scholarly journals Kinetic Study on COD Removal of Palm Oil Refinery Effluent by UV-Fenton

2012 ◽  
Vol 3 ◽  
pp. 6-10 ◽  
Author(s):  
Soo Kwan Leong ◽  
Nur Alwani Ali Bashah
Keyword(s):  
Kinetic Study ◽  
Palm Oil ◽  
Cod Removal ◽  
Oil Refinery ◽  
Refinery Effluent

scholarly journals Treatment of Palm Oil Refinery Effluent Using Tannin as a Polymeric Coagulant: Isotherm, Kinetics, and Thermodynamics Analyses

Polymers ◽  
2020 ◽  
Vol 12 (10) ◽  
pp. 2353 ◽  
Author(s):  
Nik Mohd Farid Mat Yasin ◽  
Md. Sohrab Hossain ◽  
Abdul Khalil H.P.S. ◽  
Muzafar Zulkifli ◽  
Adel Al-Gheethi ◽  
...  
Keyword(s):  
Palm Oil ◽  
Oxygen Demand ◽  
Oil Refinery ◽  
Kinetics Model ◽  
Isotherm Models ◽  
Aquatic Life ◽  
Refinery Effluent ◽  
Coagulation Study ◽  
Sedimentation Time

The refining of the crude palm oil (CPO) generates the palm oil refinery effluent (PORE). The presence of high contents of biochemical oxygen demand (BOD), chemical oxygen demand (COD), turbidity, and suspended solids (SS) in PORE encourages the determination of an effective treatment process to minimize the environmental pollution and preserve aquatic life. In the present study, a biodegradable natural polymer, namely tannin, was utilized as a coagulant to treat PORE. The coagulation experiment was conducted using a jar test apparatus. The tannin coagulation efficiency was evaluated based on the BOD, COD, turbidity, and SS removal from PORE by varying the tannin dose (50–300 mg/L), pH (pH 4–10), treatment time (15–90 min), and sedimentation time (15–90 min). It was found that the maximum removal of BOD, COD, turbidity, and SS was 97.62%, 88.89%, 93.01%, and 90.21%, respectively, at pH 6, a tannin dose of 200 mg/L, 60 min of coagulation time, and 60 min of sedimentation time. Analyses of isotherm models revealed that the Freundlich isotherm model was well fitted with the coagulation study. Kinetics studies show that the pseudo-second-order kinetics model was the well-fitted kinetics model for the BOD, COD, turbidity, and SS removal from PORE using tannin as a polymeric coagulant. The determination of thermodynamics parameters analyses revealed that BOD, COD, turbidity, and SS removal from PORE was spontaneous, exothermic, and chemical in nature. The finding of the present study shows that tannin as a natural polymeric coagulant would be utilized in PORE treatment to avoid toxic sludge generation.

CATALYTIC CRACKING OF PALM OIL: KINETIC STUDY

Clean Air ◽  
2007 ◽  
Vol 8 (1) ◽  
pp. 65-79 ◽  
Author(s):  
Farouq Twaiq ◽  
Abdul Rahman Mohamed ◽  
Subhash Bhatia
Keyword(s):  
Kinetic Study ◽  
Palm Oil ◽  
Catalytic Cracking

Treatment of Palm Oil Mill Effluent (POME) Supernatants Using Aerobic Attached–Growth System: Trickling Filter as a Case Study

2012 ◽  
Author(s):  
Ahmad Zuhairi Abdullah ◽  
Mohamad Hakimi Ibrahim ◽  
Mohd. Omar Ab. Kadir
Keyword(s):  
Palm Oil ◽  
Colloidal Particles ◽  
Oxygen Demand ◽  
Cod Removal ◽  
Palm Oil Mill Effluent ◽  
Trickling Filter ◽  
Biomass Hydrolysis ◽  
Removal Efficiencies ◽  
Palm Oil Mill ◽  
Hydrolysis Of

Kertas kerja ini membincangkan tentang kecekapan penuras cucur dalam merawat supernatan kumbahan kilang kelapa sawit (POME). Supernatan POME diperoleh menerusi dua jenis perawatan. Dalam perawatan 1, pengendapan graviti digunakan untuk menyingkir pepejal boleh mendak. Perawatan 2 digunakan untuk menyingkir pepejal boleh mendak dan gumpalan partikal dengan menggunakan 350 ppm alum. Influen dialurkan secara titisan pada biojisim yang terlekat pada penyokong pepejal rawak PVC setinggi 1 m. Penuras cucur berupaya menyingkir lebih daripada 90.0% dari keperluan oksigen biologi (BOD) dan keperluan oksigen kimia (COD) di bawah 1 m3/m2–hari. Pada 2.53 m3/m2–hari, influen dengan Perawatan 1 menghasilkan kecekapan penyingkiran COD sebanyak 40.3%, berbanding 83.1% bila Perawatan 2 digunakan. Perkara ini berlaku berikutan penyingkiran bahan organik tak boleh resap semasa Perawatan 2. Kecekapan penyingkiran menurun dengan meningkatnya bebanan hidraulik kerana wujudnya kelemahan dalam hidrolisis bahan tak boleh resap kepada substratum larut. Dengan edaran semula (α=1), penyingkiran BOD dan COD yang lebih tinggi dicapai di bawah 7 m3/m2–hari. Pencapaian ini disebabkan oleh bebanan organik yang lebih rendah serta pergedaran semula enzim dan biojisim yang aktif kepada sistem. Perawatan 2 menghasilkan enap cemar yang lebih tinggi kerana penukaran substratum boleh larut kepada biojisim tak boleh larut. Hidrolisis bahan organik tak boleh resap didapati berlaku secara aktif pada bahagian atas penuras cucur sementara bahagian bawahnya cenderung mengoksidakan substratum organik. Kata kunci: POME, turas cucur, bahan organik bolehresap, penggumpalan, alir semula This paper discusses the efficiency of a trickling filter to treat Palm Oil Mill Effluent (POME) supernatants. POME supernatants were obtained via two treatments. In Treatment 1, gravity sedimentation was used to remove settleable solids. In Treatment 2, both settleable solids and colloidal particles were removed using 350 ppm of alum. The influents were allowed to trickle over biomass attached to 1 m high random PVC solid support. Below 1 m3/m2–day, the filter demonstrated Biological Oxygen Demand (BOD) and Chemical Oxygen Demand (COD) removal efficiencies of more than 90.0%. At 2.53 m3/m2–day, the influent with Treatment 1 gave a COD removal efficiency of 40.3%, but increased to 83.1% when the influent with Treatment 2 was used. This was ascribed to the removal of non–diffusible organics during Treatment 2. The removal efficiencies decreased with an increase in hydraulic loading due to limitations in the hydrolysis of non–diffusibles into soluble substrates. With recirculation (α=1), higher BOD and COD removals were achieved below 7.0 m3/m2–day, attributed to lower organic loading and the recycling of active enzyme and biomass to the system. The influent with Treatment 2 demonstrated higher sludge production due to higher conversion of soluble substrates into insoluble biomass. Hydrolysis of non–diffusible organics mainly took place at upper reaches of the filter column while lower reaches were involved in oxidizing the organic subtrates. Key words: POME, trickling filter, diffusible organic, coagulation, recirculation

