Enhanced ex-situ biomethanation of hydrogen and carbon dioxide in a trickling filter bed reactor

2021 ◽  
pp. 108311
Author(s):  
Ajay Thapa ◽  
Jun-Gyu Park ◽  
Hang-Bae Jun
2020 ◽  
Author(s):  
Jennifer A. Rudd ◽  
Ewa Kazimierska ◽  
Louise B. Hamdy ◽  
Odin Bain ◽  
Sunyhik Ahn ◽  
...  

The utilization of carbon dioxide is a major incentive for the growing field of carbon capture. Carbon dioxide could be an abundant building block to generate higher value products. Herein, we describe the use of porous copper electrodes to catalyze the reduction of carbon dioxide into higher value products such as ethylene, ethanol and, notably, propanol. For <i>n</i>-propanol production, faradaic efficiencies reach 4.93% at -0.83 V <i>vs</i> RHE, with a geometric partial current density of -1.85 mA/cm<sup>2</sup>. We have documented the performance of the catalyst in both pristine and urea-modified foams pre- and post-electrolysis. Before electrolysis, the copper electrode consisted of a mixture of cuboctahedra and dendrites. After 35-minute electrolysis, the cuboctahedra and dendrites have undergone structural rearrangement. Changes in the interaction of urea with the catalyst surface have also been observed. These transformations were characterized <i>ex-situ</i> using scanning electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. We found that alterations in the morphology, crystallinity, and surface composition of the catalyst led to the deactivation of the copper foams.


2011 ◽  
Vol 414 ◽  
pp. 203-213 ◽  
Author(s):  
Xing Run Wang ◽  
Xiang Hua Yan ◽  
Qi Wang

It studied the geological properties and contamination characteristics of soil from contaminated sites of typical chromate plants in western plateau of China. The results indicated that in the shallow part of 0-4m, it was mainly loess-like soil and in the depth of 4-18m, it was mainly gravels and pebbles. The soil had better permeability and ex-situ washing treatment is recommended. The soil was severely contaminated and the concentration of chrome (Ⅵ) was as high as 16,000mg/kg. Based on the analysis, it developed a two-stage demonstration project of countercurrent ex-situ washing plus chemical stabilization with daily capacity of 20m3 soil and a demonstration project of chemical reduction and precipitation plus advanced treatment of filter bed with daily capacity of 200m3 wastewater. After treatment, the concentration of chrome (Ⅵ) in soil was less than 100mg/kg and that in water was reduced to below 0.05mg/L from 1,000mg/L, which can meet the requirements of third-grade groundwater quality standard.


2020 ◽  
Vol 88 ◽  
pp. 102042
Author(s):  
Davood Karimi ◽  
Ep Eding ◽  
Andre J.A. Aarnink ◽  
Peter Groor Koerkamp ◽  
Johan Verreth

2005 ◽  
Vol 578 (1) ◽  
pp. 87-94 ◽  
Author(s):  
Eduardo R. Pérez ◽  
Jarem R. Garcia ◽  
Daniel R. Cardoso ◽  
Bruce R. McGarvey ◽  
Elisete A. Batista ◽  
...  
Keyword(s):  
Ex Situ ◽  

2002 ◽  
Vol 29 (4) ◽  
pp. 543-553 ◽  
Author(s):  
Hasnaa Jorio ◽  
Guy Viel ◽  
Michèle Heitz

A new filtering material has been tested for its biofiltration performance for the treatment of air contaminated with the three isomers of xylene. The biofilter, operated at an empty bed residence time of 68 s and for xylene concentrations up to 6.7 g·m–3, allowed a xylene load and reduction of more than 92% for concentrations up to 2 g·m–3, and more than 65% for concentrations less than 6.7 g·m–3. The maximum xylene elimination capacity is of 236 g·m–3·h–1. In general, the removal efficiency of meta-xylene is the highest whereas the removal efficiency of ortho-xylene is the lowest. At high xylene concentration, the increase of biodegradation intensity leads to the accumulation of a voluminous biofilm around the filtering particles, causing the clogging of the filter bed, the progressive retention of the nutritive solution in the superior parts of the bed, and the drying of the inferior parts of the bed. These observations have showed that a biofilter operating at high elimination capacities requires a meticulous control of the humidity of the filtering bed and a regular draining of the biomass excess. Key words: biofiltration, xylene, ortho, meta, and para isomers, carbon dioxide, biofilm, pressure drop, biomass excess.[Journal translation]


2020 ◽  
Author(s):  
Jennifer A. Rudd ◽  
Ewa Kazimierska ◽  
Louise B. Hamdy ◽  
Odin Bain ◽  
Sunyhik Ahn ◽  
...  

