Multioxide phase-based nanocomposite electrolyte (M@SDC where M= Zn2+/ Ba2+/ La3+/Zr2+ /Al3+) materials

2020 ◽  
Vol 46 (5) ◽  
pp. 6882-6888
Author(s):  
Asia Rafique ◽  
Muhammad Ashfaq Ahmad ◽  
Imran Shakir ◽  
Amjad Ali ◽  
Ghazanfar Abbas ◽  
...  
2011 ◽  
Vol 84 (4) ◽  
pp. 343-356 ◽  
Author(s):  
Kamlesh Pandey ◽  
Mrigank Mauli Dwivedi ◽  
Markandey Singh ◽  
S.L. Agrawal

Author(s):  
Rizwan Raza ◽  
Ghazanfar Abbas ◽  
S. Khalid Imran ◽  
Imran Patel ◽  
Bin Zhu

Oxide based two phase composite electrolyte (Ce0.9Gd0.1O2–Y2O3) was synthesized by coprecipitation method. The nanocomposite electrolyte showed the significant performance of power density 785 mW cm−2 and higher conductivities at relatively low temperature 550°C. Ionic conductivities were measured with ac impedance spectroscopy and four-probe dc method. The structural and morphological properties of the prepared electrolyte were investigated by scanning electron microscope (SEM). The thermal stability was determined with differential scanning calorimetry. The particle size that was calculated with Scherrer formula, 15–20 nm, is in a good agreement with the SEM and X- ray diffraction results. The purpose of this study is to introduce the functional nanocomposite materials for advanced fuel cell technology to meet the challenges of solid oxide fuel cell.


2016 ◽  
Vol 34 (7) ◽  
pp. 711-716 ◽  
Author(s):  
Fei XU ◽  
Chuanming LI ◽  
Zhentao WANG ◽  
Zhupeng YE ◽  
Yuan ZHANG ◽  
...  

2002 ◽  
Vol 756 ◽  
Author(s):  
Luis J. Smith ◽  
Jean-Marc Zanotti ◽  
Giselle Sandi ◽  
Kathleen A. Carrado ◽  
Patrice Porion ◽  
...  

ABSTRACTThe activation energies for poly(ethylene oxide) motion in a polymer clay composite are reported for the polymer intercalated and external to the clay. PEO intercalated into the clay is found to have a lower activation energy for motion but also a larger Arrhenius prefactor, by almost two orders of magnitude, than for PEO found external to the clay. Neutron scattering measurements confirm the presence of two environments and the effects of confinement on the mean square displacement of the PEO.


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