Cost–Effective Retrofit Of A Palm Oil Refinery Using Pinch Analysis

2012 ◽  
Author(s):  
Sharifah Rafidah Wan Alwi ◽  
Muhammad Azan Tamar Jaya ◽  
Zainuddin Abdul Manan
Keyword(s):  
Heat Exchanger ◽  
Palm Oil ◽  
Thermal Efficiency ◽  
Capital Investment ◽  
Heat Recovery ◽  
Cost Effective ◽  
Oil Refinery ◽  
Pinch Analysis ◽  
Heat Exchanger Network ◽  
Maximum Heat

Kilang penapisan minyak sawit lazimnya melibatkan proses penggunaan tenaga yang tinggi. Peningkatan kecekapan tenaga adalah amat penting bagi memastikan keuntungan tercapai. Kertas kerja ini menggunakan teknik analisis jepit bagi memaksimumkan penggunaan semula haba dan meningkatkan kecekapan sistem rangkaian haba sedia ada di kilang penghasilan minyak sawit, tertakluk kepada kekangan–kekangan proses. Langkah–langkah yang terlibat ialah penetapan sasaran guna semula haba maksimum diikuti dengan reka bentuk rangkaian haba yang ekonomik. Aplikasi teknik berkenaan kepada kilang penghasilan minyak sawit telah menghasilkan pengurangan penggunaan haba panas dan sejuk sebanyak 700 kW (21%), atau penjimatan kos utiliti sebanyak RM370,787, dengan pelaburan kapital sebanyak RM656,293 dan jangka pulangan balik selama 1.77 tahun. Kata kunci: Analisis jepit; minyak kelapa sawit; sedia ada; rangkaian pemindahan haba; kitar semula haba maksimum A palm oil refinery involves energy–intensive processes. Maximizing thermal efficiency of palm oil refinery is crucial for the plant profitability. This work implements a pinch analysis retrofit technique to maximize heat recovery and thermal efficiency of a palm oil refinery, subject to the existing process constraints. The procedures involve setting the maximum heat recovery targets and cost–effective retrofit of the heat exchanger network (HEN). Application of the technique on a palm oil refinery results in reduction of 700 kW (21%) heating and cooling loads or a saving of RM370,787, incurring a capital investment of about RM656,293 and a payback period of 1.77 years. Key words: Pinch analysis; palm oil; retrofit; heat exchanger network; maximum heat recovery

scholarly journals Delays and Cost Overruns Causes During Construction of Palm Oil Refinery Projects

2018 ◽  
Vol 203 ◽  
pp. 02004 ◽  
Author(s):  
Muhammad Sani Abdullah ◽  
Wesam S Alaloul ◽  
Mohd Shahir Liew ◽  
Bashar S Mohammed
Keyword(s):  
Construction Industry ◽  
Palm Oil ◽  
Developing Nations ◽  
Project Performance ◽  
Oil Refinery ◽  
Cost Overrun ◽  
Cost Overruns ◽  
Planning And Scheduling ◽  
Important Index ◽  
Common Problems

Delays and cost overruns are obviously common problems in the construction industry in several developed and developing nations. The purpose of this study is to identify factors cause delays and cost overruns in the construction of palm oil refinery projects in Malaysia. A questionnaire survey of a randomly selected sample was filled by 89 respondents. The questionnaire included 179 factors which classified into 13 groups. The degree of importance of the delays and cost overrun factors were evaluated and ranked by importance degree, based on the viewpoints of stakeholders. The data was analytically investigated by descriptive statistic methods and Relative Important Index (RII). The results of RII showed that Delays in subcontractor’s work, Lack of subcontractor skill, and Poor/inadequate planning and scheduling with RII 0.78, 0.77, and 0.75, respectively, are the most important causes. These causes represent the baseline margin for project management of palm oil refinery construction and development. According to these results, it is suggested that: project client should collaborate with contractors and simplify payments procedures to mitigate delays; coordinate continuously and enhance the association among project stakeholders are obligatory in order to improve the project performance.

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