių aliejaus gamybinės nuotekos (POME) su koncentruotu butiratu buvo apdorotos 4,5 l talpos aukštyn tekančio aerobinio dumblo plokšteliniame reaktoriuje (UASBR). Nuotekos tekėjo įvairių koncentracijų (16,5–46,0 g – ChDS 1−1), cheminio deguonies suvartojimo (ChDS) normos (1,5–11,5 g – ChDS 1−1d.−1). Hidraulinio sulaikymo trukmė (HRT) nuo 11 iki 4 dienų, kai temperatūra 37 °C, pH palaikant 6,5–7,5. Vykstant procesui nuolat buvo pašalinama 97–99% ChD, kai tiekimo ir pakrovimo sparta 1,5–4,8 g – ChDS 1−1d.−1 kintant HRT(11–7,2 d.). Butiratas yra svarbus tarpininkas organinių medžiagų anaerobinio skilimo procese. Sulfatas iš aplinkos, butiratas iš POME (BDS/ChDS santykis 0,5) yra acetato ir vandenilio β oksidatoriai, priverčiantys protonų reducentus sintrofinės sąveikos su vandeniliu metu utilizuoti metanogenus. Acetato virtimas metanu pasirodė esąs greitį ribojantis veiksnys. Daugiausia biodujų (20,17 l 1−1 d.−1) ir metano (16,2 l 1−1 d.−1) susidarė tada, kai suvartojamo ChD tiekimo greitis buvo 4,80 g 1−1d.−1, o HRT – 7,2 dienos. Daugiau biodujų ir metano susidarė dalyvaujant butiratui, palyginti su kontroliniu pavyzdžiu. Biodujose metano kiekis tyrimo metu svyravo 70–80%, o kontroliniame buvo 60–65%. Šis tyrimas aiškiai parodė, kad POME su butiratu UASBreaktoriuje apdorojamas sėkmingai.

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Performance and Kinetic Evaluation of Palm Oil Mill Effluent (POME) Digestion in a Continuous High Rate Up-Flow Anaerobic Sludge Blanket (UASB) Bioreactor

Materials Science Forum ◽

10.4028/www.scientific.net/msf.1025.141 ◽

2021 ◽

Vol 1025 ◽

pp. 141-149

Author(s):

Mohamad Mokhtar Ibrahim ◽

Zulkifly Jemaat ◽

Abdurahman Hamid Nour

Keyword(s):

Palm Oil ◽

Palm Oil Mill Effluent ◽

Upflow Anaerobic Sludge Blanket ◽

Uasb Reactor ◽

Anaerobic Sludge ◽

Kinetic Evaluation ◽

Specific Biomass ◽

Palm Oil Mill ◽

Anaerobic Sludge Blanket ◽

The Impact

In this study, we operated a 10 litre upflow anaerobic sludge blanket (UASB) reactor continuosly at mesophilic temperature (38 °C). UASB reactor performance was evaluated based on the impact of the hydraulic retention time (HRT) ranged between 1 and 5 days and influent COD concentration in the range of 4540 mgL-1 and 20,820 mgL-1. The pH of the UASB was maintained in the range of 6.5 to 7.2 by adding buffering solution containing of 5 gL-1 of calcium oxide (CaO) derived from waste cockle shells. A simplified Monod’s model was employed to describe kinetics of anaerobic digestion of POME by using UASB reactor at organic loading rates (OLR) in the range between 1.17 g.CODL-1d-1 and 17.22 g.CODL-1d-1. A high COD degradation rate of 93.26 % was recorded at OLR of 3.92 g.COD L-1d-1 and HRT of 4 days. The UASB reactor generated the maximum biogas production at 34.95 L/d when operated at HRT 1 day and OLR 7.70 g.CODL-1. The proposed kinetic equations are applicable to describe anaerobic treatment of palm oil mill effluent with the UASB reactor. Biokinetic coefficients evaluated were, the growth yield (YG), 3.906 g VSS/g CODremoved.d-1; the specific biomass decay (b), 0.233 d-1; the specific biomass growth rate (μmax), 1.861 d-1; and the saturation constant (Ks), 3.459 g-CODL-1.

