Carbon Dioxide Solid-Phase Embedding Reaction of Silicon-Carbon Nanoporous Composites for Lithium-Ion Batteries

Abstract The high-nickel cathode material of LiNi0.8Co0.15Al0.05O2 (LNCA) has a prospective application for lithium-ion batteries due to the high capacity and low cost. However, the side reaction between the electrolyte and the electrode seriously affects the cycling stability of lithium-ion batteries. In this work, Ni2+ preoxidation and the optimization of calcination temperature were carried out to reduce the cation mixing of LNCA, and solid-phase Al-doping improved the uniformity of element distribution and the orderliness of the layered structure. In addition, the surface of LNCA was homogeneously modified with ZnO coating by a facile wet-chemical route. Compared to the pristine LNCA, the optimized ZnO-coated LNCA showed excellent electrochemical performance with the first discharge-specific capacity of 187.5 mA h g−1, and the capacity retention of 91.3% at 0.2C after 100 cycles. The experiment demonstrated that the improved electrochemical performance of ZnO-coated LNCA is assigned to the surface coating of ZnO which protects LNCA from being corroded by the electrolyte during cycling.

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High performance silicon carbon composite anode materials for lithium ion batteries

Journal of Power Sources ◽

10.1016/j.jpowsour.2008.12.068 ◽

2009 ◽

Vol 189 (1) ◽

pp. 16-21 ◽

Cited By ~ 43

Author(s):

Zhaojun Luo ◽

Dongdong Fan ◽

Xianlong Liu ◽

Huanyu Mao ◽

Caifang Yao ◽

...

Keyword(s):

Lithium Ion Batteries ◽

Anode Materials ◽

High Performance ◽

Lithium Ion ◽

Carbon Composite ◽

Composite Anode ◽

Silicon Carbon

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Nanosized core/shell silicon@carbon anode material for lithium ion batteries with polyvinylidene fluoride as carbon source

Journal of Materials Chemistry ◽

10.1039/b921979j ◽

2010 ◽

Vol 20 (16) ◽

pp. 3216 ◽

Cited By ~ 123

Author(s):

YuHong Xu ◽

GePing Yin ◽

YuLin Ma ◽

PengJian Zuo ◽

XinQun Cheng

Keyword(s):

Carbon Source ◽

Lithium Ion Batteries ◽

Anode Material ◽

Polyvinylidene Fluoride ◽

Lithium Ion ◽

Carbon Anode ◽

Core Shell ◽

Silicon Carbon

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Supercritical carbon dioxide extraction of electrolyte from spent lithium ion batteries and its characterization by gas chromatography with chemical ionization

Journal of Power Sources ◽

10.1016/j.jpowsour.2017.03.114 ◽

2017 ◽

Vol 352 ◽

pp. 56-63 ◽

Cited By ~ 21

Author(s):

Xaver Mönnighoff ◽

Alex Friesen ◽

Benedikt Konersmann ◽

Fabian Horsthemke ◽

Martin Grützke ◽

...

Keyword(s):

Carbon Dioxide ◽

Gas Chromatography ◽

Supercritical Carbon Dioxide ◽

Lithium Ion Batteries ◽

Chemical Ionization ◽

Lithium Ion ◽

Supercritical Carbon Dioxide Extraction ◽

Carbon Dioxide Extraction ◽

Supercritical Carbon

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Mesoporous silicon/carbon hybrids with ordered pore channel retention and tunable carbon incorporated content as high performance anode materials for lithium-ion batteries

Energy ◽

10.1016/j.energy.2015.03.090 ◽

2015 ◽

Vol 85 ◽

pp. 159-166 ◽

Cited By ~ 25

Author(s):

Qun Li ◽

Longwei Yin ◽

Jingyun Ma ◽

Zhaoqiang Li ◽

Zhiwei Zhang ◽

...

Keyword(s):

Lithium Ion Batteries ◽

Anode Materials ◽

High Performance ◽

Lithium Ion ◽

Pore Channel ◽

Mesoporous Silicon ◽

Silicon Carbon

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The Possibility of Using Oxide Cathode Materials of Spent Lithium-Ion Power Batteries for Carbon Dioxide Capture from Fossil Fuel Plant

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.779-780.52 ◽

2013 ◽

Vol 779-780 ◽

pp. 52-55

Author(s):

Guang Jin Zhao ◽

Wen Long Wu ◽

Yang Guo

Keyword(s):

Carbon Dioxide ◽

Lithium Ion Batteries ◽

Cathode Materials ◽

Fossil Fuel ◽

Lithium Ion ◽

Battery Life ◽

Environment Friendly ◽

Novel Technology ◽

Oxide Cathode ◽

Scale Test

Following during development of electric vehicles and other modern-life appliances, numerous lithium-ion batteries are fabricated and used every year, and their consumption is constantly expanding. However, the battery life of the lithium-ion batteries is about 3 to 5 years, and there are some hazardous and noxious substances in spent lithium-ion batteries. Therefore, it is necessary to recycling these spent batteries with some resourceful and environment friendly technology. In this work, we propose a novel technology of resourceful disposing and utilizing oxide cathode materials from spent power lithium-ion batteries, which is using the recovered compounds from spent lithium-ion batteries to capture carbon dioxide from fossil fuel plant. The detailed technical routes of laboratory scale test and bench scale test are also given in the work.

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