Hydroxyl radical concentration profile in photo-Fenton oxidation process: Generation and consumption of hydroxyl radicals during the discoloration of azo-dye Orange II

Chemosphere ◽  
2011 ◽  
Vol 82 (10) ◽  
pp. 1422-1430 ◽  
Author(s):  
Takuya Maezono ◽  
Masahiro Tokumura ◽  
Makoto Sekine ◽  
Yoshinori Kawase
2014 ◽  
Vol 69 (5) ◽  
pp. 1115-1119 ◽  
Author(s):  
Chang Wang ◽  
Siyue Zhang ◽  
Sakai Yuji ◽  
Zongpeng Zhang

The absorbances of different concentrations of Fe2+, Fe3+ and H2O2 were investigated by UV-visible spectrophotometry without separating the substances. The law of complex formation was studied by considering changes in the UV-vis spectra of mixtures of these three substances. The results show that upon eliminating the influence of the substrate, an iron-based complex was present in the Fenton reaction, which exhibited substantial absorbance from 190 to 500 nm. Therefore, the presence of an unknown complex in the Fenton oxidation process was verified and its concentration varied with a change in the concentration of hydrogen peroxide. This study provides a strong foundation for further studies into the mechanism of traditional hydroxyl radical theory of the Fenton reaction.


2013 ◽  
Vol 16 (2) ◽  
Author(s):  
Nese Ertugay ◽  
Filiz Nuran Acar

AbstractAdvanced oxidation of an azo dye, Basic Blue 9 (BB9) by Fenton oxidation was investigated in batch experiments. The UV-vis spectral changes of in aqueous solution during Fenton process were studied. It was easier to destruct the azo linkage group than to destruct the aromatic rings of (BB9) by Fenton process. The effects of different reaction parameters such as initial ferrous concentration, initial hydrogen peroxide (H


2007 ◽  
Vol 74 (3) ◽  
pp. 647-652 ◽  
Author(s):  
Jian-Hui Sun ◽  
Sheng-Peng Sun ◽  
Guo-Liang Wang ◽  
Li-Ping Qiao

2012 ◽  
Vol 116 (13) ◽  
pp. 7457-7463 ◽  
Author(s):  
Yujing Wang ◽  
Hongying Zhao ◽  
Junxia Gao ◽  
Guohua Zhao ◽  
Yonggang Zhang ◽  
...  

2009 ◽  
Vol 161 (2-3) ◽  
pp. 1052-1057 ◽  
Author(s):  
Sheng-Peng Sun ◽  
Cheng-Jie Li ◽  
Jian-Hui Sun ◽  
Shao-Hui Shi ◽  
Mao-Hong Fan ◽  
...  

2012 ◽  
Vol 627 ◽  
pp. 378-381
Author(s):  
Bi Rong Wang

Fenton pretreatment has been used for treating dye wastewater. The effects of the dos of H2O2 and FeSO4, reaction time and pH on the removal COD were investigated. It was found that, when the reaction conditions are as follows: COD 2850 mg/L dyeing wastewater, the dosage of H2O2 is 140mmol/L, FeSO4 17.02 mmol/L, pH 7.6, and reaction time 1.0 h, the CODcr of dye wastewater removal rate of up to 70%. Fenton pretreatment process of dye wastewater has a broad prospect.


2014 ◽  
Vol 20 (3) ◽  
pp. 848-857 ◽  
Author(s):  
Adriana Saldaña-Robles ◽  
Ricardo Guerra-Sánchez ◽  
Manuel I. Maldonado-Rubio ◽  
Juan M. Peralta-Hernández

2018 ◽  
Vol 6 (6) ◽  
pp. 7070-7079 ◽  
Author(s):  
Fernando H. Borba ◽  
Leandro Pellenz ◽  
Francine Bueno ◽  
Jonas Jean Inticher ◽  
Luana Braun ◽  
...  

Author(s):  
Wendong Feng ◽  
Jian Li ◽  
Shaoqing Jia ◽  
Yunhai Wang ◽  
Dunyi Ye

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