Rational Design of Pore Size and Functionality in a Series of Isoreticular Zwitterionic Metal–Organic Frameworks

The rational design and exploitation of highly active and stable catalysts for the electrochemical oxidation of biomass-derived 5-hydroxymethylfurfural (HMF) to valuable chemical 2,5-furandi-carboxylic acid (FDCA), is of great significance. Herein,...

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The influence of the pore size in Metal−Organic Frameworks in adsorption and separation of hydrogen sulphide: A molecular simulation study

Microporous and Mesoporous Materials ◽

10.1016/j.micromeso.2018.06.002 ◽

2018 ◽

Vol 271 ◽

pp. 160-168 ◽

Cited By ~ 17

Author(s):

Thaer M. Al-Jadir ◽

Flor R. Siperstein

Keyword(s):

Pore Size ◽

Molecular Simulation ◽

Hydrogen Sulphide ◽

Simulation Study ◽

Metal Organic Frameworks ◽

Metal Organic

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Boosting Interfacial Charge-Transfer Kinetics for Efficient Overall CO2 Photoreduction via Rational Design of Coordination Spheres on Metal–Organic Frameworks

Journal of the American Chemical Society ◽

10.1021/jacs.0c05530 ◽

2020 ◽

Vol 142 (28) ◽

pp. 12515-12523 ◽

Cited By ~ 15

Author(s):

Zhi-Bin Fang ◽

Ting-Ting Liu ◽

Junxue Liu ◽

Shengye Jin ◽

Xin-Ping Wu ◽

...

Keyword(s):

Charge Transfer ◽

Rational Design ◽

Metal Organic Frameworks ◽

Interfacial Charge Transfer ◽

Co2 Photoreduction ◽

Metal Organic ◽

Coordination Spheres ◽

Interfacial Charge

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Pore Size Reduction in Zirconium Metal–Organic Frameworks for Ethylene/Ethane Separation

ACS Sustainable Chemistry & Engineering ◽

10.1021/acssuschemeng.9b00062 ◽

2019 ◽

Vol 7 (7) ◽

pp. 7118-7126 ◽

Cited By ~ 16

Author(s):

Yuxiang Wang ◽

Shuai Yuan ◽

Zhigang Hu ◽

Tanay Kundu ◽

Jian Zhang ◽

...

Keyword(s):

Pore Size ◽

Metal Organic Frameworks ◽

Size Reduction ◽

Metal Organic ◽

Zirconium Metal

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Coupling Structural and Adsorption Properties of Metal–Organic Frameworks: From Pore Size Distribution to Pore Type Distribution

ACS Applied Materials & Interfaces ◽

10.1021/acsami.0c01682 ◽

2020 ◽

Vol 12 (13) ◽

pp. 15595-15605 ◽

Cited By ~ 1

Author(s):

Silvio Dantas ◽

Alexander V. Neimark

Keyword(s):

Pore Size Distribution ◽

Pore Size ◽

Size Distribution ◽

Metal Organic Frameworks ◽

Adsorption Properties ◽

Type Distribution ◽

Metal Organic

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Tailoring the pore geometry and chemistry in microporous metal–organic frameworks for high methane storage working capacity

Chemical Communications ◽

10.1039/c9cc06239d ◽

2019 ◽

Vol 55 (76) ◽

pp. 11402-11405 ◽

Cited By ~ 2

Author(s):

Kai Shao ◽

Jiyan Pei ◽

Jia-Xin Wang ◽

Yu Yang ◽

Yuanjing Cui ◽

...

Keyword(s):

Pore Size ◽

Metal Organic Frameworks ◽

Pore Geometry ◽

Methane Storage ◽

Working Capacity ◽

Metal Organic

We realized that engineering the pore size/geometry and chemistry in a series of MOFs can optimize the volumetric methane storage working capacity.

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Gas Sensing Properties of Mg-Incorporated Metal–Organic Frameworks

Sensors ◽

10.3390/s19153323 ◽

2019 ◽

Vol 19 (15) ◽

pp. 3323 ◽

Cited By ~ 4

Author(s):

Jae-Hyoung Lee ◽

Thanh-Binh Nguyen ◽

Duy-Khoi Nguyen ◽

Jae-Hun Kim ◽

Jin-Young Kim ◽

...

Keyword(s):

Pore Size ◽

Gas Sensors ◽

Gas Sensing ◽

High Surface ◽

Metal Organic Frameworks ◽

Kinetic Properties ◽

Sensing Properties ◽

Sensing Applications ◽

Gas Sensing Properties ◽

Metal Organic

The gas sensing properties of two novel series of Mg-incorporated metal–organic frameworks (MOFs), termed Mg-MOFs-I and -II, were assessed. The synthesized iso-reticular type Mg-MOFs exhibited good crystallinity, high thermal stability, needle-shape morphology and high surface area (up to 2900 m2·g−1), which are promising for gas sensing applications. Gas-sensing studies of gas sensors fabricated from Mg-MOFs-II revealed better sensing performance, in terms of the sensor dynamics and sensor response, at an optimal operating temperature of 200 °C. The MOF gas sensor with a larger pore size and volume showed shorter response and recovery times, demonstrating the importance of the pore size and volume on the kinetic properties of MOF-based gas sensors. The gas-sensing results obtained in this study highlight the potential of Mg-MOFs gas sensors for the practical monitoring of toxic gases in a range of environments.

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