S Vacancies Act as A Bridge to Promote Electron Injection from Z-Scheme Heterojunction to Nitrogen Molecule for Photocatalytic Ammonia Synthesis

2021 ◽  
pp. 133670
Author(s):  
Guanhua Zhang ◽  
Xinxin Yuan ◽  
Bo Xie ◽  
Yue Meng ◽  
Zheming Ni ◽  
...  
Keyword(s):  
Ammonia Synthesis ◽  
Electron Injection ◽  
Nitrogen Molecule

Learning the Stability and Activation of Chemical Bond of the Nitrogen Molecule from Ammonia Synthesis

Daxue Huaxue ◽  
2015 ◽  
Vol 30 (6) ◽  
pp. 33-44
Author(s):  
Yang Qi ◽  
◽  
◽  
Xie Gang ◽  
Chen Sanping ◽  
...  
Keyword(s):  
Chemical Bond ◽  
Ammonia Synthesis ◽  
Nitrogen Molecule ◽  
The Stability

Electron Donation by Low-Crystalline Ba-La-Ce Oxygen-Deficient Composite Oxide Accumulating on Ru Nanoparticles for Ammonia Synthesis under Mild Conditions

2019 ◽  
Author(s):  
Katsutoshi Sato ◽  
Shin-ichiro Miyahara ◽  
Yuta Ogura ◽  
Kotoko Tsujimaru ◽  
Yuichiro Wada ◽  
...  
Keyword(s):  
Ammonia Synthesis ◽  
Bond Cleavage ◽  
Synthesis Process ◽  
Strong Electron ◽  
Mild Conditions ◽  
Ru Nanoparticles ◽  
Rate Determining Step ◽  
Highly Active ◽  
Composite Oxides ◽  
Low Crystalline

<p>To mitigate global problems related to energy and global warming, it is helpful to develop an ammonia synthesis process using catalysts that are highly active under mild conditions. Here we show that the ammonia synthesis activity of Ru/Ba/LaCeO<i><sub>x</sub></i> pre-reduced at 700 °C is the highest reported among oxide-supported Ru catalysts. Our results indicate that low crystalline oxygen-deficient composite oxides, which include Ba<sup>2+</sup>, Ce<sup>3+</sup> and La<sup>3+</sup>, with strong electron-donating ability, accumulate on Ru particles and thus promote N≡N bond cleavage, which is the rate determining step for ammonia synthesis.</p>

Electron Donation by Low-Crystalline Ba-La-Ce Oxygen-Deficient Composite Oxide Accumulating on Ru Nanoparticles for Ammonia Synthesis under Mild Conditions

2019 ◽  
Author(s):  
Katsutoshi Sato ◽  
Shin-ichiro Miyahara ◽  
Yuta Ogura ◽  
Kotoko Tsujimaru ◽  
Yuichiro Wada ◽  
...  
Keyword(s):  
Ammonia Synthesis ◽  
Bond Cleavage ◽  
Synthesis Process ◽  
Strong Electron ◽  
Mild Conditions ◽  
Ru Nanoparticles ◽  
Rate Determining Step ◽  
Highly Active ◽  
Composite Oxides ◽  
Low Crystalline

<p>To mitigate global problems related to energy and global warming, it is helpful to develop an ammonia synthesis process using catalysts that are highly active under mild conditions. Here we show that the ammonia synthesis activity of Ru/Ba/LaCeO<i><sub>x</sub></i> pre-reduced at 700 °C is the highest reported among oxide-supported Ru catalysts. Our results indicate that low crystalline oxygen-deficient composite oxides, which include Ba<sup>2+</sup>, Ce<sup>3+</sup> and La<sup>3+</sup>, with strong electron-donating ability, accumulate on Ru particles and thus promote N≡N bond cleavage, which is the rate determining step for ammonia synthesis.</p>

Efficient Electron Injection into Organic Semiconductors Induced by Hydrogen Bonds

2019 ◽  
pp. 840
Author(s):  
Hirohiko Fukagawa ◽  
Munehiro Hasegawa ◽  
Katsuyuki Morii ◽  
Kazuma Suzuki ◽  
Tsubasa Sasaki ◽  
...  
Keyword(s):  
Hydrogen Bonds ◽  
Organic Semiconductors ◽  
Electron Injection

Rectification in Chiral Carbon Nanotubes with Hot Electron Injection

2020 ◽  
Vol 131 (3) ◽  
pp. 456-459
Author(s):  
S. S. Abukari ◽  
R. Musah ◽  
M. Amekpewu ◽  
S. Y. Mensah ◽  
N. G. Mensah ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Electron Injection ◽  
Hot Electron ◽  
Hot Electron Injection ◽  
Chiral Carbon
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