Bioresponsive metal–organic frameworks: Rational design and function

2020 ◽  
pp. 213682
Author(s):  
S.M. Morozova ◽  
A. Sharsheeva ◽  
M.I. Morozov ◽  
A.V. Vinogradov ◽  
E. Hey-Hawkins
Keyword(s):  
Rational Design ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
And Function

A Molecular Artisans Guide to Supramolecular Coordination Complexes and Metal Organic Frameworks

2015 ◽  
Vol 03 (01n02) ◽  
pp. 1540004 ◽  
Author(s):  
Xialu Wu ◽  
David J. Young ◽  
T. S. Andy Hor
Keyword(s):  
Chemical Reactivity ◽  
Metal Organic Frameworks ◽  
Building Blocks ◽  
Coordination Complexes ◽  
Large Molecules ◽  
Molecular Building Blocks ◽  
Supramolecular Coordination ◽  
Metal Organic ◽  
Molecular Synthesis ◽  
And Function

As molecular synthesis advances, we are beginning to learn control of not only the chemical reactivity (and function) of molecules, but also of their interactions with other molecules. It is this basic idea that has led to the current explosion of supramolecular science and engineering. Parallel to this development, chemists have been actively pursuing the design of very large molecules using basic molecular building blocks. Herein, we review the general development of supramolecular chemistry and particularly of two new branches: supramolecular coordination complexes (SCCs) and metal organic frameworks (MOFs). These two fields are discussed in detail with typical examples to illustrate what is now possible and what challenges lie ahead for tomorrow's molecular artisans.

Rational design of metal-organic frameworks to deliver methotrexate for targeted rheumatoid arthritis therapy

2021 ◽  
Vol 330 ◽  
pp. 119-131
Author(s):  
Lina Guo ◽  
Yang Chen ◽  
Ting Wang ◽  
Yu Yuan ◽  
Yihua Yang ◽  
...  
Keyword(s):  
Rheumatoid Arthritis ◽  
Rational Design ◽  
Metal Organic Frameworks ◽  
Metal Organic

Electrochemical oxidation of 5-hydroxymethylfurfural on ternary metal-organic frameworks nanoarrays: enhancement from electronic structure modulation

2021 ◽  
Author(s):  
Xiaojue Bai ◽  
Wenxiu He ◽  
Xingyu Lu ◽  
Yu Fu ◽  
Wei Qi
Keyword(s):  
Electronic Structure ◽  
Carboxylic Acid ◽  
Electrochemical Oxidation ◽  
Rational Design ◽  
Metal Organic Frameworks ◽  
Highly Active ◽  
Ternary Metal ◽  
Metal Organic ◽  
Structure Modulation

The rational design and exploitation of highly active and stable catalysts for the electrochemical oxidation of biomass-derived 5-hydroxymethylfurfural (HMF) to valuable chemical 2,5-furandi-carboxylic acid (FDCA), is of great significance. Herein,...

scholarly journals Rational Design of Pore Size and Functionality in a Series of Isoreticular Zwitterionic Metal–Organic Frameworks

2018 ◽  
Vol 30 (22) ◽  
pp. 8332-8342 ◽  
Author(s):  
Darpandeep Aulakh ◽  
Timur Islamoglu ◽  
Veronica F. Bagundes ◽  
Juby R. Varghese ◽  
Kyle Duell ◽  
...  
Keyword(s):  
Pore Size ◽  
Rational Design ◽  
Metal Organic Frameworks ◽  
Metal Organic

Postsynthetic Approach for the Rational Design of Chiral Ferroelectric Metal–Organic Frameworks

2017 ◽  
Vol 139 (24) ◽  
pp. 8098-8101 ◽  
Author(s):  
Marta Mon ◽  
Jesús Ferrando-Soria ◽  
Michel Verdaguer ◽  
Cyrille Train ◽  
Charles Paillard ◽  
...  
Keyword(s):  
Rational Design ◽  
Metal Organic Frameworks ◽  
Metal Organic

Rational design of 1-D metal–organic frameworks based on the novel pyrimidine-4,6-dicarboxylate ligand. New insights into pyrimidine through magnetic interaction

2007 ◽  
pp. 2669-2680 ◽  
Author(s):  
Garikoitz Beobide ◽  
Oscar Castillo ◽  
Antonio Luque ◽  
Urko García-Couceiro ◽  
Juan P. García-Terán ◽  
...  
Keyword(s):  
Rational Design ◽  
Metal Organic Frameworks ◽  
Magnetic Interaction ◽  
The Novel ◽  
Metal Organic ◽  
Dicarboxylate Ligand

A rational design of efficient trifunctional electrocatalysts derived from tailored Co2+-functionalized anionic metal–organic frameworks

2020 ◽  
Vol 49 (7) ◽  
pp. 2280-2289 ◽  
Author(s):  
Miaojie Shi ◽  
Jun-Hao Wang ◽  
Ying Zhang ◽  
Xian-Ming Zhang
Keyword(s):  
Water Splitting ◽  
Rational Design ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Organic Framework

An efficient trifunctional electrocatalyst was fabricated through pyrolyzing a rationally designed Co2+- functionalized anionic metal–organic framework, yielding excellent performances in Zn–air batteries and water-splitting applications.

scholarly journals Rational design of metal–organic frameworks with anticipated porosities and functionalities

CrystEngComm ◽  
2014 ◽  
Vol 16 (20) ◽  
pp. 4069-4083 ◽  
Author(s):  
Muwei Zhang ◽  
Mathieu Bosch ◽  
Thomas Gentle III ◽  
Hong-Cai Zhou
Keyword(s):  
Rational Design ◽  
Metal Organic Frameworks ◽  
Structure Property ◽  
Systematic Overview ◽  
Structure Property Relationships ◽  
Recent Advances ◽  
Metal Organic

This highlight review will outline the recent advances on rational design of MOFs from both our and other groups based on their structure–property relationships, and provide a systematic overview of different methods for rational design of MOFs with desired porosities and functionalities.

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