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Performance evaluation of upflow anaerobic sludge blanket reactor using immobilized ZnO nanoparticle enhanced continuous biogas production

Energy & Environment ◽

10.1177/0958305x19865967 ◽

2019 ◽

Vol 31 (2) ◽

pp. 330-347 ◽

Cited By ~ 1

Author(s):

Anwar Ahmad ◽

Sajjala Sreedhar Reddy

Keyword(s):

Zinc Oxide ◽

Palm Oil ◽

Biogas Production ◽

Palm Oil Mill Effluent ◽

Upflow Anaerobic Sludge Blanket ◽

Anaerobic Sludge ◽

Zinc Oxide Nanoparticle ◽

Oxide Nanoparticle ◽

Palm Oil Mill ◽

Anaerobic Sludge Blanket

In this study, zinc oxide nanoparticles immobilized by methylenebisacrylamide were used for anaerobic consortium application and were examined for biomass retention capacity characterized in terms of volatile solids and specific methanogenic activity. The upflow anaerobic sludge blanket reactor was operated at various hydraulic retention times and was fed with palm oil mill effluent as a carbon source. The highest methane production rate of 510 mL CH4·L−1·h−1 with a methane yield of 68.3 L CH4 g−1·CODadded was obtained at palm oil mill effluent concentration of 20 g COD·L-1 and 24 h of hydraulic retention time. The average biogas (4.5 L) showed methane content and chemical oxygen demand reduction of 84.5 and 95.7%, respectively. Rmax was 570 mL L−1·POME·h−1 at 15% of zinc oxide nanoparticles, with butyrate and acetic acid in an effluent contained when operated at a hydraulic retention time of 24 h and a palm oil mill effluent concentration of 20 g COD L−1. A CO2 reduction of 93.6% was obtained at 15% w/v loading of zinc oxide nanoparticle. Experiments demonstrated that with the granule bead size of immobilized zinc oxide nanoparticle of 3.99 mm, production of CH4 and sequester of CO2 were 650 m3·d−1 and 456 m3·d−1, respectively. At 15% zinc oxide nanoparticle, granule leakage was found to be 0.065 mg·L−1. It is significant that this is the first report on immobilized zinc oxide nanoparticle granule biomass for biogas production from wastewater.

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PENGARUH PENAMBAHAN TRACE METAL FE TERHADAP PENYISIHAN KANDUNGAN PADATAN LIMBAH CAIR KELAPA SAWIT MENGGUNAKAN REAKTOR HYBRID UPFLOW ANAEROBIC SLUDGE BLANKET

Jurnal Teknik Kimia USU ◽

10.32734/jtk.v3i1.1492 ◽

2014 ◽

Vol 3 (1) ◽

pp. 1-4

Author(s):

Julika Sitinjak ◽

Janwarisman Purba ◽

Fatimah

Keyword(s):

Trace Metal ◽

Palm Oil ◽

Suspended Solid ◽

Solid Content ◽

Palm Oil Mill Effluent ◽

Upflow Anaerobic Sludge Blanket ◽

Organic Load ◽

Anaerobic Sludge ◽

Palm Oil Mill ◽

Anaerobic Sludge Blanket

Research about influence the addition of trace metal Fe against allowance for the solid content of palm oil mill effluent using Hybrid Upflow Anaerobic Sludge Blanket Reactor aim to know the additionof trace metal Fe against allowance for the solid content of palm oil mill effluent using HUASB reactor based on removal of Chemical Oxygen Demand (COD), Total Suspended Solid (TSS) dan Volatile Suspended Solid (VSS). The reactor isa reactor with a combination of suspended growth reactor in the bottom and attached growth reactor at the top. The material used is palm oil mill effluent and inoculum derived from PKS Pagar Merbau. Test parameters to observed are COD, TSS and VSS. The optimum conditions obtained on the organic load is 17024 mg/l with the addition of Fe is 0.5 mg/l so that obtained COD reduction is 85.891%, TSS reduction is 86.047% and VSS reduction is 36.566%.

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