A dual dynamic chamber system based on IBBCEAS for measuring fluxes of nitrous acid in agricultural fields in the North China Plain

2019 ◽  
Vol 196 ◽  
pp. 10-19 ◽  
Author(s):  
Ke Tang ◽  
Min Qin ◽  
Jun Duan ◽  
Wu Fang ◽  
Fanhao Meng ◽  
...  
2020 ◽  
Vol 20 (20) ◽  
pp. 12115-12131
Author(s):  
Ying Jiang ◽  
Likun Xue ◽  
Rongrong Gu ◽  
Mengwei Jia ◽  
Yingnan Zhang ◽  
...  

Abstract. Nitrous acid (HONO) is a significant precursor of atmospheric “detergent” OH radicals and plays a vital role in tropospheric chemistry. The current knowledge about daytime HONO sources is incomplete, and its impact on the tropospheric radical chemistry has not been fully quantified. Existing observational studies of HONO were mostly conducted at the surface, with few efforts focusing on the high-elevation atmosphere. In order to better understand the characteristics and sources of HONO in the upper boundary layer and lower free troposphere, two intensive field observations were carried out at the summit of Mt. Tai (1534 m a.s.l.), the peak of the North China Plain (NCP), in winter 2017 and spring 2018. HONO showed moderate concentration levels (average ± standard deviation: 0.15±0.15 and 0.13±0.15 ppbv), with maximum values of 1.14 and 3.23 ppbv in winter and spring, respectively. Diurnal variation patterns with broad noontime maxima and lower nighttime concentrations were observed during both campaigns, which is distinct from most of the previous studies at the ground level. The Lagrangian particle dispersion model (LPDM, WRF-FLEXPART v3.3) simulations indicated the combined effects of the planetary boundary layer evolution and valley breeze on the daytime HONO peak. A photostationary state (PSS) analysis suggested a strong unknown daytime HONO source with production rates of 0.45±0.25 ppb h−1 in winter and 0.64±0.49 ppb h−1 in spring. Correlation analysis supported the important role of photo-enhanced heterogeneous conversion of NO2 to HONO on the aerosol surface at this high-elevation site. HONO photolysis is the predominant primary source of OH radical and plays a major role in the radical chemistry at Mt. Tai. The model only considering a homogenous HONO source predicted much lower levels of the HOx radicals and atmospheric oxidation capacity than the model constrained with measured HONO data. This study sheds light on the characteristics, sources, chemistry, and impacts of HONO in the upper boundary layer and lower free troposphere in the NCP region.


Chemosphere ◽  
2021 ◽  
pp. 132034
Author(s):  
Tian Feng ◽  
Shuyu Zhao ◽  
Lang Liu ◽  
Xin Long ◽  
Chao Gao ◽  
...  

2016 ◽  
Vol 551-552 ◽  
pp. 197-204 ◽  
Author(s):  
Yuanyuan Zhang ◽  
Yujing Mu ◽  
Yizhen Zhou ◽  
Di Tian ◽  
Junfeng Liu ◽  
...  

Author(s):  
Min Xue ◽  
Jianzhong Ma ◽  
Guiqian Tang ◽  
Shengrui Tong ◽  
Bo Hu ◽  
...  

Sensors ◽  
2020 ◽  
Vol 21 (1) ◽  
pp. 46
Author(s):  
Gangqiang Zhang ◽  
Wei Zheng ◽  
Wenjie Yin ◽  
Weiwei Lei

The launch of GRACE satellites has provided a new avenue for studying the terrestrial water storage anomalies (TWSA) with unprecedented accuracy. However, the coarse spatial resolution greatly limits its application in hydrology researches on local scales. To overcome this limitation, this study develops a machine learning-based fusion model to obtain high-resolution (0.25°) groundwater level anomalies (GWLA) by integrating GRACE observations in the North China Plain. Specifically, the fusion model consists of three modules, namely the downscaling module, the data fusion module, and the prediction module, respectively. In terms of the downscaling module, the GRACE-Noah model outperforms traditional data-driven models (multiple linear regression and gradient boosting decision tree (GBDT)) with the correlation coefficient (CC) values from 0.24 to 0.78. With respect to the data fusion module, the groundwater level from 12 monitoring wells is incorporated with climate variables (precipitation, runoff, and evapotranspiration) using the GBDT algorithm, achieving satisfactory performance (mean values: CC: 0.97, RMSE: 1.10 m, and MAE: 0.87 m). By merging the downscaled TWSA and fused groundwater level based on the GBDT algorithm, the prediction module can predict the water level in specified pixels. The predicted groundwater level is validated against 6 in-situ groundwater level data sets in the study area. Compare to the downscaling module, there is a significant improvement in terms of CC metrics, on average, from 0.43 to 0.71. This study provides a feasible and accurate fusion model for downscaling GRACE observations and predicting groundwater level with improved accuracy.


2021 ◽  
Vol 20 (6) ◽  
pp. 1687-1700
Author(s):  
Li-chao ZHAI ◽  
Li-hua LÜ ◽  
Zhi-qiang DONG ◽  
Li-hua ZHANG ◽  
Jing-ting ZHANG ◽  
...  

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