Preparation of Mn/Mg/Ce Ternary Ozone Catalyst and Its Mechanism for the Degradation of Printing and Dyeing Wastewater

The printing and dyeing wastewater produced by different dyes, as well as different printing and dyeing processes, have different components. These wastewater have high toxicity, high organic concentration, and deep chromaticity. Ozone catalytic oxidation is a very promising technical method for wastewater treatment. In this paper, Mn/Mg/Ce ternary catalyst was prepared, and the ozone catalytic oxidation treatment of actual and simulated printing and dyeing wastewater was performed to study the performance of four different carrier catalysts, namely, molecular sieve (MS), silica gel (SG), attapulgite (ATP), and nano alumina (Al2O3), by simulated dynamic test. The effects of reaction time, pH, and catalyst dosage on methyl orange degradation were studied. The results showed that under the optimum treatment conditions (120 min, pH 11, and 12.5 g/L catalyst dosage), the degradation rate of methyl orange reached 96% and the removal rate of the chemical oxygen demand of printing and dyeing wastewater reached 48.7%. This study shows that the treatment effect of ozone catalytic oxidation on printing and dyeing wastewater is remarkably improved after catalyst addition. This study provides a new choice of ozone catalyst for the degradation of printing and dyeing wastewaters in the future.

Treatment of C.I Reactive Blue 160 by ozonation system

This study was carried out to assess the treatment ability of color, dye, and COD in the dyeing wastewater containing C.I Reactive Blue 160 by ozonation system. Both batch and continuous operating modes with concurrent and counter-current flows were investigated. The effects of the ozone gas flow rate, pH, temperature, Na2CO3 concentration, and initial dye concentration were evaluated. The decolorization, dye removal efficiencies, and mineralization ability of COD by ozonation were determined. The results indicated that ozonation had high efficiency in the treatment of dyeing wastewater containing C.I Reactive Blue 160. The treatment performance was affected by the ozone gas flow rate, pH, temperature, Na2CO3 concentration, and initial dye concentration. The removal efficiency of color, dye, and COD were 98.04%, 99.84%, and 87.31% for the treatment of 200 mg/L initial dye concentration in batch mode with 30 min ozonation time, respectively. In the continuous operation and counter-current flow, the color, dye, and COD removal efficiencies reached 97.24%, 99.76%, and 86.38% after 30 min HRT, respectively, and higher than concurrent flow. The reaction of ozone and C. I Reactive Blue 160 was the first-order reaction in both batch and continuous operation. The complete mineralization required 90 min ozonation time.

Optimization of Process Parameters for Enhanced Degradation of Methylene Blue by Trough Ultrasonic

Due to the complex quality and the large discharge of printing and dyeing wastewater, it will pollute the environment and affect human health. Therefore, how to use efficient and inexpensive treatment methods to treat printing and dyeing wastewater has become an urgent problem to be solved. At present, most printing and dyeing wastewater contains methylene blue pollutants. Based on the previous research in this article, the process conditions for the enhanced degradation of methylene blue by trough ultrasound are optimized. Orthogonal test results show that the optimal process parameter for the degradation of methylene blue by trough ultrasonic is pH 12.70, and the initial With a concentration of 10.00mg/L and an ultrasonic power of 200W, under the above optimal process conditions, the degradation rate of methylene blue is 77.95%; Ultrasound improves the rapid degradation of methylene blue through mechanisms such as cavitation, thermal and mechanical effects. This process can be used for the industrial degradation of methylene blue. The application provides a research basis.

Preparation and the Catalytic Properties of Attapulgite / TiO2 Nanocomposites

With the rapid development of industry, the discharge of textile printing and dyeing wastewater will cause serious pollution to other pure water bodies. It is imperative to deal with textile printing and dyeing wastewater. In this paper, with titanium tetrachloride as a precursor, attapulgite (ATP) / TiO2 nanocomposites were prepared by a neutralizing hydrolysis method and their catalytic activities were investigated by the oxidative degradation of methylene blue dye using ozone as oxidant. The test results showed that there were significant interactions between TiO2 and ATP support. The effects were also studied of ozone concentration, catalyst amount, reaction temperature, and initial concentration of methylene blue on the degradation rate of methylene blue catalyzed by the prepared attapulgite / TiO2 nanocomposites, and under the optimal conditions, the methylene blue could be degraded more than 90% in 30 minutes. Compared with that of pure ATP, the catalytic activities of ATP / TiO2 nanocomposites were enhenced remarkably. The degradation mechanism of methylene blue was also discussed.

The effect of different types of AOPs supported by hydrogen peroxide on the decolorization of methylene blue and viscose fibers dyeing wastewater

Wastewater from the textile industry containing a high concentration of organic and inorganic chemicals have strong color and residual chemical oxygen demand (COD). Therefore, advanced oxidation processes (AOPs) are very good candidates to treat textile industry wastewater. In this study, we investigated the effect of different types of AOPs supported with hydrogen peroxide (H2O2) on the treatment of viscose fibers dyeing wastewater. Fenton, photo-Fenton, and Fenton supported subcritical water oxidation (FSWO) processes were chosen as AOPs to compare the treatment efficiency of viscose fibers dyeing wastewater. The effects of solution pH, Fe2+ concentration, and H2O2 concentration on the treatment of viscose fibers dyeing wastewater were tested. The maximum color and COD removal efficiency was obtained corresponding to pH 2.5 for all oxidation methods when MB dye solution was used. However, the maximum efficiencies were obtained at pH 3.0 for real textile wastewater decolorization. The MB dye removal efficiency was increased to 97.22, 100, and 100% for Fenton, photo-Fenton, and FSWO processes, respectively, when the addition of H2O2 concentration was adjusted to 125 mg/L. However, the maximum color removal efficiencies of viscose fibers dyeing wastewater were obtained 56.94, 61.26, 64.11% for Fenton, photo-Fenton, FSWO processes, respectively. As a result, the FSWO showed maximum color removal efficiencies.