Dislocations and particle size governed band gap and ferromagnetic ordering in Ni doped ZnO nanoparticles synthesized via co-precipitation

2019 ◽  
Vol 45 (17) ◽  
pp. 23341-23354 ◽  
Author(s):  
Saikat Chattopadhyay ◽  
Kamakhya Prakash Misra ◽  
Arunava Agarwala ◽  
Aga Shahee ◽  
Sukriti Jain ◽  
...  
2020 ◽  
Vol 54 (3) ◽  
pp. 311-316 ◽  
Author(s):  
K. P. Misra ◽  
S. Jain ◽  
A. Agarwala ◽  
N. Halder ◽  
S. Chattopadhyay

2021 ◽  
Author(s):  
Shradha Roy ◽  
MRITUNJOY PRASAD GHOSH ◽  
Samrat Mukherjee

Abstract Proper correlation among the microstructural, optical and magnetic responses of Fe doped ZnO nanoparticles have been established in this work. All the Fe doped ZnO nanoparticles (Zn1-xFexO: x = 0.00, 0.05, 0.10 and 0.15) were prepared using chemical co-precipitation route. Average crystallites size of 18 nm to 28 nm was estimated using Scherrer’s formula. Compressive microstrain was detected in pristine ZnO samples, which moved toward tensile regime upon introducing Fe ions of different weight percentages. Mean crystallites size obtained from Scherrer’s formula was found in almost exact match with the particle size estimated from HRTEM images. Nearly spherical ZnO nanoparticles were seen in HRTEM images and negligible agglomeration among particles was also observed. Direct optical band gaps were found in the range of 2.89 eV to 3.24 eV as estimated from Tauc plots. A decent ferromagnetic signature in non-magnetic ZnO nanoparticles was also introduced at room temperature with the doping of Fe ions.


2016 ◽  
Vol 675-676 ◽  
pp. 69-72
Author(s):  
Krisana Chongsri ◽  
Wanichaya Mekprasart ◽  
Wisanu Pecharapa

In this work, we reported the preparation of F-doped ZnO nanoparticles by facile precipitation process using zinc nitrate and ammonium fluoride as starting precursors for Zn and F, respectively dissolved in deionized water. The precursor solution was prepared at various fluoride composition ranging from 1-5 wt%. The as-precipitated powders were calcined at different temperature from 500 °C to 700 °C for 2 h. Effect of calcination temperature and fluoride concentration on structural, morphologies, optical and electrical properties were investigated by X-ray diffraction (XRD), scanning electron microscope (SEM), UV-Vis spectroscopy, respectively. XRD results indicated the complete formation of hexagonal wurtzite structure of ZnO. SEM micrographs showed the agglomeration for each sample that noticeably influenced by fluoride content.


2015 ◽  
Vol 161 ◽  
pp. 275-280 ◽  
Author(s):  
Mohd. Arshad ◽  
Mohd. Meenhaz Ansari ◽  
Arham S. Ahmed ◽  
Pushpendra Tripathi ◽  
S.S.Z. Ashraf ◽  
...  

RSC Advances ◽  
2017 ◽  
Vol 7 (63) ◽  
pp. 39657-39665 ◽  
Author(s):  
Anju Anna Jacob ◽  
L. Balakrishnan ◽  
K. Shambavi ◽  
Z. C. Alex

Cobalt doping enhances visible absorption in ZnO nanoparticles as a result of d–d transitions. By co-precipitation method, Zn1−xCoxO nanoparticles had been synthesised and multiband photodetectors were fabricated after characteristic analysis.


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