In situ preparation and fluorescence quenching properties of polythiophene/ZnO nanocrystals hybrids through atom-transfer radical polymerization and hydrolysis

2010 ◽  
Vol 256 (9) ◽  
pp. 2948-2955 ◽  
Author(s):  
Xiaoming Peng ◽  
Lin Zhang ◽  
Yiwang Chen ◽  
Fan Li ◽  
Weihua Zhou
2008 ◽  
Vol 23 (12) ◽  
pp. 3316-3322 ◽  
Author(s):  
Ayhan Oral ◽  
Talal Shahwan ◽  
Çetin Güler

The poly-2-hyroxyethyl methacrylate (PHEMA)/clay nanocomposite was synthesized by in situ atom transfer radical polymerization (ATRP) from initiator moieties immobilized within the silicate galleries of the clay particles. To produce organically modified montmorillonite (MMT) that has ATRP initiator moiety, a new catalyst that consists of quaternary ammonium salt moiety and an initiator moiety was synthesized. This initiator was intercalated into the interlayer spacing of the MMT. The polymerization reaction was carried out in a mixed solvent system consisting of methyl ethyl ketone and 1-propanol at 50 °C, using the initiator that has been already synthesized with a copper bromide catalyst. The 2, 2′-bipyridyl (bpy) complex was used as ligand. The products were characterized via Fourier transform infrared, nuclear magnetic resonance (1H NMR, 12C NMR), transmission electron microscopy, x-ray diffraction, thermogravimetric analysis, and differential scanning calorimetry.


2016 ◽  
Vol 8 (11) ◽  
pp. 2434-2440 ◽  
Author(s):  
Lin Gao ◽  
Wenjuan Han ◽  
Yongsheng Yan ◽  
Xiuying Li ◽  
Chunxiang Li ◽  
...  

A highly selective and sensitive molecular imprinted polymer sensor suitable for fluorescence detection of cyhalothrin samples has been successfully fabricated via atom transfer radical polymerization.


2014 ◽  
Vol 56 (6) ◽  
pp. 909-918 ◽  
Author(s):  
Khezrollah Khezri ◽  
Hossein Roghani-Mamaqani ◽  
Mohammadreza Sarsabili ◽  
Masoud Sobani ◽  
Seyed-Ataollah Mirshafiei-Langari

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