<p class="western" align="justify">The parameter space for the very uncertain composition of sublimated H2O and its photochemical products H and H2 in Callisto's atmosphere is examined using the Direct Simulaton Monte Carlo (DSMC) method.</p>
<p class="western" align="justify">We focus on two significantly different versions of H2O production in which:</p>
<p class="western" align="justify">(1) the ice and dark, non-ice/ice-poor material are intimately mixed and H2O sublimates at Callisto's warm day-side temperatures (e.g., as in most atmospheric modeling efforts at Callisto to date [1-4]); and</p>
<p class="western" align="justify">(2) the ice and dark, non-ice/ice-poor material are segregated (e.g., consistent with interpretations of images of Callisto's surface taken by Voyager [5, 6] and Galileo [7]) and H2O sublimates at "ice" temperatures [8].</p>
<p class="western" align="justify">Our 2D molecular kinetic models track the motion H2O, whose sublimation yield varies several orders of magnitude depending on the description of Callisto's surface, its photochemical products H and H2, and a relatively dense O2 component. Whereas H is assumed to react in the regolith on return to the surface, H2 is assumed to thermalize and re-enter the atmosphere.</p>
<p class="western" align="justify">We compare the simulated LOS column densities of H to the detected H corona at Callisto [9], which was suggested to be produced primarily by photodissociation of sublimated H2O. Our goal is to use the corona observations to help constrain the source rate for H2O from Callisto&#8217;s complex surface.</p>
<p class="western" align="justify"><strong>References</strong></p>
<p class="western" align="justify">[1] Liang et al., 2005. Atmosphere of Callisto. <em>Journal of Geophysical Research: Planets</em>.</p>
<p class="western" align="justify">[2] Vorburger et al., 2015. Monte-Carlo simulation of Callisto&#8217;s exosphere. <em>Icarus</em>.</p>
<p class="western" align="justify">[3] Hartkorn et al., 2017. Structure and density of Callisto&#8217;s atmosphere from a fluid-kinetic model of its ionosphere: Comparison with Hubble Space Telescope and Galileo observations. <em>Icarus.</em></p>
<p class="western" align="justify">[4] Carberry Mogan et al., 2021 (<em>under review</em>). A tenuous, collisional atmosphere on Callisto. <em>Icarus</em>.</p>
<p class="western" align="justify">[5] Spencer and Maloney, 1984. Mobility of water ice on Callisto: Evidence and implications. <em>Geophysical Research Letters</em>.</p>
<p class="western" align="justify">[6] Spencer, 1987. Thermal segregation of water ice on the Galilean satellites. <em>Icarus</em>.</p>
<p class="western" align="justify">[7] Moore et al., 1999. Mass movement and landform degradation on the icy Galilean satellites: Results of the Galileo nominal mission. <em>Icarus</em>.</p>
<p class="western" align="justify">[8] Grundy et al., 1999. Near-infrared spectra of icy outer solar system surfaces: Remote determination of H2O ice temperatures. <em>Icarus</em>.</p>
<p class="western" align="justify">[9] Roth et al., 2017. Detection of a hydrogen corona at Callisto. <em>Journal of Geophysical Research: Planets</em>.</p>