Mechanistic Kinetic Modelling of Enzyme-catalysed Oxidation Reactions of 5-Hydroxymethylfurfural (HMF) to 2,5-Furandicarboxylic acid (FDCA)

2021 ◽  
pp. 116982
Author(s):  
Miša Mojca Cajnko ◽  
Miha Grilc ◽  
Blaž Likozar
Keyword(s):  
Kinetic Modelling ◽  
Oxidation Reactions ◽  
Catalysed Oxidation ◽  
Furandicarboxylic Acid

Oscillatory phenomena in heterogeneous catalysed oxidation reactions

Catalysis ◽  
2007 ◽  
pp. 1-26 ◽  
Author(s):  
D. Mukesh ◽  
M. Goodman ◽  
C. M. Kenney ◽  
W. Morton
Keyword(s):  
Oxidation Reactions ◽  
Catalysed Oxidation

Cytochrome P-450 model reaction: effects of substitution on the rate of aromatic hydroxylation

2000 ◽  
Vol 04 (03) ◽  
pp. 285-291 ◽  
Author(s):  
NASSER SAFARI ◽  
FARZAD BAHADORAN ◽  
MOHAMMAD REZA HOSEINZADEH ◽  
REZA GHIASI
Keyword(s):  
Relative Rate ◽  
Kinetic Method ◽  
Oxidation Reactions ◽  
Aromatic Rings ◽  
Aromatic Hydroxylation ◽  
Catalysed Oxidation ◽  
Epoxidation Of Alkenes ◽  
Cytochrome P 450 ◽  
Related Compounds ◽  
Electron Withdrawing Substituents

The study of haemin-catalysed oxidation reactions was extended to substituted aromatic rings. Both electron-donating and electron-withdrawing substituents on aromatic rings act as para- and meta-directing agents in the presence of tetrakis(2,6-dichlorophenyl)porphyrin iron(III) chloride as catalyst and m-chloroperbenzoic acid as oxidant. A new kinetic method for measuring relative rates of epoxidation of alkenes and related compounds has been developed; while steric hindrance results in decreasing the rate of hydroxylation, electron-rich and electron-withdrawing substituents were found to increase the rate of hydroxylation. A linear relationship between the logarithm of the relative rate of hydroxylation and σ Hammet is obtained, although electron-donating and electron-withdrawing substituents fit separate lines. Addition of pyridine to haemin was shown to increase the yield of epoxidation but decrease the yield of aromatic hydroxylation.

Understanding the reaction mechanisms of Pd-catalysed oxidation of alcohols and domino oxidation–arylation reactions using phenyl chloride as an oxidant

2014 ◽  
Vol 1 (10) ◽  
pp. 1188-1196 ◽  
Author(s):  
Yang Li ◽  
Zhenyang Lin
Keyword(s):  
Reaction Mechanisms ◽  
Oxidation Reactions ◽  
Catalysed Oxidation ◽  
Oxidation Of Alcohols

The Pd-catalysed oxidation reactions of alcohols and their domino oxidation–arylation reactions using phenyl chloride as an oxidant have been computationally investigated.

scholarly journals Oxidation of Benzaldehyde and Substituted Benzaldehydes by Permanganate under Phase Transfer Catalysis in Non Polar Solvents

2016 ◽  
Vol 5 (3) ◽  
pp. 110
Author(s):  
K. Bijudas ◽  
P. Bashpa
Keyword(s):  
Phase Transfer ◽  
High Yield ◽  
Phosphonium Salts ◽  
Oxidation Reactions ◽  
Polar Solvents ◽  
Phase Transfer Catalysts ◽  
Catalysed Oxidation ◽  
Point Determination ◽  
Substituted Benzaldehydes ◽  
Substituted Benzoic Acids

<div><p class="Affiliation"><em>Phase transfer catalysed oxidation of benzaldehyde and substituted benzaldehydes by permanganate ion have been studied in non polar solvents like ethyl acetate and toluene. The obtained products were charecterised by melting point determination and infra red spectral analysis. Benzoic acid and corresponding substituted benzoic acids were formed as the product with very high yield. The oxidation reactions were carried out by using various quaternary ammonium and phosphonium salts as phase transfer catalyst. The effect of non polar solvents and various phase transfer catalysts on yield of product was also carried out.</em></p></div>

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