Interfacial reinforcement structure design towards ultrastable lithium storage in MoS2-based composited electrode

2021 ◽  
Vol 416 ◽  
pp. 129094
Author(s):  
Chunyan Cao ◽  
Huilong Dong ◽  
Fanghua Liang ◽  
Yu Zhang ◽  
Wei Zhang ◽  
...  
2021 ◽  
Author(s):  
Wencai Zhao ◽  
Y.F. Yuan ◽  
S.M. Yin ◽  
Gaoshen Cai ◽  
S.Y. Guo

Abstract Hollow mesoporous nanospheres MoO2/C are successfully constructed through metal chelating reaction between molybdenum acetylacetone and glycerol as well as the Kirkendall effect induced by diammonium hydrogen phosphate. MoO2 nanoparticles coupled by amorphous carbon are assembled to unique zigzag-like hollow mesoporous nanosphere with large specific surface area of 147.7 m2 g-1 and main pore size of 8.7 nm. The content of carbon is 9.1%. As anode material for lithium-ion batteries, the composite shows high specific capacity and excellent cycling performance. At 0.2 A g-1, average discharge capacity stabilizes at 1092 mAh g-1. At 1 A g-1 after 700 cycles, the discharge capacity still reaches 512 mAh g-1. Impressively, the composite preserves intact after 700 cycles. Even at 5 A g-1, the discharge capacity can reach 321 mAh g-1, exhibiting superior rate capability. Various kinetics analyses demonstrate that in electrochemical reaction, the proportion of the surface capacitive effect is higher, and the composite has relatively high diffusion coefficient of Li ions and fast faradic reaction kinetics. Excellent lithium storge performance is attributed to the synergistic effect of zigzag-like hollow mesoporous nanosphere and amorphous carbon, which improves reaction kinetics, structure stability and electronic conductivity of MoO2. The present work provides a new useful structure design strategy for advanced energy storage application of MoO2.


2017 ◽  
Vol 9 (18) ◽  
pp. 15470-15476 ◽  
Author(s):  
Chaoji Chen ◽  
Linfeng Peng ◽  
Yiju Li ◽  
Lei Zhang ◽  
Jingwei Xiang ◽  
...  

Author(s):  
A. Ferrerón Labari ◽  
D. Suárez Gracia ◽  
V. Viñals Yúfera

In the last years, embedded systems have evolved so that they offer capabilities we could only find before in high performance systems. Portable devices already have multiprocessors on-chip (such as PowerPC 476FP or ARM Cortex A9 MP), usually multi-threaded, and a powerful multi-level cache memory hierarchy on-chip. As most of these systems are battery-powered, the power consumption becomes a critical issue. Achieving high performance and low power consumption is a high complexity challenge where some proposals have been already made. Suarez et al. proposed a new cache hierarchy on-chip, the LP-NUCA (Low Power NUCA), which is able to reduce the access latency taking advantage of NUCA (Non-Uniform Cache Architectures) properties. The key points are decoupling the functionality, and utilizing three specialized networks on-chip. This structure has been proved to be efficient for data hierarchies, achieving a good performance and reducing the energy consumption. On the other hand, instruction caches have different requirements and characteristics than data caches, contradicting the low-power embedded systems requirements, especially in SMT (simultaneous multi-threading) environments. We want to study the benefits of utilizing small tiled caches for the instruction hierarchy, so we propose a new design, ID-LP-NUCAs. Thus, we need to re-evaluate completely our previous design in terms of structure design, interconnection networks (including topologies, flow control and routing), content management (with special interest in hardware/software content allocation policies), and structure sharing. In CMP environments (chip multiprocessors) with parallel workloads, coherence plays an important role, and must be taken into consideration.


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