Recent advances in molecular oxygen activation via photocatalysis and its application in oxidation reactions

2021 ◽  
Vol 421 ◽  
pp. 129915
Author(s):  
Qi Li ◽  
Fa-tang Li
Keyword(s):  
Molecular Oxygen ◽  
Oxygen Activation ◽  
Oxidation Reactions ◽  
Recent Advances

Insights into oxygen activation on metal clusters for catalyst design

2021 ◽  
Author(s):  
LiXin Chen ◽  
Zi Wen ◽  
Zhi Wen Chen ◽  
Qing Jiang ◽  
Chandra Veer Singh
Keyword(s):  
Metal Clusters ◽  
Aerobic Oxidation ◽  
Oxygen Activation ◽  
Vital Role ◽  
Catalyst Design ◽  
Activation Mechanism ◽  
Oxidation Reactions

The activation mechanism of O2 molecules plays a vital role in the development of catalysts for aerobic oxidation reactions. To gain insights into the activation mechanism of O2, the square...

Giant Electron–Hole Interactions in Confined Layered Structures for Molecular Oxygen Activation

2017 ◽  
Vol 139 (13) ◽  
pp. 4737-4742 ◽  
Author(s):  
Hui Wang ◽  
Shichuan Chen ◽  
Dingyu Yong ◽  
Xiaodong Zhang ◽  
Shuang Li ◽  
...  
Keyword(s):  
Molecular Oxygen ◽  
Oxygen Activation ◽  
Layered Structures ◽  
Electron Hole

scholarly journals Water-assisted oxygen activation during selective oxidation reactions

2016 ◽  
Vol 13 ◽  
pp. 100-108 ◽  
Author(s):  
Hung-Vu Tran ◽  
Hieu A Doan ◽  
Bert D Chandler ◽  
Lars C Grabow
Keyword(s):  
Selective Oxidation ◽  
Oxygen Activation ◽  
Oxidation Reactions ◽  
Selective Oxidation Reactions

scholarly journals Recent Advances in Homogeneous Metal-Catalyzed Aerobic C–H Oxidation of Benzylic Compounds

Catalysts ◽  
2018 ◽  
Vol 8 (12) ◽  
pp. 640 ◽  
Author(s):  
Garazi Urgoitia ◽  
Raul SanMartin ◽  
María Herrero ◽  
Esther Domínguez
Keyword(s):  
Molecular Oxygen ◽  
Aerobic Oxidation ◽  
Key Factors ◽  
Reaction Conditions ◽  
Aromatic Ketones ◽  
Recent Advances ◽  
Metal Catalyzed

Csp3–H oxidation of benzylic methylene compounds is an established strategy for the synthesis of aromatic ketones, esters, and amides. The need for more sustainable oxidizers has encouraged researchers to explore the use of molecular oxygen. In particular, homogeneous metal-catalyzed aerobic oxidation of benzylic methylenes has attracted much attention. This account summarizes the development of this oxidative strategy in the last two decades, examining key factors such as reaction yields, substrate:catalyst ratio, substrate scope, selectivity over other oxidation byproducts, and reaction conditions including solvents and temperature. Finally, several mechanistic proposals to explain the observed results will be discussed.

Sign in / Sign up

Export Citation Format

Share Document