The utilization of carbon dioxide is a major incentive for the growing field of carbon capture. Carbon dioxide could be an abundant building block to generate higher value products. Herein, we describe the use of porous copper electrodes to catalyze the reduction of carbon dioxide into higher value products such as ethylene, ethanol and, notably, propanol. For <i>n</i>-propanol production, faradaic efficiencies reach 4.93% at -0.83 V <i>vs</i> RHE, with a geometric partial current density of -1.85 mA/cm<sup>2</sup>. We have documented the performance of the catalyst in both pristine and urea-modified foams pre- and post-electrolysis. Before electrolysis, the copper electrode consisted of a mixture of cuboctahedra and dendrites. After 35-minute electrolysis, the cuboctahedra and dendrites have undergone structural rearrangement. Changes in the interaction of urea with the catalyst surface have also been observed. These transformations were characterized <i>ex-situ</i> using scanning electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. We found that alterations in the morphology, crystallinity, and surface composition of the catalyst led to the deactivation of the copper foams.


2021 ◽  
Vol 12 ◽  
Author(s):  
Washington Logroño ◽  
Denny Popp ◽  
Marcell Nikolausz ◽  
Paul Kluge ◽  
Hauke Harms ◽  
...  

Ex situ biomethanation allows the conversion of hydrogen produced from surplus electricity to methane. The flexibility of the process was recently demonstrated, yet it is unknown how intermittent hydrogen feeding impacts the functionality of the microbial communities. We investigated the effect of starvation events on the hydrogen consumption and methane production rates (MPRs) of two different methanogenic communities that were fed with hydrogen and carbon dioxide. Both communities showed functional resilience in terms of hydrogen consumption and MPRs upon starvation periods of up to 14 days. The origin of the inoculum, community structure and dominant methanogens were decisive for high gas conversion rates. Thus, pre-screening a well performing inoculum is essential to ensure the efficiency of biomethanation systems operating under flexible gas feeding regimes. Our results suggest that the type of the predominant hydrogenotrophic methanogen (here: Methanobacterium) is important for an efficient process. We also show that flexible biomethanation of hydrogen and carbon dioxide with complex microbiota is possible while avoiding the accumulation of acetate, which is relevant for practical implementation. In our study, the inoculum from an upflow anaerobic sludge blanket reactor treating wastewater from paper industry performed better compared to the inoculum from a plug flow reactor treating cow manure and corn silage. Therefore, the implementation of the power-to-gas concept in wastewater treatment plants of the paper industry, where biocatalytic biomass is readily available, may be a viable option to reduce the carbon footprint of the paper industry.


Entecho ◽  
2021 ◽  
Vol 4 (1) ◽  
pp. 1-9
Author(s):  
Eva-Žofie Hlinková ◽  
Zdeněk Varga ◽  
Jana Zábranská

Přechod ze stávajících neobnovitelných zdrojů elektrické energie na zdroje obnovitelné se jeví jako vhodné řešení pro celosvětově narůstající spotřebu energie. Udržitelná technologie pro zpracování organických odpadů formou anaerobní fermentace produkuje bioplyn, z kterého se odstraněním oxidu uhličitého získává biometan – energeticky bohatý plyn kompatibilní se zemním plynem a využitelný jako biopalivo. Zaváděním externího vodíku, získaného z přebytečné energie z obnovitelných zdrojů, do procesu anaerobní fermentace dochází pomocí hydrogenotrofních metanogenů k redukci oxidu uhličitého na metan, čímž se zvyšuje výhřevnost bioplynu v ideálním případě až na biometan. V rámci této práce byla zkoumána technologie obohacování bioplynu pomocí vodíku přímým zaváděním do fermentoru tzv. metoda in-situ a s využitím externího bioreaktoru tzv. metoda ex-situ Získané výsledky z provozu laboratorních modelů insitu a ex-situ bioreaktoru poslouží k sestrojení poloprovozního modelu této technologie pro následné převedení do praxe. Abstract - EN The transition from existing sources of electricity to renewables seems to be a suitable solution for the global increase of energy consumption. Sustainable technology of anaerobic fermentation for the treatment of organic wastes produces biogas, from which is by removing carbon dioxide obtained biomethane – energy-rich gas compatible with natural gas and can be used as biofuel. Hydrogen obtained by using excess energy production from renewable sources, can be introduce into the anaerobic fermentation process. Hydrogenotrophic methanogens use external hydrogen for reduction of carbon dioxide to methane, which increases energetical potencial of biogas, ideally up to the level of biomethane. In this work, the technology of enrichment of biogas with hydrogen by direct introduction into the fermenter, the “in-situ” method and with the use of an external bioreactor, the “ex-situ method,” was investigated. The results obtained from the operation of laboratory models of insitu and ex-situ bioreactors will be used to build a pilot model of this technology for subsequent implementation in practice.


2018 ◽  
Vol 2 (12) ◽  
pp. 2733-2741 ◽  
Author(s):  
Ming Zhao ◽  
Xu He ◽  
Guozhao Ji ◽  
Yinqiang Song ◽  
Xiao Zhao

Zirconia incorporation greatly enhances the sintering resistance of CaO.


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