A route of alkylated carbon black with hydrophobicity, high dispersibility and efficient thermal conductivity

2021 ◽  
Vol 538 ◽  
pp. 147858
Author(s):  
Yanchen Li ◽  
Weiye Zhang ◽  
Junqi Zhao ◽  
Wenping Li ◽  
Beibei Wang ◽  
...  
2015 ◽  
Vol 6 (2) ◽  
pp. 159-172 ◽  
Author(s):  
Junping Song ◽  
Lianxiang Ma ◽  
Yan He ◽  
Wei Li ◽  
Shi-Chune Yao

2013 ◽  
Vol 753-755 ◽  
pp. 2379-2382
Author(s):  
Shi Meng Xu ◽  
Run Bo Ma ◽  
Jian Hua Du ◽  
Jun Hong Liu ◽  
Qi Jin

Filled the N330 carbon black, silica T80 carbon black and Al powder and Fe2O3 magnetic nanoparticles, the rubber composites on multi-component electromagnetic fillers were prepared according to orthogonal experiment analysis, and the preliminary experiment conclusions of the filler prescription designs were given; Based on the experiment design, the mechanical properties and thermal conductivity of the rubber composite were tested, and the testing results were analyzed by using variance analysis. Thus, the paper shows that the effects of N330 on rubber mechanical properties are significant, and the effects of Al powder on the rubber thermal conductivity are significant. Moreover, it is highly emphasized in this paper that the orthogonal experiment design must be carefully explored before the tests are executed.


2009 ◽  
Vol 87-88 ◽  
pp. 86-91 ◽  
Author(s):  
Yan He ◽  
Hai Tao Li ◽  
Lian Xiang Ma

The thermal conductivities of two rubbers filled with different carbon black (N330 and N375) are measured by experiments, and compared with five theoretical models calculated results. It is shown that thermal conductivity of carbon-filled rubber is obviously enhanced with increase of the volume filler fraction of carbon black and the thermal conductivity of carbon-filled rubber is related to the microstructure and morphology of carbon black. The estimated thermal conductivities by using the model proposed in our previous paper are of the same variation as the experimental ones of N330 carbon/rubber and N375 carbon/rubber during the range of volume fraction from 2% to 20%.


2018 ◽  
Vol 72 ◽  
pp. 24-31 ◽  
Author(s):  
Sohrab Azizi ◽  
Eric David ◽  
Michel F. Fréchette ◽  
Phuong Nguyen-Tri ◽  
Claudiane M. Ouellet-Plamondon

Nanomaterials ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 1168 ◽  
Author(s):  
David Cabaleiro ◽  
Samah Hamze ◽  
Jacek Fal ◽  
Marco A. Marcos ◽  
Patrice Estellé ◽  
...  

This paper presents the preparation and thermal/physical characterization of phase change materials (PCMs) based on poly(ethylene glycol) 400 g·mol−1 and nano-enhanced by either carbon black (CB), a raw graphite/diamond nanomixture (G/D-r), a purified graphite/diamond nanomixture (G/D-p) or nano-Diamond nanopowders with purity grades of 87% or 97% (nD87 and nD97, respectively). Differential scanning calorimetry and oscillatory rheology experiments were used to provide an insight into the thermal and mechanical changes taking place during solid-liquid phase transitions of the carbon-based suspensions. PEG400-based samples loaded with 1.0 wt.% of raw graphite/diamond nanomixture (G/D-r) exhibited the lowest sub-cooling effect (with a reduction of ~2 K regarding neat PEG400). The influences that the type of carbon-based nanoadditive and nanoparticle loading (0.50 and 1.0 wt.%) have on dynamic viscosity, thermal conductivity, density and surface tension were also investigated in the temperature range from 288 to 318 K. Non-linear rheological experiments showed that all dispersions exhibited a non-Newtonian pseudo-plastic behavior, which was more noticeable in the case of carbon black nanofluids at low shear rates. The highest enhancements in thermal conductivity were observed for graphite/diamond nanomixtures (3.3–3.6%), while nano-diamond suspensions showed the largest modifications in density (0.64–0.66%). Reductions in surface tension were measured for the two nano-diamond nanopowders (nD87 and nD97), while slight increases (within experimental uncertainties) were observed for dispersions prepared using the other three carbon-based nanopowders. Finally, a good agreement was observed between the experimental surface tension measurements performed using a Du Noüy ring tensiometer and a drop-shape analyzer.


2011 ◽  
Vol 221 ◽  
pp. 466-471 ◽  
Author(s):  
Jun Ping Song ◽  
Yan He ◽  
Lian Xiang Ma

Graphitized carbon black 40b2 and acetylene black were filled separately in natural rubber matrix for preparing vulcanized rubber. The thermal conductivity of both kinds of composites was studied considering filler loading and temperature. SEM and TEM were applied to observe morphology of the filler and composites. The experimental results show that thermal conductivity of acetylene black/rubber composites is much better than that of graphitized carbon black 40b2/rubber composites, which is opposite to the electric conduction properties. As filler loading increased, the difference increased, and when the filler loading is up to 40phr, the thermal conductivity value of acetylene black/rubber composite is 53% larger than the other one. TEM shows that acetylene black has more botryoidal structure, larger carbon black aggregates in size, and much looser surface than 40b2.Moreover, for acetylene black, particles contact by surface mainly, and for 40b2, particles contact by point mainly. SEM shows that the distribution of carbon black 40b2 in rubber matrix is much better than acetylene black. The better thermal conductivity for acetylene black is attributed to the higher structure, nonuniform distribution in rubber matrix and surface contact between particles.


2009 ◽  
Vol 87-88 ◽  
pp. 536-541 ◽  
Author(s):  
Jun Ping Song ◽  
Lian Xiang Ma

Five kinds of carbon black filled natural rubber were prepared, and thermal conductivity was studied considering two factors, which include temperature and volume percent of the filler. It was found that thermal conductivity had relevance to temperature and volume percent of carbon black, besides, structure and specific area of carbon black were also very important influencing factors. Moreover, reuniting phenomenon of nanometer grade of carbon black has much effect on thermal conductivity.


2011 ◽  
Vol 221 ◽  
pp. 373-376 ◽  
Author(s):  
Ze Peng Wang ◽  
Yan He

Thermal conductivity of rubber composites filled with CNTs (carbon nanotubes) and N234 CB (carbon black) were investigated. Result indicated that Thermal conductivity of NR (natural rubber) filled with CNTs is higher than that of NR filled with CB in the case of the same filling amount. CNTs can better improve the performance of thermal conduct of rubber composites than CB. The more the filling content of CNTs is, the higher thermal conductivity of NR composites.


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