Pentanuclear Yb(III) cluster-based metal-organic frameworks as heterogeneous catalysts for CO2 conversion

Biofuel synthesis is of great significance for producing alternative fuels. Among the developed catalytic materials, the metal-organic framework-based hybrids used as acidic, basic, or supported catalysts play major roles in the biodiesel production. This paper presents a timely and comprehensive review of recent developments on the design and preparation of metal-organic frameworks-based catalysts used for biodiesel synthesis from various oil feedstocks, including MILs-based catalysts, ZIFs-based catalysts, UiO-based catalysts, Cu-BTC-based catalysts, and MOFs-derived porous catalysts. Due to their unique and flexible structures, excellent thermal and hydrothermal stability, and tunable host-guest interactions, as compared with other heterogeneous catalysts, metal-organic framework-based catalysts have good opportunities for application in the production of biodiesel at industrial scale.

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Metal–organic frameworks as catalytic selectivity regulators for organic transformations

Chemical Society Reviews ◽

10.1039/d0cs01538e ◽

2021 ◽

Author(s):

Jun Guo ◽

Yutian Qin ◽

Yanfei Zhu ◽

Xiaofei Zhang ◽

Chang Long ◽

...

Keyword(s):

Heterogeneous Catalysts ◽

Metal Organic Frameworks ◽

Research Topic ◽

Organic Transformations ◽

Catalytic Selectivity ◽

Challenging Research ◽

Metal Organic

Selective organic transformations using metal–organic frameworks (MOFs) and MOF-based heterogeneous catalysts have been an intriguing but challenging research topic in both the chemistry and materials communities.

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Selective Cyclohexene Oxidation to Allylic Compounds over Cu-triazole Framework via Homolytic Activation of Hydrogen Peroxide

Dalton Transactions ◽

10.1039/d1dt00227a ◽

2021 ◽

Author(s):

Panyapat Ponchai ◽

Kanyaporn Adpakpang ◽

Sareeya Bureekaew

Keyword(s):

Hydrogen Peroxide ◽

Heterogeneous Catalysts ◽

Metal Organic Frameworks ◽

Porous Structures ◽

Cyclohexene Oxidation ◽

Catalytic Sites ◽

P Utilization ◽

Metal Organic ◽

Activation Of Hydrogen Peroxide

Utilization of metal-organic frameworks as heterogeneous catalysts is crucial owing to their abundant catalytic sites and well-defined porous structures. Highly robust [Cu3(trz)3(μ3-OH)(OH)2(H2O)4]∙2H2O (trz = 1,2,4-triazole) was employed as a catalyst...

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Incorporation of Chromophores into Metal–Organic Frameworks for Boosting CO2 Conversion

Inorganic Chemistry ◽

10.1021/acs.inorgchem.1c02294 ◽

2021 ◽

Author(s):

Yun-Nan Gong ◽

Jin-Wang Liu ◽

Jian-Hua Mei ◽

Xue-Lian Lin ◽

Ji-Hua Deng ◽

...

Keyword(s):

Metal Organic Frameworks ◽

Co2 Conversion ◽

Metal Organic

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Cu(I)-Based Metal–Organic Frameworks as Efficient and Recyclable Heterogeneous Catalysts for Aqueous-Medium C–H Oxidation

Crystal Growth & Design ◽

10.1021/acs.cgd.8b01527 ◽

2018 ◽

Vol 19 (2) ◽

pp. 976-982 ◽

Cited By ~ 7

Author(s):

Kuan Gao ◽

Chao Huang ◽

Yisen Yang ◽

Hong Li ◽

Jie Wu ◽

...

Keyword(s):

Aqueous Medium ◽

Heterogeneous Catalysts ◽

Metal Organic Frameworks ◽

Metal Organic

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Heterogeneous catalytic wet peroxide oxidation of simulated phenol wastewater by copper metal–organic frameworks

RSC Advances ◽

10.1039/c5ra01707f ◽

2015 ◽

Vol 5 (41) ◽

pp. 32795-32803 ◽

Cited By ~ 54

Author(s):

Kai Huang ◽

Yang Xu ◽

Lianguang Wang ◽

Dongfang Wu

Keyword(s):

Heterogeneous Catalysts ◽

Metal Organic Frameworks ◽

Peroxide Oxidation ◽

Copper Metal ◽

Heterogeneous Catalytic ◽

Wet Peroxide Oxidation ◽

Porous Copper ◽

Metal Organic ◽

Catalytic Wet Peroxide Oxidation ◽

Phenol Wastewater

Two different porous copper metal–organic frameworks (Cu-MOFs) named as Cu3(BTC)2 and Cu(BDC) were synthesized and applied as heterogeneous catalysts for the catalytic wet peroxide oxidation (CWPO) of simulated phenol wastewater (100 mg L−1).

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