scholarly journals Gas-Phase Conformations of a Huntingtin N-Terminal Peptide Reveal Condensed-Phase Heterogeneity with and without the Presence of a PPII Helix

2015 ◽  
Vol 108 (2) ◽  
pp. 385a
Author(s):  
James R. Arndt ◽  
Samaneh G. Kondalaji ◽  
Olivia Sarver ◽  
Megan M. Maurer ◽  
Arlo Parker ◽  
...  
Keyword(s):  
Gas Phase ◽  
Condensed Phase ◽  
Phase Heterogeneity

Preparation and Pyrolysis of Stereoisomeric Bromobicyclo[n.1.0]alkanes ( n = 6, 8 , 10)

1987 ◽  
Vol 42 (4) ◽  
pp. 489-494 ◽  
Author(s):  
Eckehard V. Dehmlow ◽  
Roland Kramer
Keyword(s):  
Thermal Stability ◽  
Gas Phase ◽  
Condensed Phase ◽  
Secondary Products ◽  
Gas Phase Reactions ◽  
Stereoselective Reduction ◽  
Derivatives Of ◽  
Thermal Stability Of

Abstract The title compounds la-3c were prepared by stereoselective reduction of the respective dibromides. Pyrolysis gave allylic bromides (8, 9, 11) as primary and dienes (10, 12) as secondary products. Product ratios were independent of the stereochemistry of the starting materials. No differences of the rearrangement rates of the stereoisomers were observed in gas phase reactions of the derivatives of bicyclo[6.1.0]- and bicyclo[8.1.0]alkanes. With the larger bicyclo[10.1.0] derivatives, however, distinct differences in the thermal stability of cis-trans-isomers4c/5c or 2c/3c were found in condensed phase.

scholarly journals Surface Reactions in Interstellar Space

2002 ◽  
Vol 12 ◽  
pp. 55-57 ◽  
Author(s):  
Eric Herbst
Keyword(s):  
Surface Chemistry ◽  
Gas Phase ◽  
Condensed Phase ◽  
Current Knowledge ◽  
Surface Reactions ◽  
Future Research ◽  
Interstellar Space ◽  
Interstellar Molecules ◽  
Grain Surface

AbstractIt is impossible to explain the abundances of some gas-phase and most condensed-phase interstellar molecules without the use of grain chemistry. Nevertheless, grain-surface chemistry is relatively poorly understood for a variety of reasons. Our current knowledge of this chemistry and its use in interstellar models is discussed along with specific needs for future research.

Carbanion Rearrangements in the Gas Phase: The Unusual Claisen Rearrangement of Deprotonated Allyl Vinyl Ether

1990 ◽  
Vol 43 (9) ◽  
pp. 1479 ◽  
Author(s):  
PCH Eichinger ◽  
JH Bowie
Keyword(s):  
Gas Phase ◽  
Vinyl Ether ◽  
Condensed Phase ◽  
Claisen Rearrangement ◽  
Negative Ions ◽  
Marked Contrast ◽  
Wittig Rearrangement ◽  
Major Reaction

Allyl vinyl ether is reported to undergo a facile Wittig rearrangement to yield penta-1,4-dien-3-ol under base- catalysed conditions in the condensed phase. In marked contrast, the Wittig rearrangement is not a major reaction in the gas phase. Instead, initial rearrangement occurs by a Claisen process and subsequent fragmentations involve some of the most complex interconversions yet proposed for negative ions.

Determination of the Force Constants of Non-linear XY2 Molecules in the Gas-Phase by the GF Matrix Method

2004 ◽  
Vol 59 (9) ◽  
pp. 621-622 ◽  
Author(s):  
Fatih Ucun ◽  
Vesile Gūçlü
Keyword(s):  
Gas Phase ◽  
Condensed Phase ◽  
Matrix Method ◽  
Solid Phase ◽  
Force Constants ◽  
Matrix Solution ◽  
The Matrix ◽  
Newton Raphson ◽  
Raphson Method

The force constants of the internal coordinates of nonlinear XY2 molecules in the gas-phase were calculated by using the GF matrix method. The matrix solution was carried out by means a computer program built relative to the Newton-Raphson method and the calculations were listed in a table. The force constants of some molecules in the liquidand solid- phase were also found and compared with these ones, and it was seen that the force constants for more condensed phase are lower as in an agreement with having its lower frequency.

scholarly journals Modelling multi-phase halogen chemistry in the remote marine boundary layer: investigation of the influence of aerosol size resolution on predicted gas- and condensed-phase chemistry

2009 ◽  
Vol 9 (2) ◽  
pp. 5289-5320 ◽  
Author(s):  
D. Lowe ◽  
D. Topping ◽  
G. McFiggans
Keyword(s):  
Boundary Layer ◽  
Gas Phase ◽  
Condensed Phase ◽  
Significant Influence ◽  
Marine Boundary Layer ◽  
Turnover Rates ◽  
Gas Phase Chemistry ◽  
Size Dependent ◽  
Multi Phase ◽  
Phase Chemistry

Abstract. A coupled box model of photochemistry and aerosol microphysics which explicitly accounts for size-dependent chemical properties of the condensed-phase has been developed to simulate the multi-phase chemistry of chlorine, bromine and iodine in the marine boundary layer (MBL). The model contains separate seasalt and non-seasalt modes, each of which may be composed of 1–16 size-sections. By comparison of gaseous and aerosol compositions predicted using different size-resolutions with both fixed and size-dependent aerosol turnover rates, it was found that, for halogen-activation processes, the physical property initialisation of the aerosol-mode has a significant influence on gas-phase chemistry. Failure to adequately represent the appropriate physical properties can lead to substantial errors in gas-phase chemistry. The size-resolution of condensed-phase composition has a less significant influence on gas-phase chemistry.

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