HFOs as substitute for R-134a as working fluids in ORC power plants: A thermodynamic assessment and thermal stability analysis

2016 ◽  
Vol 103 ◽  
pp. 790-797 ◽  
Author(s):  
Costante M. Invernizzi ◽  
Paolo Iora ◽  
Markus Preißinger ◽  
Giampaolo Manzolini
Author(s):  
Juan Carlos Jouvin ◽  
Jeffrey Samuel ◽  
Igor Pioro

Currently, there are six Generation IV reactor systems under development worldwide: 1) Very-High-Temperature Reactor (VHTR); 2) Sodium-cooled Fast Reactor (SFR); 3) SuperCritical Water-cooled Reactor (SCWR), 4) Gas-cooled Fast Reactor (GFR), 5) Lead-cooled Fast Reactor (LFR); and 6) Molten Salt Reactor (MSR). Of these six systems, Canada has decided to pursue the SCWR as its choice for a Generation IV reactor, with some research being conducted on the VHTR. One main objective of SCWRs is to increase the thermal efficiency of current nuclear power plants from the 30–35% range to approximately 45–50%. In order to accomplish this, SCWRs are being designed to operate well above the critical point of water at pressures of 25 MPa and reactor outlet temperatures up to 625°C. These operating conditions also make the SCWR, along with the VHTR and other Generation IV systems, suitable candidates to support thermochemical hydrogen cogeneration. The design and operation of a facility capable of accurately and safely conducting experiments in supercritical water is a very expensive task. In order to facilitate our understanding of supercritical heat-transfer phenomena, modeling fluids such as carbon dioxide, refrigerants, ammonia and helium can be used to complement our knowledge of supercritical fluids. Some of these fluids, namely helium and carbon dioxide, have also been considered as potential working fluids in some special designs of reactors and power cycles. The objective of this paper is to investigate the feasibility of using alternative working fluids such as helium and Refrigerant-134a (R-134a) by comparing the fluid and transport properties with those of water. Operating conditions of SCWRs are scaled into those of the modeling fluid, R-134a, in order to provide proper SCWR-equivalent conditions. The equivalent properties for helium, which is one possible coolant for the VHTR, are also discussed. The thermophysical properties for selected working fluids are obtained from NIST REFPROP software. The results indicate that the thermophysical properties of the fluids undergo significant changes within the critical and pseudocritical regions similar to that of supercritical water. A sensitivity analysis for the effect of temperature on selected thermophysical properties at various supercritical pressures was performed.


2017 ◽  
Vol 4 ◽  
pp. 155-162
Author(s):  
Alec Ian Perry-Cain

In this paper the efficiency of three common working fluids in binary cycle geothermal power plants were compared by modeling the properties of the fluid within the working parameters of the Dora-II geothermal power plant. It was concluded that ammonia has the highest efficiency of the fluids and R-134a was the least efficient.


1980 ◽  
Vol 102 (4) ◽  
pp. 636-639 ◽  
Author(s):  
J. R. Parsons ◽  
J. C. Mulligan

A study of the onset of transient natural convection from a suddenly heated, horizontal cylinder of finite diameter is presented. The termination of the initial conductive and “locally” conuectiue heat transfer regime which precedes the onset of global natural convection is treated as a thermal stability phenomenon. An analysis is presented wherein the effects of finite cylinder diameter, cylinder heat capacity, and cylinder thermal conductivity are included in calculations of the convective delay time. A simple experimental apparatus is described and data presented. The thermal stability analysis is confirmed experimentally and data is presented which indicates localized natural convection prior to global motion.


Author(s):  
T. Junquera ◽  
J. Lesrel ◽  
M. Fouaidy ◽  
S. Bousson

Author(s):  
Yongcong Wu ◽  
Jiangjun Ruan ◽  
Yujia Gong ◽  
Mingyang Long ◽  
Peng Li

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