Porous hexagonal boron nitride nanosheets from g-C3N4 templates with a high specific surface area for CO2 adsorption

2020 ◽  
Vol 46 (17) ◽  
pp. 27627-27633
Author(s):  
Shuwen Li ◽  
Xianghui Zeng ◽  
Hui Chen ◽  
Wei Fang ◽  
Xuan He ◽  
...  
2020 ◽  
Vol 44 (48) ◽  
pp. 21125-21133
Author(s):  
Yaoyu Pan ◽  
Ziqiang Xu ◽  
Wenze Tan ◽  
Yalin Zhu ◽  
Yun Wang ◽  
...  

Commercial polymers have large cost advantage to drive HCPs to industrialize. The AHCPNPs using commercial PS as main block prove that it still has well-defined microporous structure, high specific surface area and extremely CO2 capture capacity.


2020 ◽  
Vol 20 (10) ◽  
pp. 6222-6234 ◽  
Author(s):  
Raghubeer S. Bangari ◽  
Niraj Sinha

In this study, we report the synthesis and characterization of boron nitride nanosheets (BNNSs), and their application as an adsorbent to remove the cationic dyes methylene blue (MB) and rhodamine B (RhB) from contaminated water. The synthesized adsorbent was characterized by high-resolution transmission electron microscopy (HR-TEM), field emission electron microscopy (FE-SEM), X-ray diffraction (XRD), Fourier transformed infrared spectroscopy (FTIR) and nitrogen adsorption–desorption isotherm. Detailed experiments and analysis were performed on various molar ratios of boron and nitrogen precursors (1:5 to 1:48) to achieve maximize specific surface area of BNNSs. Among all, the samples synthesized with boric acid and urea (1:30) dissolved in water and methanol produced maximum specific surface area (1801.9 m2 g−1). Further, the adsorption study was performed in batches by investigating various adsorption parameters such as effect of pH, contact time, adsorbent dose and adsorption isotherm. The pH study revealed that optimum value was found to be at pH 8. It was found through the kinetic study that pseudo-second-order (PSO) kinetic model was followed by the adsorbent during the adsorption of both the dyes. Further, the adsorption isotherm data well fitted with Langmuir isotherm model. The maximum adsorption capacities of MB and RhB were found to be 333.33 and 312.5 mg g−1, respectively. This demonstrates the potential of BNNSs as novel adsorbent for treatment of dye-contaminated water.


2010 ◽  
Vol 45 (8) ◽  
pp. 1013-1016 ◽  
Author(s):  
Hongming Yu ◽  
Xiaoxiao Huang ◽  
Guangwu Wen ◽  
Bo Zhong ◽  
Tao Zhang ◽  
...  

2017 ◽  
Vol 41 (20) ◽  
pp. 11640-11646 ◽  
Author(s):  
Bikramjeet Singh ◽  
Gurpreet kaur ◽  
Paviter Singh ◽  
Kulwinder Singh ◽  
Jeewan Sharma ◽  
...  

Boron nitride and titanium oxide composite (BN–TiO2) photocatalyst endowed with high specific surface area and large pore size was synthesized by ice bath method.


Metals ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 345 ◽  
Author(s):  
Lianzan Yang ◽  
Yongyan Li ◽  
Zhifeng Wang ◽  
Weimin Zhao ◽  
Chunling Qin

High-entropy alloys (HEAs) present excellent mechanical properties. However, the exploitation of chemical properties of HEAs is far less than that of mechanical properties, which is mainly limited by the low specific surface area of HEAs synthesized by traditional methods. Thus, it is vital to develop new routes to fabricate HEAs with novel three-dimensional structures and a high specific surface area. Herein, we develop a facile approach to fabricate nanoporous noble metal quasi-HEA microspheres by melt-spinning and dealloying. The as-obtained nanoporous Cu30Au23Pt22Pd25 quasi-HEA microspheres present a hierarchical porous structure with a high specific surface area of 69.5 m2/g and a multiphase approximatively componential solid solution characteristic with a broad single-group face-centered cubic XRD pattern, which is different from the traditional single-phase or two-phase solid solution HEAs. To differentiate, these are named quasi-HEAs. The synthetic strategy proposed in this paper opens the door for the synthesis of porous quasi-HEAs related materials, and is expected to promote further applications of quasi-HEAs in various chemical fields.


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